Synthesis and characterization of new thermally stable poly(ester‐imide)s derived from 2,2′‐bis(4‐trimellitimidophenoxy)biphenyl and 2,2′‐bis(4‐trimellitimidophenoxy)‐1,1′‐binaphthyl and various aromatic dihydroxy compounds

A series of new alternating aromatic poly(ester‐imide)s were prepared by the polycondensation of the preformed imide ring‐containing diacids, 2,2′‐bis(4‐trimellitimidophenoxy)biphenyl (2a) and 2,2′‐bis(4‐trimellitimidophenoxy)‐1,1′‐binaphthyl (2b) with various aromatic dihydroxy compounds in the presence of pyridine and lithium chloride. A model compound (3) was also prepared by the reaction of 2b with phenol, its synthesis permitting an optimization of polymerization conditions. Poly(ester‐imides) were fully characterized by FTIR, UV‐vis and NMR spectroscopy. Both biphenylene‐ and binaphthylene‐based poly(ester‐imide)s exhibited excellent solubility in common organic solvents such as tetrahydrofuran, m‐cresol, pyridine and dichloromethane. However, binaphthylene‐based poly(ester‐imide)s were more soluble than those of biphenylene‐based polymers in highly polar organic solvents, including N‐methyl‐2‐pyrrolidone, N,N‐dimethylacetamide, N,N‐dimethylformamide and dimethyl sulfoxide. From differential scanning calorimetry thermograms, the polymers showed glass‐transition temperatures between 261 and 315 °C. Thermal behaviour of the polymers obtained was characterized by thermogravimetric analysis, and the 10 % weight loss temperatures of the poly(ester‐imide)s was in the range 449–491 °C in nitrogen. Furthermore, crystallinity of the polymers was estimated by means of wide‐angle X‐ray diffraction. The resultant poly(ester‐imide)s exhibited nearly an amorphous nature, except poly(ester‐imide)s derived from hydroquinone and 4,4′‐dihydroxybiphenyl. In general, polymers containing binaphthyl units showed higher thermal stability but lower crystallinity than polymers containing biphenyl units. Copyright © 2005 Society of Chemical Industry     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

A study on melt recycling of bio-based polypropylene/thermoplastic starch compound

The compulsion to use bioplastics has increased significantly today. One of the important aspects of plastics is their recyclability. Therefore, the important question of this research is that although bio-based compounds containing starch are sensitive to thermal-mechanical recycling processes, are such products thermally recyclable? To answer the question, polypropylene (PP)/thermoplastic starch (TPS) compound granules were extruded up to five times, and in the other part, single-extruded granules were blended at different ratios with virgin granules by extrusion. In order to characterize these samples, Fourier transform infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry, rotational disc rheometry, tensile properties, and appearance evaluation were used. The results showed that it is possible to recycle PP/TPS granules up to four times repetition of the extrusion operation and the fifth repetition also showed slight changes. There was also a blend of single-extruded granules with virgin material up to a 50:50% composition without significant variation.     

Simultaneous state estimation and parameter identification in linear fractional order systems using coloured measurement noise

In the present paper, the identification and estimation problem of a single-input–single-output (SISO) fractional order state-space system will be addressed. A SISO state-space model is considered in which parameters and also state variables should be estimated. The canonical fractional order state-space system will be transformed into a regression equation by using a linear transformation and a shift operator that are appropriate for identification. The identification method provided in this paper is based on a recursive identification algorithm that has the capability of identifying the parameters of fractional order state-space system recursively. Another subject that will be addressed in this paper is a novel fractional order Kalman filter suitable for the systems with coloured measurement noise. The promising performance of the proposed methods is verified using two stable fractional order systems.     

The availability of source code in relation to timely response to security vulnerabilities

Once a vulnerability has been found in an application or service that runs on a computer connected to the Internet, fixing that exploit in a timely fashion is of the utmost importance. There are two parts to fixing vulnerability: a party acting on behalf of the application's vendor gives instructions to fix it or makes a patch available that can be downloaded; then someone using that information fixes the computer or application in question. This paper considers the effects of proprietary software versus non-proprietary software in determining the speed with which a security fix is made available, since this can minimize the amount of time that the computer system remains vulnerable.     

Application of ion-engineered Persian Gulf seawater in EOR:effects of different ions on interfacial tension,contact angle,zeta potential,and oil recovery

In this study,we initially performed interfacial tension(IFT)tests to investigate the potential of using the Persian Gulf sea-water(PGSW)as smart water with dif...     

Production and radiochemical separation of no-carrier-added <Superscript>88</Superscript>Y by liquid-liquid extraction

A method was suggested for the cyclotron production of ⁸⁸Y with liquid-liquid extraction. The sedimented ^natSrCO₃ target was irradiated with 18-MeV protons at current of 20 μA for 10 h. The ⁸⁸Y yields of about 1.326 MBq μA⁻¹ h⁻¹ were experimentally obtained. Solvent extraction of no-carrier-added ⁸⁸Y from irradiated strontium carbonate target in the hydrochloric acid solution was studied using di(2-ethylhexyl) hydrogen phosphate (HDEHP). The optimum separation was achieved in the system n-hexane/10% HDEHP-0.1 M HCl. Yttrium radionuclides were recovered from the HDEHP phase by stripping with 60 ml of 9 M HC1. Also, excitation functions of the proton, deuteron, and α-particle induced reactions of ⁸⁹Y, ⁸⁸Sr, ^natSr, and natRb were determined using computer codes and compared to the existing data.     

Additional degree of freedom in phased-MIMO radar signal design using space-time codes

In this paper, an additional degree of freedom in phased multi-input multi-output (phased-MIMO) radar with any arbitrary desired covariance matrix is proposed using space-time codes. By using the proposed method, any desired transmit covariance matrix in MIMO radar (phased-MIMO radars) can be realized by employing fully correlated base waveforms such as phased-array radars and simply extending them to different time slots with predesigned phases and amplitudes. In the proposed method, the transmit covariance matrix depends on the base waveform and space-time codes. For simplicity, a base waveform can be selected arbitrarily (ie, all base waveforms can be fully correlated, similar to phased-array radars). Therefore, any desired covariance matrix can be achieved by using a very simple phased-array structure and space-time code in the transmitter. The main advantage of the proposed scheme is that it does not require diverse uncorrelated waveforms. This considerably reduces transmitter hardware and software complexity and cost. One the receiver side, multiple signals can be analyzed jointly in the time and space domains to improve the signal-to-interference-plus-noise ratio.     

The PANOPTIC Camera: A Plenoptic Sensor with Real-Time Omnidirectional Capability

A new biologically-inspired vision sensor made of one hundred “eyes” is presented, which is suitable for real-time acquisition and processing of 3-D image sequences. This device, named the Panoptic camera, consists of a layered arrangement of approximately 100 classical CMOS imagers, distributed over a hemisphere of 13 cm in diameter. The Panoptic camera is a polydioptric system where all imagers have their own vision of the world, each with a distinct focal point, which is a specific feature of the Panoptic system. This enables 3-D information recording such as omnidirectional stereoscopy or depth estimation, applying specific signal processing. The algorithms dictating the image reconstruction of an omnidirectional observer located at any point inside the hemisphere are presented. A hardware architecture which has the capability of handling these algorithms, and the flexibility to support additional image processing in real time, has been developed as a two-layer system based on FPGAs. The detail of the hardware architecture, its internal blocks, the mapping of the algorithms onto the latter elements, and the device calibration procedure are presented, along with imaging results.     

Synthesis,characterization, and supercapacitor studies of manganese (IV) oxide nanowires

One-dimensional manganese (IV) oxide (MnO₂) (～20 nm in average diameter) were synthesized by cathodic electrodeposition and heat treatment. The mechanism of electrodeposition and nanowire formation were discussed. The product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Fourier transform infrared (FT-IR). Nanowires with varying lengths and diameters were found in TEM and SEM images of the sample. The results of N₂ adsorption–desorption analysis indicated that the BET surface area of the MnO₂ nanowires was 157 m² g^?1 and the pore size distributions were 2.5 and 4.5 nm. The electrochemical performances of the prepared MnO₂ as an electrode material for supercapacitors were evaluated by cyclic voltammetry and galvanostatic charge/discharge measurements in a solution of 0.5 M Na₂SO₄. The higher specific capacitance of 318 F g^?1 and good capacity retention of 86% were achieved after 1000 charge–discharge cycles had been observed for the MnO₂ nanowires electrode.