Copolymerization of bromophenylmaleimide with ethyl or butyl methacrylate

N‐p‐Bromophenylmaleimide (BrPMI) does not polymerize in solution by conventional free radical mechanism. However, it readily polymerized in bulk when mixed with a free radical initiator and heated in a microwave oven for 7–8 min. Copolymerization of ethyl methacrylate or butyl methacrylate with BrPMI was conducted in dioxane. The copolymers were characterized by IR and ¹H NMR spectroscopy and gel permeation chromatography. The monomer reactivity ratios were calculated by a non‐linear least‐square analysis. Thermal analysis indicated a great improvement in thermal stability of the copolymers compared with the methacrylate homopolymers. BrPMI was also polymerized in bulk in the DSC pan, which allowed the calculation of the activation energy of its polymerization. Copyright © 2003 Society of Chemical Industry     

Preparation and characterization of oxygen deficient perovskites,BaBiO3−x

Oxygen nonstoichiometry in the distorted perovskite BaBiO₃ has been studied by thermogravimetric analysis using controlled oxygen pressures. Three distinct regions of nonstoichiometry are observed with composition ranges which narrow as the temperature is lowered. Samples isolated from each region were shown by powder X-ray diffraction to retain the perovskite subcell but show different types of framework distortion. Low temperature reoxidation of the oxygen deficient phases is also described.     

Models of human reaction to vehicle environments

Models for predicting human comfort responses to environmental variables are presented for diverse vehicles. Air mode studies reveal that comfort is a function of vertical and transverse accelerations, noise levels and seat factors, as well as manoeuvre conditions. Comfort models for ground-based vehicles involve roll rates and noise levels.     

Cross-correlation analyses of nonlinear systems with spatiotemporalinputs [visual neurons]

Methods are presented for analyzing the low-order stimulus-response cross-correlation functions (or kernels) of visual neurons studied with spatiotemporal white noise. In particular, formulas are derived that relate the low-order kernels of a cell to its responses to single-drifting, double-drifting, and counterphase gratings. The harmonic response terms contributed by the low-order kernels include a mean response term, first- and second-harmonic terms, and sum- and difference-harmonic terms. Using the formulas given, one can obtain kernel-based predictions for the spatiotemporal-frequency tuning of each harmonic. These kernel-based predictions can then be compared with harmonic tuning data obtained in experiments with real grating stimuli. The methods are illustrated using data recorded from one simple and one complex cell from the primary visual cortex of the monkey. The approach of transforming low-order kernels into predicted harmonic tuning functions provides a useful data reduction technique as well as providing insight into the interpretation of kernels     

The tail of localized states in the band gap of the quantum well in the In0.2Ga0.8N/GaN system and its effect on the laser-excited photoluminescence spectrum

Semiconductors - It is established experimentally that the peak in the photoluminescence spectrum of the In0.2Ga0.8N/GaN heterostructure with a quantum well shifts by ～150 meV as the power...     

Ten-inch molecular beam epitaxy production system for HgCdTe growth

Growth of Hg_1−xCd_xTe by molecular beam epitaxy (MBE) has been under development since the early 1980s at Rockwell Scientific Company (RSC), formerly the Rockwell Science Center; and we have shown that high-performance and highly reproducible MBE HgCdTe double heterostructure planar p-on-n devices can be produced with high throughput for various single- and multiplecolor infrared applications. In this paper, we present data on Hg_1−xCd_xTe epitaxial layers grown in a ten-inch production MBE system. For growth of HgCdTe, standard effusion cells containing CdTe and Te were used, in addition to a Hg source. The system is equipped with reflection high energy electron diffraction (RHEED) and spectral ellipsometry in addition to other fully automated electrical and optical monitoring systems. The HgCdTe heterostructures grown in our large ten-inch Riber 49 MBE system have outstanding structural characteristics with etch-pit densities (EPDs) in the low 10⁴ cm⁻² range, Hall carrier concentration in low 10¹⁴ cm⁻³, and void density <1000 cm². The epilayers were grown on near lattice-matched (211)B Cd_0.96Zn_0.04Te substrates. High-performance mid wavelength infrared (MWIR) devices were fabricated with R₀A values of 7.2×10⁶ Ω-cm² at 110 K, and the quantum efficiency without an antireflection coating was 71.5% for cutoff wavelength of 5.21 μm at 37 K. For short wavelength infrared (SWIR) devices, an R₀A value of 9.4×10⁵ Ω-cm² at 200 K was obtained and quantum efficiency without an antireflection coating was 64% for cutoff wavelength of 2.61 μm at 37 K. These R₀A values are comparable to our trend line values in this temperature range.     

Development of the Utah Artificial Arm

The development of a practical multifunction, electronically controlled artificial arm is an extremely complex undertaking. Various technical factors such as the limited capability of man-made components, together with problems in the development of adequate control systems, impair the ultimate performance of any prosthesis. Also, nontechnical problems in clinical, marketing, and economic areas strongly influence the potential success of any system. Consequently, the realization of a practical system with the possibility of near-term application requires simultaneous and coordinated work by personnel in a number of normally unrelated areas of medicine and engineering. The opinions of engineers, physicians, amputees, industrial entities, and institutions responsible for funding the fitting of artificial limnbs must be understood and must influence the design process. This paper begins with a discussion of the natural limb and those design objectives and compromises which govern the development of its artificial counterpart Specific details of the Utah Arm are then reviewed, along with general comments regarding the area of prosthetic limb research and application.     

Ractions of SiC with H2/H2O/Ar Mixtures at 1300°C

The reactions of a sintered α-SiC with 5% H₂/H₂O/Ar at 1300°C were studied. Thermomchemical modeling indicates that three reaction regions are expected, depending on the initial water vapor or equivalently oxygen content of the gas stream. A high oxygen content ( P (O₂) > 10⁻²² atm) leads to a SiO₂ formation. This generally forms as a protective film and limits consumption of the SiC (passive oxidation). An intermediate oxygen content (10⁻²² atm > P (O₂) > 10⁻²⁶ atm) leads to SiO and CO formation. These gaseous products can lead to rapid consumption of the SiC (active oxidation). Thermogravimetric studies in this intermediate region gave reaction rates which appear to be controlled by H₂O gas-phase transport to the sample and reacted microstructures showed extensive grain-boundary attack in this region. Finally, a very low oxygen content ( P (O₂) < 10⁻²⁶ atm) is thermochemically predicted to lead to selective removal of carbon and formation of free silicon. Experimentally low weight losses and iron silicides are observed in this region. The iron silicides are attributed to reaction of free silicon and iron impurities in the system.     

Intermittent metal cutting at small cutting depths—1. Dead zone phenomena and surface finish

Chip formation in intermittent metal cutting at small cutting depths was investigated by single edge experiments. Single cutting strokes were performed in a modified Charpy pendulum tester which offers force measurement, accurate selection of cutting speed and feed in the ranges typical of many intermittent high speed steel (HSS) tool operations. The pendulum is also provided with an excellent quick-stop mechanism.

The cutting performance of HSS tools in three widely used steel grades (including one plain carbon, one quenched and tempered and one austenitic stainless steel) was studied. A number of double rake micro geometries, with primary rake angles ranging from +20° (parrot bill) to −60°, all with a prepared 0.1 mm wear land were tested. The performance of the different edge geometries was investigated with respect to class of dead zone developed on the cutting edge, and its relation to chip curl and finish of the cut surface. The results are visualized in a dead zone map. The influence of cutting length, cutting speed, cutting depth and TiN-coating was treated specifically.

Among the most important observations were:

• the micro geometry of the edge influences the dead zone formation mechanism and hence the class of dead zone,

• the surface finish is strongly dead zone class dependent,

• the chip curl is determined by edge micro geometry and dead zone class.

The relationships between the varied parameters, generated dead zones and resulting cutting forces are presented in part 2 of this paper.