铁磁偶合的Gd（Ⅲ）Cu（Ⅱ）配合物──组装分子基铁磁体的一种重要元件

铁磁偶合的Ｇｄ（Ⅲ）Ｃｕ（Ⅱ）配合物──组装分子基铁磁体的一种重要元件缪明明，廖代正，王耕霖（南开大学化学系天津３０００７１）摘要分子基磁体的设计是自然界向化学家挑战的一个热点课题。铁磁偶合的Ｇｄ（Ⅲ）Ｃｕ（Ⅱ）配合物是组装分子基磁体的一种重要元件。...     

袖珍计算机放射性总量测量系统

本文介绍以PC-1500(A)型袖珍计算机为主体的地面放射性总量数据采集及处理系统的方案、硬件、软件及应用。     

Poly(3‐chlorothiophene) films prepared by the direct electrochemical oxidation of 3‐chlorothiophene in mixed electrolytes of boron trifluoride diethyl etherate and sulfuric acid

3‐Chlorothiophene (CT) was electrochemically polymerized in mixed electrolytes of a boron trifluoride diethyl etherate solution containing 0–20% (by volume) sulfuric acid. The oxidation potentials of the monomer in these media were measured to be only 1.06–1.31 V (vs Ag/AgCl). These values were much lower than that of CT in acetonitrile and 0.1 mol/L (Bu)₄NBF₄ (1.92 V vs Ag/AgCl). Poly(3‐chlorothiophene) (PCT) films with conductivities of 0.1–2 S cm^?1 were obtained. The structure, morphology, and electrochemical behavior of the PCT films also were investigated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 502–509, 2003     

Solvent free oxidation of alcohols catalyzed by KMnO4 adsorbed on Kieselguhr

Efficient and selective oxidation of primary and secondary alcohols to the corresponding aldehydes and ketones catalyzed by potassium permanganate supported on Kieselguhr reagent under solvent free conditions are reported.     

新型城镇化下欠发达地区传统文化保护研究——以张家口市段家堡村为例

新型城镇化背景下欠发达地区传统文化保护的关键取决于其能否在保护文化资本和环境资本的基础上,实现经济资本的提升、文化价值观念及生活方式的转变.通过对张家口市下花园区段家堡村传统文化的调查研究,提出转变观念,主动保护、挖掘和丰富欠发达地区传统文化特色,提升旅游开发优势,带动地区经济发展,实现新型城镇化的同时更好地保护传统文化.     

中英规范有关建筑物防雷接地做法的比较

结合国家标准GB 50057-2010《建筑物防雷设计规范》和BS规范BS EN 62305-2006《Protection against lightning》,介绍了两本规范中建筑物防雷装置做法,简述了两种规范中有关建筑物外部防雷(接闪器、引下线、接地装置)、内部防雷以及防雷击电磁脉冲的有关规范条文规定和比较。     

环境经济系统工程的思考

环境问题与经济问题紧密相连,由于环境问题的综合性和复杂性,需要运用系统工程的方法和经济学原理,将环境问题置于整个经济系统中统筹考虑,建立相对完整的环境经济系统工程方法体系,将环境保护工作纳入经济社会发展中,使其成为决策中主要考虑的因素之一,并引起应有的重视。本研究从环境与经济承载力、环境投资的经济分析、环境与投资效率比较、环境资源的经济价值以及生态补偿与污染赔偿等方面构建环境经济系统工程的基本框架体系,并结合实际进行案例分析。研究表明,单纯的政府行政干预不如创造条件,如补偿、税收减免、投资、贴息等,使其具备在市场规则下.自动引导资源向环境保护与污染治理的投入,如排污指标的交易等。此外,自然资源是不可或缺的稀有资本,应该将保护生态系统及生物多样性纳入各级政府决策的主要方面。     

Application potential of bone marrow mesenchymal stem cell (BMSCs) based tissue-engineering for spinal cord defect repair in rat fetuses with spina bifida aperta

Spina bifida aperta are complex congenital malformations resulting from failure of fusion in the spinal neural tube during embryogenesis. Despite surgical repair of the defect, most patients who survive with spina bifida aperta have a multiple system handicap due to neuron deficiency of the defective spinal cord. Tissue engineering has emerged as a novel treatment for replacement of lost tissue. This study evaluated the prenatal surgical approach of transplanting a chitosan–gelatin scaffold seeded with bone marrow mesenchymal stem cells (BMSCs) in the healing the defective spinal cord of rat fetuses with retinoic acid induced spina bifida aperta. Scaffold characterisation revealed the porous structure, organic and amorphous content. This biomaterial promoted the adhesion, spreading and in vitro viability of the BMSCs. After transplantation of the scaffold combined with BMSCs, the defective region of spinal cord in rat fetuses with spina bifida aperta at E20 decreased obviously under stereomicroscopy, and the skin defect almost closed in many fetuses. The transplanted BMSCs in chitosan–gelatin scaffold survived, grew and expressed markers of neural stem cells and neurons in the defective spinal cord. In addition, the biomaterial presented high biocompatibility and slow biodegradation in vivo. In conclusion, prenatal transplantation of the scaffold combined with BMSCs could treat spinal cord defect in fetuses with spina bifida aperta by the regeneration of neurons and repairmen of defective region.