Surface Chemistry of Lead Titanate and Its Impact on Binder Removal

Carbon residue after binder burnout was characterized for several nonstoichiometric lead titanate powders. Thermal decomposition of the poly(methyl methacrylate) (PMMA) binder was performed in nitrogen at 600°C. A drastic decrease in carbon retention was obtained in the case of the titanium-rich samples. The amount of carbon retention varies from 0.2 mg/m² to 1.2 mg/m² by changing the Pb/Ti molar ratio from 0.92 to 1.08. The surface reaction between PMMA and lead titanate particles was studied by diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS). Surface hydroxyls reacted with ester groups in the PMMA or the methylmethacrylate monomer produced upon pyrolysis. The DRIFTS results showed that titaniumrich samples are less reactive and produce less surfacebound organic groups. Interestingly, titanium-rich samples contained more surface hydroxyls. Isoelectric point measurements, however, show that titanium-rich samples are more acidic. Thus, the reactivity of the surface hydroxyls is determined primarily by their acid-base characteristics rather than their concentration. Lead titanate powder was exposed to MMA vapor in a tube furnace at the indicated temperatures using nitrogen carrier gas as a model experiment. DRIFTS difference spectroscopy and Raman spectroscopy were performed on these samples after the exposure. MMA reacts with lead titanate powder in manner similar to PMMA. Analysis for sp ² and sp ³ absorbance of Raman spectra of these exposed powders at 400°–600°C showed pyrolysis behavior of surface-reacted species. The relative amount of sp ² bonded carbon decreases with increasing exposure temperature.     

iOS application for quadrotor remote control

With the progress of electronics technology, the development of civilian UAV (unmanned aerial vehicle) applications becomes possible. In addition, smartphones have rapidly gained popularity and become very important due to the simple operability and mobility. Hence, there is a need to have an easy and flexible way to control a UAV using such technology. In this study, a remote controller using an iOS device is developed for a quadrotor to enable remote control with easy operations. Four basic programs for obtaining compass information, controlling a gimbal, autopilot function for return, and video preview function are developed and implemented for an iOS device. The basic functionalities of the programs are evaluated and confirmed through experiments using a quadrotor and an iOS device.     

Removal of Interlayer Water of two Ti3C2Tx MXenes as a Versatile Tool for Controlling the Fermi-Level Pinning-Free Schottky Diodes with Nb:SrTiO3

Striving for the sixth-generation communication technology discovery, semiconductors beyond Si with wider bandgaps as well as non-conventional metals are actively being sought to achieve high speeds whilst maintaining devices miniaturization. 2D materials may provide the potential for downsizing, but their functional advantage over existing counterparts still longs to be discovered. Along that path, surface-adsorbed or bulk-intercalated water molecules remaining after wet-chemical synthesis of 2D materials are generally seen as obstacles to high-performance achievement. Herein, the control of such water within the interlayers of solution-processed metallic 2D titanium carbide (MXene) by vacuum annealing duration is demonstrated. Moreover, the impact of water removal on work function (WF) and functional terminations is unveiled for the first time. Furthermore, the usefulness of such water for controlling a novel Schottky diode in contact with an n-type oxide semiconductor, niobium-doped strontium titanate (Nb:SrTiO₃) is observed. The advantage of MXene compared to conventional gold as facile processing, WF tunability, and lower turn-on voltage in the Schottky anode application is highlighted. This fundamental study shows the way for a novel Schottky diode preparation in atmospheric conditions and provides implications for further research directions aiming at commercialization.     

Application of magnetic pulse welding technique for flexible printed circuit boards (FPCB) lap joints

The magnetic pulse welding (MPW) is a high speed solid state welding process which has been used successfully to provide metallurgical and electrical bonds between flexible printed circuit board (FPCB) with using: (1) welding with aluminum driver sheet and (2) without driver sheet. The optimum bank energy for reliable bonding was about 1 kJ with 160–180 kA maximum current. The maximum tensile shearing for most welded samples was nearly same as tensile shearing strength of copper layer of FPCB sheet.     

Do they see eye to eye? Management and employee perspectives of high-performance work systems and influence processes on service quality.

Extant research on high-performance work systems (HPWSs) has primarily examined the effects of HPWSs on establishment or firm-level performance from a management perspective in manufacturing settings. The current study extends this literature by differentiating management and employee perspectives of HPWSs and examining how the two perspectives relate to employee individual performance in the service context. Data collected in three phases from multiple sources involving 292 managers, 830 employees, and 1,772 customers of 91 bank branches revealed significant differences between management and employee perspectives of HPWSs. There were also significant differences in employee perspectives of HPWSs among employees of different employment statuses and among employees of the same status. Further, employee perspective of HPWSs was positively related to individual general service performance through the mediation of employee human capital and perceived organizational support and was positively related to individual knowledge-intensive service performance through the mediation of employee human capital and psychological empowerment. At the same time, management perspective of HPWSs was related to employee human capital and both types of service performance. Finally, a branch's overall knowledge-intensive service performance was positively associated with customer overall satisfaction with the branch's service. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Preparation and dielectric properties of polycrystalline films with dense nano-structured BaTiO3 by chemical vapor deposition using inductively coupled plasma

To clarify the dielectric properties of BaTiO₃ with nanometer size region, it is necessary to fabricate the dense structure composed of BaTiO₃ nanoparticles. In the present study, BaTiO₃ nanoparticles were directly deposited on Pt/Al₂O₃/SiO₂/Si substrate by introducing Ba(DPM)₂ and Ti(OiPr)₄ into an inductively coupled plasma (ICP). The optimal condition for preparing dense structure of BaTiO₃ nanoparticles was investigated by changing the substrate temperature. Single phase BaTiO₃ of perovskite structure was obtained at the substrate temperatures between 773 and 1173 K. The dense structure of BaTiO₃ nanoparticles with particle sizes of about 30 nm was successfully obtained at the substrate temperature of 773 K. At the substrate temperature>873 K, the deposited nanoparticles sintered to be the columnar structure. The ε_r and tan δ of the BaTiO₃ nanoparticles were estimated to be 285 and 6.6%, respectively (1 kHz and 100 mV). The phase of the BaTiO₃ nanoparticles were found to be paraelectric by the measurement of C-V curves. The breakdown field of the dense structure of BaTiO₃ nanoparticles was estimated to be 649 kV/cm according to I-V curves. These features are favorable for applying the structure to the dielectric layer of multilayer capacitors.     

Oral Squamous Cell Carcinoma Contributes to Differentiation of Monocyte-Derived Tumor-Associated Macrophages via PAI-1 and IL-8 Production

Tumor-associated macrophages (TAMs) promote cancer cell proliferation and metastasis, as well as anti-tumor immune suppression. Recent studies have shown that tumors enhance the recruitment and differentiation of TAMs, but the detailed mechanisms have not been clarified. We thus examined the influence of cancer cells on the differentiation of monocytes to TAM subsets, including CD163⁺, CD204⁺, and CD206⁺ cells, in oral squamous cell carcinoma (OSCC) using immunohistochemistry, flow cytometry, and a cytokine array. Furthermore, we investigated the effect of OSCC cells (HSC-2, SQUU-A, and SQUU-B cells) on the differentiation of purified CD14⁺ cells to TAM subsets. The localization patterns of CD163⁺, CD204⁺, and CD206⁺ in OSCC sections were quite different. The expression of CD206 on CD14⁺ cells was significantly increased after the co-culture with OSCC cell lines, while the expressions of CD163 and CD204 on CD14⁺ cells showed no change. High concentrations of plasminogen activator inhibitor-1 (PAI-1) and interleukin-8 (IL-8) were detected in the conditioned medium of OSCC cell lines. PAI-1 and IL-8 stimulated CD14⁺ cells to express CD206. Moreover, there were positive correlations among the numbers of CD206⁺, PAI-1⁺, and IL-8⁺ cells in OSCC sections. These results suggest that PAI-1 and IL-8 produced by OSCC contribute to the differentiation of monocytes to CD206⁺ TAMs.     

Evaluation of energy saving and CO2 emission reduction technologies in energy supply and end‐use sectors using a global energy model

Assessments of global warming mitigation technologies are important for achieving the Kyoto target and planning post‐Kyoto regimes. Regional differences in energy resources, growth in energy consumption, current technology diffusions, etc., should be considered in the assessments. A global energy systems model, DNE21+, with high regional resolution had treated the energy supply sectors in a bottom‐up fashion and the end‐use sectors in a top‐down fashion, which was expressed by using long‐term price elasticity. However, the assessments of technological options in the end‐use sectors are currently more important, particularly for the near and middle terms. In order to evaluate the technological options not only in the energy supply sectors but also in the end‐use sectors for energy savings and CO₂ emission reductions, DNE21+ has been modified for treating two energy‐intensive end‐use sectors, i.e. steel and cement sectors, in the bottom‐up fashion. The results reveal that the cost‐effective global CO₂ emission reductions in 2030 for stabilizing the atmospheric CO₂ concentration at 550 ppmv in comparison with that in the reference case would be approximately 68 MtC/yr and almost zero in the steel and cement sectors, respectively. The cost‐effective options include next‐generation coke ovens and coke dry quenching (CDQ) in the steel sector. Copyright © 2007 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

A solution to SLAM problems by simultaneous estimation of kinematic parameters including sensor mounting offset with an augmented UKF

Accurate localization is required for autonomous robots to navigate in cluttered environments safely. Therefore, Extended Kalman Filter (EKF) and Unscented Kalman Filter (UKF), which incorporate probabilistic concepts as localization methods, have been researched up to now. It should be noted, however, that the errors of kinematic parameters such as wheel diameter, tread, and mounting sensor offset are not enough considered in conventional works. We propose an Augmented UKF-SLAM (AUKF-SLAM), which is an extension of the UKF-SLAM and can estimate the kinematic parameters including a sensor mounting offset together with the localization and mapping. The UKF-SLAM and the AUKF-SLAM are compared through some simulations to show that the proposed AUKF-SLAM is more accurate than the UKF-SLAM. Furthermore, localization experiments with only odometry are conducted using a real robot. The experimental results show to demonstrate that the localization using kinematic parameters estimated by the AUKF-SLAM is more accurate than that using values measured by hand in advance. Through some experimental verifications in an elevator hall, cluttered rooms, and a long distance corridor, it is confirmed that the proposed AUKF-SLAM which simultaneously estimates the effective kinematic parameters largely contributes to the total accuracy improvement of SLAM.     

A Fuzzy Behavior-Based Control for Mobile Robots Using Adaptive Fusion Units

It is known that a behavior-based control approach is effective for acquiring an intelligent control system of robots. However, further improvements are required for making any behavior-based control system robust against changes in the environments. A module learning method has been applied in the framework of fuzzy behavior-based control to have an adaptive behavioral fusion. In this paper, an adaptive fusion strategy is proposed to adaptively select a cooperative fusion unit or competitive fusion unit, depending on the external sensor information. Some simulations are given to illustrate that the present control systems are flexible against the change of environments or untrained environments, compared to those with a conventional priority-based fusion unit.