Analysis of PC6 window function using fractional Fourier transform

Fractional Fourier transform (FRFT) is a linear transform generalizing Fourier transform (FT) that plays an important role in the field of signal processing and analysis. FRFT contains an adjustable parameter α, which it rotates the signal in the time frequency plane and represents the signal in an intermediate domain between time and frequency. FRFT provides a measure about the angular distribution of signal's energy in time frequency plane. FT is a special case of FRFT when angle α is equal to π/2. This paper presents mathematical model for obtaining FRFT of PC6 window function. The different parameters of this window function are also obtained with the help of simulation results. A comparison of window function parameters is presented using FT and FRFT. Also comparison of this window function with Hanning window function is presented in terms of Side Lobe Fall off Rate (SLFOR). For different values of FRFT order, PC6 window function shows variation in different parameters. Thus by changing the FRFT order, the minimum stop band attenuation of the resulting window function can be controlled.     

Influence of samarium doping on the phase stability and optical properties of calcium silicates derived from agro-food wastes

Calcium silicates are very stable and good hosts for luminescent materials. These calcium silicates are synthesized using cost-effective agro-food wastes such as rice husk ash and eggshell powder along with doping of samarium oxide [Ca_3?xSi₂O₇:xSm³⁺(x(%)?=?0.25, 0.50, 0.75, and 1.00)] via solid-state reaction method. X-ray diffraction confirms that the Ca₃Si₂O₇ phase co-exists with the monoclinic-Ca₂SiO₄ phase. An increase in doping concentration of Sm³⁺ enhances the Ca₂SiO₄ phase content. Two types of morphology can be seen in the SEM micrographs confirming the presence of two phases. Photoluminescence emission spectra contain peaks in the visible region. Characteristic emission peaks of Sm³⁺ are present along with strong peaks due to the titanium ions present in agro-food wastes. Commission International de'Eclairage (CIE) co-ordinates correspond to the green region, which is significantly different from the CIE co-ordinates of Sm³⁺ doped samples derived from mineral oxides. This study presents an alternate use of agro-food wastes for synthesizing visible light-emitting phosphors and presents a mechanism for stabilizing Ca₂SiO₄ in waste-derived samples.

     

Adaptive MAC Protocol for Solar Energy Harvesting Based Wireless Sensor Networks in Agriculture

The wireless sensor network is one of the promising technologies in the agriculture field. Its actual usage in real agriculture fields is limited by its dependence on the small batteries which cannot make the network survive for long. Various protocols are being designed at the network and MAC layer to increase the lifetime of the nodes, but up to a certain extent only. Hence the energy harvesting to power up the WSN nodes is a promising technology to fulfill this ever energy demand, but the protocols need to be redesigned for this scenario. Solar energy harvesting based MAC protocol which is adaptive to the changing weather conditions is designed in this paper for the smart agriculture applications. It is based on the multilayer and receiver-initiated process to improve network quality. It has shown the remarkable performance over the other energy harvesting based protocols in terms of ENO ratio, energy consumption and collision rate.

     

Silver Dopant-Induced Effect on Structural and Optoelectronic Properties of CdSe Thin Films

Thin films of CdSe and silver(Ag)-doped CdSe have been prepared on glass substrates by thermal evaporation in argon gas atmosphere. X-ray diffraction pattern indicates the presence of hexagonal structure with preferred orientation along (100) plane. Elemental composition of the thin films has been analyzed using energy dispersive X-ray analysis. Scanning electron microscopy has been used to investigate the morphology of the thin films. Transmission electron microscope reveals spherical nature of nanoparticles. A decrease in the band gap due to the formation of band tails in the band gap with increase in Ag doping in CdSe lattice has been observed. Photoluminescence spectra indicate redshift in band edge emission peak with increase in Ag doping in CdSe. Electrical conductivity measurements are also studied, and two types of conduction mechanisms taking part in the transport phenomena are observed. Hall measurements indicate n-type behavior of undoped and Ag-doped CdSe thin films.     

Nyctanthes arbor‐tristis leaves extract as Antagonizer of immunotoxic effects of chemical pesticides (experimental study)

Increased incidence of immunosuppression due to diseases like AIDS, drug resistant tuberculosis, malaria or exposure to chemicals, calls for general immunopotentiators or anti immunosuppressents. In our previous work while screening the chemical and biopesticides for their immunopotentiating activity, aqueous leaves extract of bio‐pesticidal plant Nyctanthes arbor‐tristis [HL(aq)] was found to be a potent immuno‐modulator. The present study was conducted to evaluate the immunorestorative or anti immunosuppressive activity of the N. arbor‐tristis leaves aqueous extract in the malathion exposed immunosuppressed mice. The immunorestorative potential of HL(aq) was evaluated by studying various immunological parameters (humoral, cell mediated immune, numerical values of immunocytes and functions of phagocytes) in HL(aq) treated or untreated malathion‐exposed mice. The results revealed that the immunological parameters which were suppressed with malathion either reverted back to normal or showed a trend towards normalacy, when treated with HL(aq) extract.     

R Curves and Crack-Stability Map: Application to Ce-TZP/Al2O3

The concept of a crack-stability map is developed by considering the interaction between the crack-driving force and the rising crack-growth resistance of a toughened ceramic. The map plots normalized transition crack length as function of the ratio of the crack-initiation fracture toughness and the plateau toughness to delineate regimes of stable and unstable crack growth. The plot is used to analyze R curves and fracture stresses of a transformation-toughened Ce-TZP/Al₂O₃. It is shown that the fracture stress and the small scatter measured for this ceramic are consistent with its R- curve behavior, which enables stable growth of surface cracks from flaws (pores and second-phase particles), leading to a flaw-insensitive ceramic.     

Photophysical studies of copolymers of N‐vinylcarbazole

The absorption, fluorescence excitation and emission spectroscopy, and time‐dependent spectrofluorimetry have been used to study the photophysics of copolymers of N‐vinylcarbazole with different monomers like vinyl acetate, methyl acrylate, methyl methacrylate, butyl acrylate, and butyl methacrylate in dichloromethane. In all the copolymers and at different N‐vinylcarbazole content, the absorption spectra reflect only the monomer carbazole units. The two kinds of excited monomer species of N‐vinylcarbazole are present in S₁ state. Short‐lived (～3 ns) excited monomer decays forming low energy excimer obtained by the complete overlap of the excited carbazole monomer. The long‐lived excited monomer (～8 ns) decays to ground state without formation of any excimer. The high energy excimer is relatively short‐lived and is formed by the partial overlap of the carbazole units. The presence of bulky group in the copolymer chain hinders the formation of excimers. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 372–380, 2006     

Low frequency ac conduction and dielectric relaxation behavior of solution grown and uniaxially stretched poly(vinylidene fluoride) films

The measurements of ac conductivity [σ_m(ω)], dielectric constant [?′(ω)] and loss [?″(ω)] have been performed on solution grown (thickness ∼85 μm) and uniaxially stretched (thickness ∼25, 45 and 80 μm) films of poly(vinylidene fluoride) (PVDF) in the frequency range 0.1 kHz-10 MHz and in the temperature range 77-400 K. The σ_m(ω) can be described by the relation σ(ω) = Aω^s, where s is close to unity and decreases with increase in temperature. Three relaxations, observed in the present investigation, have been designated as the α_c-, the α_a- and the β-relaxations appearing from high temperature side to the low temperature side. The α_c-relaxation could not be observed in the case of uniaxially stretched poly(vinylidene fluoride) films. The α_c- and α_a-relaxations are associated with the molecular motions in the crystalline regions and micro-Brownian motion in the amorphous regions of the main polymer chain, respectively, whereas the β-relaxation is attributed to the rotation of side group dipoles or to the local oscillations of the frozen main polymer chain.