Anomalous off-current mechanisms in N-channel poly-Si thin film transistors

The anomalous off-current (I_off) in polysilicon thin film transistors (polysilicon TFTs) is one of the major problems preventing a wide use of these devices in active matrix liquid crystal displays. While previous investigations have focused on the temperature range above 300 K, in this study we have investigated the behaviour of I_off over a wide range of temperatures, namely 180–400 K. The data have been analysed by combining 2D simulations and existing analytic models. By this approach we have identified a pure trap-to-band tunnelling mechanism in polysilicon TFTs and deduced, by a simple procedure, the physical constants. The temperature and bias dependence of the off-current has been explained quantitatively in terms of phonon-assisted tunnelling. The number of generating centres, the dominant trap energy and the thermal capture cross section are deduced from this analysis.     

Improved safety and efficacy in adaptive control of arterial bloodpressure through the use of a supervisor

A dual approach to adaptive control of arterial blood pressure using sodium nitroprusside is presented. In the clinical environment, a controller must be aggressive to achieve specific step response characteristics (less than 10 min setting time, less than 10 mm Hg overshoot), yet conservative enough to prevent overreactions to large disturbances, which are common in both the operating room and the intensive care unit. These mutually exclusive requirements make it difficult to design a closed-loop controller for this environment. To prevent possible overreactions while maintaining proper step response, an aggressive adaptive controller has been designed to achieve the desired step response, and a supervisor has been designed around the adaptive controller to limit potential overreactions in the presence of disturbances. Simulations and dog experiments demonstrate the potential for increased safety and efficacy using this dual approach to the control of a complex physiological system     

Temperature effects on trigate SOI MOSFETs

Trigate silicon-on-insulator (SOI) MOSFETs have been measured in the 5-400 K temperature range. The device fin width and height is 45 and 82 nm, respectively, and the p-type doping concentration in the channel is 6/spl times/10/sup 17/ cm/sup -3/. The subthreshold slope varies linearly with temperature as predicted by fully depleted SOI MOS theory. The mobility is phonon limited for temperatures larger than 100 K, while it is limited by surface roughness below that temperature. The corner effect, in which the device corners have a lower threshold voltage than the top and sidewall Si/SiO/sub 2/ interfaces, shows up at temperatures lower than 150 K.     

Varietal Differentiation of Grape Juice Based on the Analysis of Near- and Mid-infrared Spectral Data

The aim of this study was to evaluate the usefulness of visible (VIS), near-infrared reflectance (NIR) and mid-infrared (MIR) spectroscopy combined with pattern recognition methods as tools to differentiate grape juice samples from commercial Australian Chardonnay (n = 121) and Riesling (n = 91) varieties. Principal component analysis (PCA), partial least squares discriminant analysis and linear discriminant analysis (LDA) were applied to classified grape juice samples according to variety based on both NIR and MIR spectra using full cross-validation (leave-one-out) as a validation method. Overall, LDA models correctly classify 86% and 80% of the grape juice samples according to variety using MIR and VIS-NIR, respectively. The results from this study demonstrated that spectral differences exist between the juice samples from different varietal origins and confirmed that the infrared (IR) spectrum contains information able to discriminate among samples. Furthermore, analysis and interpretation of the eigenvectors from the PCA models developed verified that the IR spectrum of the grape juice has enough information to allow the prediction of the variety. These results also suggested that IR spectroscopy coupled with pattern recognition methods holds the necessary information for a successful classification of juice samples of different varieties.     

ACE-Asia intercomparison of a thermal-optical method for the determination of particle-phase organic and elemental carbon

A laboratory intercomparison of organic carbon (OC) and elemental carbon (EC) measurements of atmospheric particulate matter samples collected on quartz filters was conducted among eight participants of the ACE-Asia field experiment The intercomparison took place in two stages: the first round of the intercomparison was conducted when filter samples collected during the ACE-Asia experiment were being analyzed for OC and EC, and the second round was conducted after the ACE-Asia experiment and included selected samples from the ACE-Asia experiment Each participant operated ECOC analyzers from the same manufacturer and utilized the same analysis protocol for their measurements. The precision of OC measurements of quartz fiber filters was a function of the filter's carbon loading but was found to be in the range of 4-13% for OC loadings of 1.0-25 microg of C cm(-2). For measurements of EC, the precision was found to be in the range of 6-21% for EC loadings in the range of 0.7-8.4 microg of C cm(-2). It was demonstrated for three ambient samples, four source samples, and three complex mixtures of organic compounds that the relative amount of total evolved carbon allocated as OC and EC (i.e., the ECOC split) is sensitive to the temperature program used for analysis, and the magnitude of the sensitivity is dependent on the types of aerosol particles collected. The fraction of elemental carbon measured in wood smoke and an extract of organic compounds from a wood smoke sample were sensitive to the temperature program used for the ECOC analysis. The ECOC split for the three ambient samples and a coal fly ash sample showed moderate sensitivity to temperature program, while a carbon black sample and a sample of secondary organic aerosol were measured to have the same split of OC and EC with all temperature programs that were examined.     

Single nanoskived nanowires for electrochemical applications

In this work, we fabricate gold nanowires with well controlled critical dimensions using a recently demonstrated facile approach termed nanoskiving. Nanowires are fabricated with lengths of several hundreds of micrometers and are easily electrically contacted using overlay electrodes. Following fabrication, nanowire device performance is assessed using both electrical and electrochemical characterization techniques. We observe low electrical resistances with typical linear Ohmic responses from fully packaged nanowire devices. Steady-state cyclic voltammograms in ferrocenemonocarboxylic acid demonstrate scan rate independence up to 1000 mV s(-1). Electrochemical responses are excellently described by classical Butler-Volmer kinetics, displaying a fast, heterogeneous electron transfer kinetics, k(0) = 2.27 ± 0.02 cm s(-1), α = 0.4 ± 0.01. Direct reduction of hydrogen peroxide is observed at nanowires across the 110 pM to 1 mM concentration range, without the need for chemical modification, demonstrating the potential of these devices for electrochemical applications.     

The purification and specificity of a lipase fromVernonia anthelmintica seed

Acetone powders prepared fromVernonia anthelmintica seed catalyzed the release of 6.4 to 9.6 μ-moles of free fatty acids per milligram of protein when blended with olive oil and phosphate buffer and shaken for 20 min at 43 C. A 20 fold purification was achieved by differential centrifugation of an ammonium hydroxide extract of the acetone powder. Results from Sephadex G-200 chromatography and polyacrylamide gel electrophoresis suggested that the lipase activity was associated with a molecule of molecular weight greater than 200,000. Free fatty acids, 1,2- and 1,3-diglycerides, monoglycerides and glycerol were found in the digestion products. With most substrates the 1,2-to 1,3-diglyceride ratio was approximately 2∶1 and monoglycerides tended to accumulate. Analysis of the digestion products from synthetic triglycerides of known structure indicated that both primary and secondary ester positions of the triglyceride molecule were hydrolyzed and that considerable isomerization of 1,2-diglyceride to 1,3-diglyceride occurred. The monoglyceride was consistently lower than the 1,2-diglyceride and in the majority of cases also lower than the 1,3-diglyceride in the fatty acid originally present in the 2 position of the triglyceride. No fatty acid preference was observed. Scientific contribution No. 316. Presented in part at the AOCS Meeting, Philadelphia, October 1966.     

THE ESTIMATION OF RANDOM COEFFICIENT AUTOGRESSIVE MODELS. II

Abstract. In Nicholls and Quinn (1980) a procedure was proposed for the determination of strongly consistent estimates of random coefficient autoregressive models. These estimates are used here as starting values in a Newton-Raphson algorithm which is employed to obtain the maximum likelihood estimates of a class of random coefficient autoregressions. The maximum likelihood estimates are shown to be strongly consistent and to satisfy a central limit theorem. The problem of testing for the randomness of the coefficients is also briefly discussed. The results of a number of simulations are reported which illustrate the theoretical results obtained.     

Continuous ion exchange using magnetic shell resins. II. Dealkalisation—pilot plant study

From the results obtained in the treatment of a number of hard, alkaline feed waters in a pilot scale dealkalisation plant, it has been shown that the use of a magnetic carboxylic acid resin in a fluidised bed has definite advantages over conventional systems. Less resin is needed and simpler plants can handle the same throughput of raw water whilst maintaining the same quality of product. Plant operation is truely continuous without any complex valve system or pressurised vessels.