Selectivity Enhancement to the Exclusive Formation of Ethyltoluenes and Hydrogen During Dehydroalkylation of Toluene with Ethane

The dehydroalkylation of toluene with ethane to the isomeric ethyltoluenes was studied on 0.4Pt/H-ZSM-5 at varying contact times (1/WHSV). At a high contact time of 1.0 h, toluene disproportionation and hydrogenolysis reactions dominate, resulting in low selectivity to the desired ethyltoluenes via the alkylation reaction. However, at a low contact time of 0.12 h side reactions are eliminated, resulting in maximum selectivities to the kinetically favored ethyltoluenes and hydrogen. Results at high selectivities to ethyltoluenes provide significant insight into reaction pathways.     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

Thermodynamic studies on the complete phase diagram of aqueous two phase system containing polyethylene glycol dimethyl ether 2000 and di-potassium hydrogen phosphate at different temperatures

The liquid-liquid equilibrium of polyethylene glycol dimethyl ether 2000 (PEGDME₂₀₀₀)+K₂HPO₄+H₂O system has been determined experimentally at T=(298.15,303.15,308.15 and 318.15) K. The liquid-solid and complete phase diagram of this system was also obtained at T=(298.15 and 308.15) K. A nonlinear temperature dependent equation was successfully used for the correlation of the experimental binodal data. Furthermore, a temperature dependent Setschenow-type equation was successfully used for the correlation of the tie-lines of the studied system. Moreover, the effect of temperature on the binodal curves and the tie-lines for the investigated aqueous two-phase system have been studied. Also, the free energies of cloud points for this system and some previously studied systems containing PEGDME₂₀₀₀ were calculated from which it was concluded that the increase of the entropy is the driving force for formation of aqueous two-phase systems. Additionally, the calculated free energies for phase separation of the studied systems were used to investigate the salting-out ability of the salts having different anions. Furthermore, the complete phase diagram of the investigated system was compared with the corresponding phase diagrams of previously studied systems, in which the PEGDME₂₀₀₀ has been used, in order to obtain some information regarding the phase behavior of these PEGDME₂₀₀₀+salt+water systems.     

Application of ion-engineered Persian Gulf seawater in EOR:effects of different ions on interfacial tension,contact angle,zeta potential,and oil recovery

In this study,we initially performed interfacial tension(IFT)tests to investigate the potential of using the Persian Gulf sea-water(PGSW)as smart water with dif...     

FQL‐RED: an adaptive scalable schema for active queue management

In a potentially congested network, random early detection (RED) active queue management (AQM) proved effective in improving throughput and average queuing delay. The main disadvantage of RED is its sensitive parameters that are impossible to estimate perfectly and adjust manually because of the dynamic nature of the network. For this reason, RED performs differently during different phases of a scenario and there is no guarantee that it will have optimal performance. Giving adaptability to RED has been the subject of broad research studies ever since RED was proposed. After a substantial study of AQM schemes and presenting a novel categorization for so‐called modern approaches utilizing artificial intelligence tools to improve AQM, this paper proposes an algorithm enhancing RED as an add‐on patch that makes minimal changes to the original RED. Being built on the basis of AQM schemes like ARED and Fuzzy‐RED, this algorithm inherits adaptability and is able to adjust RED inaccurate parameters regarding network traffic status, trying to optimize throughput and average queuing delay in a scenario. This algorithm is a Q‐learning method enhanced with a fuzzy inference system to provide RED with self‐adaptation and improved performance as a result. Given the name of FQL‐RED, this algorithm outperformed RED, ARED, and Fuzzy‐RED, as the OPNET simulations show. Copyright © 2010 John Wiley & Sons, Ltd.     

Dependability evaluation of Altera FPGA-based embedded systems subjected to SEUs

Dependability evaluation of embedded systems due to the integration of hardware and software parts is difficult to analyze. In this paper, we have proposed an experimental method to determine sensitivity to soft errors in an embedded system exploiting Altera SRAM-based FPGAs. The evaluation is performed using both the hardware and software parts of the embedded system in a single framework. To do this, the HDL hardware model of the target system as well as the C-written software codes of the target system, are required. Both permanent and transient faults are injected into the partially- or fully-synthesizable hardware of the target system and this can be performed during the design cycle of the system. The fault injection is composed of injecting SEUs into user design memory, and used configuration memory of the exploited FPGA. Using the experimental results, the sensitivity of Altera FPGAs to SEU faults are analyzed and derived. The analytical results reveal that the configuration memory is more significant than design memory to the SEUs due to the relative number of SRAM bits. Moreover, in this framework, in the case of injecting SEUs into user memory, the fault injection experiments are accelerated by the cooperation between a simulator and the FPGA.     

J‐divergence‐based Power Allocation in Wireless Sensor Networks with Distributed Detection under Correlated Noises

In this paper, the power allocation problem in a wireless sensor network (WSN) with binary distributed detection is considered. It is assumed that the sensors independently transmit their local decisions to a fusion center (FC) through a slow fading orthogonal multiple access channel (OMAC), where, in every channel, the interferences from other devices are considered as correlated noises. In this channel, the associated power allocation optimization problem with equal power constraint is established between statistical distributions under different hypotheses by using the Jeffrey divergence (J‐divergence) as a performance criterion. It is shown that this criterion for the power allocation problem is more efficient compared to other criteria such as mean square error (MSE). Moreover, several numerical simulations and examples are presented to illustrate the effectiveness of the proposed approach.