Interlayer Engineering of Molybdenum Trioxide toward High‐Capacity and Stable Sodium Ion Half/Full Batteries

Orthorhombic molybdenum trioxide (MoO₃) is one of the most promising anode materials for sodium‐ion batteries because of its rich chemistry associated with multiple valence states and intriguing layered structure. However, MoO₃ still suffers from the low rate capability and poor cycle induced by pulverization during de/sodiation. An ingenious two‐step synthesis strategy to fine tune the layer structure of MoO₃ targeting stable and fast sodium ionic diffusion channels is reported here. By integrating partially reduction and organic molecule intercalation methodologies, the interlayer spacing of MoO₃ is remarkably enlarged to 10.40 Å and the layer structural integration are reinforced by dimercapto groups of bismuththiol molecules. Comprehensive characterizations and density functional theory calculations prove that the intercalated bismuththiol (DMcT) molecules substantially enhanced electronic conductivity and effectively shield the electrostatic interaction between Na⁺ and the MoO₃ host by conjugated double bond, resulting in improved Na⁺ insertion/extraction kinetics. Benefiting from these features, the newly devised layered MoO₃ electrode achieves excellent long‐term cycling stability and outstanding rate performance. These achievements are of vital significance for the preparation of sodium‐ion battery anode materials with high‐rate capability and long cycling life using intercalation chemistry.     

Supramolecular Glyco‐nanoparticles Toward Immunological Applications

Glyco‐mimicking nanoparticles (glyco‐NPs) with Förster resonance energy transfer (FRET) donor and acceptor groups formed via dynamic covalent bond of benzoboroxole and sugar from two complementary polymers are prepared. The glyco‐NPs are proved to be quite stable under physiological conditions but sensitive to pH. So the glyco‐NPs can be internalized by dendritic cells with integrity and nontoxicity and then dissociate within the acidic organelles. This particle dissociation is directly observed and visualized in vitro, for the first time via the FRET measurements and fluorescent microscopy. This feature makes controlled release of drug or protein by glyco‐NPs possible, i.e., when model antigen Ovalbumin is loaded in the glyco‐NPs, the released Ovalbumin in dendritic cells stimulates T cells more efficiently than the free Ovalbumin itself as a result of the enhanced antigen processing and presentation. Thus, the results enlighten a bright future of the glyco‐NPs in immunotherapy.     

多功能半导体激光医疗仪电源的研制

根据“多功能半导体激光医疗仪”整机的要求,采用同一电源对667nm和808nm半导体激光器实施供电。为避免电源在开、关机时对半导体激光管产生浪涌冲击,电源在设计中采用了适当的逻辑功能。并可保证对667nm激光器供电时,即使打开808nm激光器供电开关,也不对808nm半导体激光器供电,反之亦然。电源设有手动、计算机两种控制方法,及恒定功率、电流两种工作方式。     

关于加强财务管理,提高经济效益的思考

随着我国经济改革的不断深入,我局的经济工作也从单一的地质勘查向经济多元化方面发展,并且取得了可喜的成果,仅去年我局的多经产值就上亿元,经济规模比上世纪末又上了一个台阶.但我们同时又看到,经济规模虽已扩大,而效益却不尽如人意,虽有利润但微乎其微,有些甚至出现负数.是什么原因使之我们的经济状况总是停留在维持简单再生产上呢？其中原因虽有客观上的,比如：承揽的工程项目单价太低,业务量不饱满,安置人员任务较重等等.但主观原因我认为我们的成本管理还是不到位,“跑、冒、滴、漏”现象严重,这就给我们的财务管理提出了一个严竣的问题,财务应如何管理才能为经济效益的提高发挥其作用呢？我想就这个问题谈谈自己的一些看法和想法.     

Efficient Skyline and Top-k Retrieval in Subspaces

Skyline and top-k queries are two popular operations for preference retrieval. In practice, applications that require these operations usually provide numerous candidate attributes, whereas, depending on their interests, users may issue queries regarding different subsets of the dimensions. The existing algorithms are inadequate for subspace skyline/top-k search because they have at least one of the following defects: 1) they require scanning the entire database at least once, 2) they are optimized for one subspace but incur significant overhead for other subspaces, or 3) they demand expensive maintenance cost or space consumption. In this paper, we propose a technique SUBSKY, which settles both types of queries by using purely relational technologies. The core of SUBSKY is a transformation that converts multidimensional data to one-dimensional (1D) values. These values are indexed by a simple B-tree, which allows us to answer subspace queries by accessing a fraction of the database. SUBSKY entails low maintenance overhead, which equals the cost of updating a traditional B-tree. Extensive experiments with real data confirm that our technique outperforms alternative solutions significantly in both efficiency and scalability.     

一种基于EPID的安全OA系统

文章对OA系统中存在的安全问题进行了讨论,引人了一种新的基于远程匿名身份认证EPID模式,它能通过保存设备拥有者私密信息的硬件设施进行身份鉴定。一个嵌入EPID私密的硬件设备可以向远程机构证实它的有效性,而不必暴露自己的身份和其他私密信息。可以撤消一个签名的EPID私钥,即使不知道密钥的身份。同时,把EPID和其它的一些方法进行了对比。     

小型储气罐火灾工况数值模拟分析

以某输气管线气液联动执行机构中的储气罐为例,利用Ansys Fluent软件建立同比例三维模型,模拟火灾工况下,外部热量不断输入,罐内压力和罐体温度随时间的变化情况。利用Aspen Hysys软件模拟计算该小型储气罐在火灾工况下安全泄放所需的最小安全阀口径。结果表明,当钢制储气罐外部发生火灾时,罐体温度和罐内压力急剧升高,在很短的时间内就能达到储气罐坍塌温度和储气罐设计压力;达到钢制储气罐坍塌温度的时间滞后于达到储气罐设计压力的时间;从安全的角度,设置安全阀可安全有效泄放气体,即使储气罐发生坍塌,也有助于降低事故发生的危害程度;确定的安全阀最小口径为0.03 cm²,建议选型的安全阀口径不低于0.05 cm²。     

Photocatalytic syngas synthesis from CO2 and H2O using ultrafine CeO2-decorated layered double hydroxide nanosheets under visible-light up to 600 nm

The rational design of photocatalyst that can effectively reduce CO₂ under visible light(l>400 nm),and simultaneously precise control of the products syngas(CO/H2)ratio is highly desirable for the Fischer-Tropsch reaction.In this work,we synthesized a series of CeO₂-decorated layered double hydroxides(LDHs,Ce-x)samples for photocatalytic CO₂ reduction.It was found that the selectivity and productivity of CO and H₂ from photoreduction of CO₂ in conjunction with Ru-complex as photosensitizer performed an obvious“volcano-like”trend,with the highest point at Ce-0.15 and the CO/H₂ ratio can be widely tunable from 1/7.7 to 1/1.3.Furthermore,compared with LDH,Ce-0.15 also drove photocatalytic CO₂ to syngas under 600 nm irradiation.It implied that an optimum amount of CeO₂ modifying LDH promoted the photoreduction of CO₂ to syngas.This report gives the way to fully utilize the rare earth elements and provides a promising route to enhance the photo-response ability and charge injection efficiency of LDH-based photocatalysts in the synthesis of syngas with a tunable ratio under visible light irradiation.     

不同类型避雷针雷击接闪效能差异的实验评价方法

探讨一种直观、易于理解且反映雷击放电机理的实验方法,以评价不同类型避雷针的雷击接闪效能差异,对雷电防护领域形成共识显得尤为重要.为此,论文首先分析了雷电环境下地面目标物上避雷针的雷击接闪过程,指出不同类型避雷针接闪效能的差异主要体现在对迎面放电过程的影响上;接着,提出了如下实验评价方法:采用针-板间隙的放电实验布置,对4m及以上间隙施加1.2/50μs标准雷电波模拟迎面流注放电过程,对6m及以上间隙施加250/2500μs标准操作波模拟迎面先导放电过程;然后,通过比较非传统避雷针与传统避雷针的放电起始时刻与平均发展速度2个指标,以评价不同类型针的接闪效能差异;最后,利用所提方法对典型提前放电(early streamer emission,ESE)非传统避雷针与传统避雷针开展了接闪效能差异的评价实验.实验结果表明:ESE针与传统避雷针的评价指标基本一致,不具备研发商所宣称的引雷增效作用.