Conducting composites of polythiophene and polyfuran with acetylene black

Conducting composites of polythiophene (PTP) and polyfuran (PF) with acetylene black (AB) were prepared via chemical oxidative polymerization of thiophene and furan in a suspension of AB in CHCl₃ at room temperature using anhydrous FeCl₃ as the oxidant. Formation of PTP and PF and their subsequent incorporation in PTP–AB and PF–AB composite systems were confirmed by FTIR analysis. Scanning electron microscope analysis showed the presence of compact clusters of particles in both composites. Transmission electron micrographs of PTP–AB and PF–AB composites showed formation of globular polymer encapsulated AB particles with average diameters of the order of ～100 nm in both systems. Thermogravimetric analysis revealed that the overall thermal stability varied in the order: AB > PTP–AB > PTP and AB > PF–AB > PF. DC conductivity values for the PTP–AB and PF–AB composites were of the order of 10^?2 and 10^?3 S cm^?1, respectively. Copyright © 2004 Society of Chemical Industry     

Initiation of air core in a swirl nozzle using time-independent power-law fluids

Summary Theoretical and experimental analyses have been carried out for determining the injection condition below which the formation of air core does not take place in the course of flow of a time-independent power-law fluid through a swirl nozzle. Analytical solution lends one distinct value of generalized Reynolds number at the inlet to a nozzle below which the air core is not formed. Experiments reveal that there exist two limiting values of such generalized Reynolds number regarding the formation of air core in a nozzle. One value being the upper limit below which steady flow occurs without air core, the other one is the lower limit above which steady flow with fully developed air core persists. In between these two limiting values, there prevails a transition zone through which fully developed air core is set up within the nozzle. For all the nozzles, theoretical results are in fair agreement with the experimental values of upper limit of generalized Reynolds numbers with respect to steady flow without air core. Amongst all the pertinent independent geometrical parameters of a nozzle, the orifice-to-swirl chamber-diameter ratio has the remarkable influence on generalized Reynolds number describing the initiation of air core.Nomenclature D ₁ Swirl chamber diameter - D ₂ Orifice diameter - D _s Diameter of tangential entry ports - E A non-dimensional parameter defined by Eq. (9) - E _R A non-dimensional parameter defined by Eq. (25) - K Flow consistency index - L ₁ Length of the swirl chamber - n Flow behaviour index - P Static pressure inside the nozzle - P _b Back-pressure of the nozzle - Q Volume flow rate - R Radius vector or longitudinal coordinate with respect to spherical coordinate system (Fig. 3) - R ₁ Radius of the swirl chamber - R ₂ Radius of the orifice - Generalized Reynolds number at the inlet to the nozzle - Limiting value of generalized Reynolds number describing initiation of air core - R _z Radius at any section - r Radial distance from the nozzle axis - r _a Air core radius - u Longitudinal component of velocity with respect to spherical coordinate system (Fig. 3) - V _r Radial velocity component - V _z Axial velocity component - V Tangential velocity component - Tangential velocity at inlet to the nozzle - v Component of velocity in the axial plane perpendicular toR (Fig. 3) - w Component of velocity perpendicular to axial plane with respect to the spherical coordinate system (Fig. 3) - z Distance along the nozzle axis from its inlet plane - Half of the spin chamber angle - Boundary layer thickness measured perpendicularly from the nozzle wall - ₂ Boundary layer thickness at the orifice - Angle, which a radius vector makes with the nozzle axis, in spherical coordinate system (Fig. 3) - Density of the fluid - Running coordinate in the azimuthal direction with respect to the cylindrical polar coordinate system as shown in Fig. 3 - Circulation constant With 8 Figures     

Electrical properties of vanadium pentoxide doped with lithium and sodium in the α-phase range

The electrical conductivity and Seebeck coefficients have been measured from room temperature to 500° C for polycrystalline V₂O₅ and V₂O₅ doped with lithium and sodium in the -phase range. The conductivity increases with doping and the energy of activation decreases. The Seebeck coefficient indicates that electrons are the majority carriers. The results have been discussed in terms of the two-level hopping model.     

The cluster scanning system

Users with severe physical impairment often use computers with one or two switches using a scanning system. Scanning is a technique of successively highlighting portions of screen. This paper presents a new scanning system that works through clustering screen objects. The system is initially calibrated through simulation and later validated through a user trial. Results show that it outperforms existing block scanning systems.     

Effect of dysprosia doping on structural and electrical property of stabilized zirconia for intermediate- temperature SOFCs

Present work deals with structural, micro-structural and electrical properties of dysprosia stabilized zirconia electrolyte, which have been evaluated by means of X-ray diffraction (XRD) and scanning (SEM), and complex impedance analysis respectively. The amount of dysprosia was varied from 2 to 12 mol% in zirconia. The addition of dysprosia (8-12 mol%) stabilized the cubic zirconia phase, which was analyzed from XRD analysis. SEM micrographs clearly showed the improvement in sinterability with increase in dysprosia concentration up to 6 mol% disprosia. Complex impedance analysis was performed in the temperature range from 250 to 600 °C. The results indicated a gradual decrease in impedance of both bulk and grain boundary and increase in conductivity with dysprosia doping up to 6 mol% and thereafter showing a reverse trend. The activation energies for oxygen ion migration were also found to decrease with increase in dysprosia doping which was in the range of 0.99 ? 1.28 eV. The average thermal expansion coefficient increases linearly.     

Multiple material domain‐based computational tools for ease assessment of modal parameter in photonic crystal fibers

We report here the development of two computational tools PCFPS (Photonic Crystal Fiber Parameter Study) and PCFPA (Photonic Crystal Fiber Parameter Analysis), equipped with graphical user interface (GUI) for modeling of photonic crystal fiber. The tools are based on different structural parameters, and they provide characteristic analysis of the modal parameters from the structural parameters. The main feature of PCFPS is that it enables the user to find out the values of each defining modal parameter that has an immense contribution towards the manufacture of photonic crystal fiber. Additionally, PCFPA allows the user to observe the variation in the modal parameters with respect to the changes in structural parameters (such as d, Λ, d/Λ, and λ/>Λ). Besides their ease of use, these two schemes have high computational precision and adaptability, giving a novel platform to optical engineers to modulate the microstructured fibers according to their requirement.     

CNS: a new energy efficient transmission scheme for wireless sensor networks

We present in this paper a new energy-efficient communication scheme called CNS (Compression with Null Symbol) that combines the power of data compression and communication through silent symbol. The concept of communication through silent symbol is borrowed from the energy efficient schemes proposed in Sinha (Proceedings of 6th IEEE consumer communications and networking conference (CCNC), Las Vegas, pp. 1–5, 2009), Ghosh et al. (Proceedings of 27th IEEE international performance computing and communications conference (IPCCC), USA, pp. 85–92, 2008), and Sinha and Sinha (Proceedings of international conference on distributed computing and internet technologies (ICDCIT), LNCS, pp. 139–144, 2008). We show that the average theoretical energy saving at the transmitter by CNS is 62.5%, assuming an ideal channel and for equal likelihood of all possible binary strings of a given length. Next, we propose a transceiver design that uses a hybrid modulation scheme utilizing FSK and ASK so as to keep the cost/complexity of the radio devices low. Considering an additive white gaussian noise (AWGN) channel and a non-coherent detection based receiver, CNS shows a saving in transmitter energy by 30% when compared to binary FSK, for equal likelihood of all possible binary strings of a given length. Simultaneously, there is a saving of 50% at the receiver for all types of data modulation due to halving of the transmitted data duration, compared to binary encoding. In contrast, RBNSiZeComm proposed in Sinha (Proceedings of 6th IEEE consumer communications and networking conference (CCNC), Las Vegas, pp. 1–5, 2009), TSS proposed in Ghosh et al. (Proceedings of 27th IEEE international performance computing and communications conference (IPCCC), USA, pp. 85–92, 2008) and RZE proposed in Sinha and Sinha (Proceedings of international conference on distributed computing and internet technologies (ICDCIT), LNCS, pp. 139–144, 2008) generate average transmitter energy savings of about 41, 20, and 35.2%, respectively. Also, at the receiver side, while RBNSiZeComm does not generate any saving, TSS and RZE produce about 36.9 and 12.5% savings on an average, respectively. Considering certain data types that may occur in the context of some wireless sensor networks (WSN) based applications (e.g., remote healthcare, agricultural WSNs, etc.), our simulation results demonstrate that for AWGN noisy channels, the transmitter side savings vary from about 33–50% on an average, while for RBNSiZeComm, this saving is about 33–61% on the same data set (Sinha in Proceedings of 6th IEEE consumer communications and networking conference (CCNC), Las Vegas, pp. 1–5, 2009). Thus, taking into account the low cost/complexity of the proposed transceiver, these results clearly establish that CNS can be a suitable candidate for communication in low power wireless sensor networks, such as in remote healthcare applications, body area networks, home automation, WSNs for agriculture and many others.     

Attribute Allocation and Retrieval Scheme for Large-Scale Sensor Networks

Wireless sensor network is an emerging technology that enables remote monitoring of large geographical regions. In this paper, we address the problem of distributing attributes over such a large-scale sensor network so that the cost of data retrieval is minimized. The proposed scheme is a data-centric storage scheme where the attributes are distributed over the network depending on the correlations between them. The problem addressed here is similar to the Allocation Problem of distributed databases. In this paper, we have defined the Allocation Problem in the context of sensor networks and have proposed a scheme for finding a good distribution of attributes to the sensor network. We also propose an architecture for query processing given such a distribution of attributes. We analytically determine the conditions under which the proposed architecture is beneficial and present simulation results to demonstrate the same. To the best of our knowledge, this is the first attempt to determine an allocation of attributes over a sensor network based on the correlations between attributes.     

In-Flight Synthesis of Core–Shell Mg/Si–SiOx Particles with Greatly Reduced Ignition Temperature

Magnesium is a promising candidate as a solid fuel for energetic applications, however, the diffusion-controlled oxidation mechanism impedes its reaction with an oxidizer, often resulting in diminished performance. In this study, non-thermal plasma processing is implemented to modify the surface of magnesium nanoparticles with silicon in-flight, in the gas-phase to enhance the rate of interfacial reactions and tune the ignition pathways. Allowing the silicon coating to partially oxidize provides direct contact between the fuel and oxidizer, resulting in a nanostructured thermite system at the single particle level. The proximal distance between oxidizer and fuel directly impacts the ignition temperature and, therefore, the combustion kinetics. An intermetallic reaction occurs within the magnesium/silicon system to supplement the heating of the magnesium fuel to initiate its reaction with the oxidizer, resulting in highly reduced ignition thresholds. The ignition temperature is lowered significantly from ≈740 °C for magnesium particles with a native oxide layer to ≈520 °C for particles coated via the in-flight plasma process.