An investigation into physicochemical characteristics of ash produced from combustion of oil palm biomass wastein a boiler

Ash derived from combustion of Malaysian oil palm biomass (empty fruit bunches consisting of fibers) was physically and chemically characterized in order to provide a comprehensive understanding of its specific properties in terms of toxicity, compositions and reusability. Principal analyses conducted include particle size distribution, scanning electron microscopy, elemental dispersive X-ray, elemental analysis, toxicity characteristic leaching procedure (TCLP) as well as thermogravimetric, X-ray diffractometry and Fourier-transform infrared analyses. TCLP result indicated that the oil palm ash (OPA) should not be classified as toxic wastes in terms of heavy metal leachability since leachable copper, cadmium, lead and nickel concentrations were detected below the stipulated leachability limits. It was determined that the OPA contained high amount of potassium as well as presence of silica which implied its suitability to be reused as crude fertilizer or cement replacement material.     

An improved formalism for quantum computation based on geometric algebra—case study: Grover’s search algorithm

The Grover search algorithm is one of the two key algorithms in the field of quantum computing, and hence it is desirable to represent it in the simplest and most intuitive formalism possible. We show firstly, that Clifford’s geometric algebra, provides a significantly simpler representation than the conventional bra-ket notation, and secondly, that the basis defined by the states of maximum and minimum weight in the Grover search space, allows a simple visualization of the Grover search analogous to the precession of a spin- ${\frac{1}{2}}$ particle. Using this formalism we efficiently solve the exact search problem, as well as easily representing more general search situations. We do not claim the development of an improved algorithm, but show in a tutorial paper that geometric algebra provides extremely compact and elegant expressions with improved clarity for the Grover search algorithm. Being a key algorithm in quantum computing and one of the most studied, it forms an ideal basis for a tutorial on how to elucidate quantum operations in terms of geometric algebra—this is then of interest in extending the applicability of geometric algebra to more complicated problems in fields of quantum computing, quantum decision theory, and quantum information.     

Local calibration of rigid pavement performance models using resampling methods

The performance prediction models in the Pavement-ME design software are nationally calibrated using in-service pavement material properties, pavement structure, climate and truck loadings, and performance data obtained from the Long-Term Pavement Performance programme. The nationally calibrated models may not perform well if the inputs and performance data used to calibrate those do not represent the local design and construction practices. Therefore, before implementing the new M-E design procedure, each state highway agency (SHA) should evaluate how well the nationally calibrated performance models predict the measured field performance. The local calibrations of the Pavement-ME performance models are recommended to improve the performance prediction capabilities to reflect the unique conditions and design practices. During the local calibration process, the traditional calibration techniques (split sampling) may not necessarily provide adequate results when limited number of pavement sections are available. Consequently, there is a need to employ statistical and resampling methodologies that are more efficient and robust for model calibrations given the data related challenges encountered by SHAs. The main objectives of the paper are to demonstrate the local calibration of rigid pavement performance models and compare the calibration results based on different resampling techniques. The bootstrap is a non-parametric and robust resampling technique for estimating standard errors and confidence intervals of a statistic. The main advantage of bootstrapping is that model parameters estimation is possible without making distribution assumptions. This paper presents the use of bootstrapping and jackknifing to locally calibrate the transverse cracking and IRI performance models for newly constructed and rehabilitated rigid pavements. The results of the calibration show that the standard error of estimate and bias are lower compared to the traditional sampling methods. In addition, the validation statistics are similar to that of the locally calibrated model, especially for the IRI model, which indicates robustness of the local model coefficients.     

Reliability analysis of nuclear containment without metallic liners against jet aircraft crash

The present study presents a methodology for detailed reliability analysis of nuclear containment without metallic liners against aircraft crash. For this purpose, a nonlinear limit state function has been derived using violation of tolerable crack width as failure criterion. This criterion has been considered as failure criterion because radioactive radiations may come out if size of crack becomes more than the tolerable crack width. The derived limit state uses the response of containment that has been obtained from a detailed dynamic analysis of nuclear containment under an impact of a large size Boeing jet aircraft. Using this response in conjunction with limit state function, the reliabilities and probabilities of failures are obtained at a number of vulnerable locations employing an efficient first-order reliability method (FORM). These values of reliability and probability of failure at various vulnerable locations are then used for the estimation of conditional and annual reliabilities of nuclear containment as a function of its location from the airport. To study the influence of the various random variables on containment reliability the sensitivity analysis has been performed. Some parametric studies have also been included to obtain the results of field and academic interest.     

Optimization of abrasive water jet cutting of ductile materials

Full factorial design of experiments was developed in order to investigate the effects of jet pressure, abrasive mixing rate, cutting feed, and plate thickness upon three response variables, surface finish of cutting wear zone, percentage proportion of striation free area, and maximum width of cut. The set of sixteen experiments was performed on each of the following two ductile materials: AISI 4340 (high strength low alloy steel, hardened to 49HRc) and Aluminum 2219. Analysis of Variance (ANOVA) was performed on experimental data in order to determine the significance of effects of different parameters on the performance measures. It was found that cutting feed and thickness were highly influential parameters, while abrasive mixing rate is influential upon surface roughness only. Strong interaction was found between jet pressure and workpiece material. Multi-criteria numerical optimization was performed in order to simultaneously maximize/minimize different combinations of performance measures.     

Synthesis and Physical Properties of Mn Doped ZnO Dilute Magnetic Semiconductor Nanostructures

Mn doped ZnO nanostructures have been prepared using low temperature simple, quick, and versatile synthesis approach. The structural, microstructural, and vibrational investigations reveal that as prepared nanostructures with low Mn doping concentration have single hexagonal phase and are grown along the preferred c-axis. The X-rays photoelectron spectroscopy demonstrates that the Mn ions are in mixed oxidation states for high doping concentration of Mn, while are in 2+ oxidation state for low concentration into ZnO lattice. The photoluminescence spectrum (PL) exhibits a significant red-shift of 22 nm in the optical band gap of doped ZnO and shows the improved luminescence properties, which makes it potential for its use in the photocatalyst, optoelectronics and solar cell nanodevices. Furthermore, the magnetic measurement of Mn doped ZnO nanostructures exhibits the ferromagnetism at room temperature.     

Chemical Coupled PEDOT:PSS/Si Electrode: Suppressed Electrolyte Consumption Enables Long‑Term Stability

Huge volume changes of Si during lithiation/delithiation lead to regeneration of solid-electrolyte interphase(SEI)and consume electrolyte.In this article,γ-glycidoxypropyl trimethoxysilane(GOPS)was incorporated in Si/PEDOT:PSS electrodes to construct a flexible and conductive artificial SEI,effectively suppressing the consumption of electrolyte.The optimized electrode can maintain 1000 mAh g^−1 for nearly 800 cycles under limited electrolyte compared with 40 cycles of the electrodes without GOPS.Also,the optimized electrode exhibits excellent rate capability.The use of GOPS greatly improves the interface compatibility between Si and PEDOT:PSS.XPS Ar+etching depth analysis proved that the addition of GOPS is conducive to forming a more stable SEI.A full battery assembled with NCM 523 cathode delivers a high energy density of 520 Wh kg^−1,offering good stability.     

DVCC-Based Non-linear Feedback Neural Circuit for?Solving System of Linear Equations

A neural circuit to solve a system of simultaneous linear equations is presented. The circuit employs non-linear feedback to achieve a transcendental energy function that ensures fast convergence to the exact solution while enjoying reduction in hardware complexity over existing schemes. A new building block for analog signal processing, the digitally controlled differential voltage current conveyor (DC-DVCC) is introduced and is utilized for the non-linear synaptic interconnections between neurons. The proof of the energy function has been given and it is shown that the gradient network converges exactly to the solution of the system of equations. PSPICE simulation results are presented for linear systems of equations of various sizes and are found to be in close agreement with the algebraic solution. The use of CMOS DC-DVCCs and operational amplifiers facilitates monolithic integration.     

Asymptotic stability, ℓ2 gain,boundness analysis,and control synthesis for switched systems: a switching frequency approach

In this paper, several concepts of switching frequency are introduced to analyze the properties and performance of switched systems in infinite as well as finite‐time intervals. The observation is very motivating that different system properties and performances depend on different switching frequencies. Sufficient conditions ensuring asymptotic stability, ?₂ gain performance, and state boundness are derived on the basis of the notions of switching frequency, respectively. Then, on the basis of the analysis results, the control synthesis problems are addressed. LMI‐based design algorithms are proposed to meet different control synthesis requirements. Numerical design examples are provided to demonstrate our results. Copyright © 2011 John Wiley & Sons, Ltd.     

Scanning and Address Allocation Delays in Vehicular Communications

WLAN-based roadside-to-vehicle communications is an increasingly popular research trend. This paper examines the applicability of WLANs in the Intelligent Transportation Systems with focus on reducing the scanning phase delay and the address allocation delay. The handover delays become intolerable when the indoor WLAN Access Poins are accessed from by the outdoor mobile nodes at vehicular speeds. In this work, we propose a baseline scheme which calls for passively scanning only the orthogonal channels to reduce the scanning phase delay in the overall handover latency. We argue that the interference free orthogonal channels are ideal for conveying time critical information in vehicular environments. Secondly, this paper evaluates the delays incurred by the Dynamic Host Configuration Protocol (DHCP) in the handover process. The focus on establishing the amount of delay contributed by each DHCP phase and make some meaningful comments at the end. The conclusions made in this paper are based on real-world experiments and tests.