Synthesis of amphiphilic magnetic microspheres by dispersion copolymerization of styrene and poly(ethylene oxide) macromonomer

Amphiphilic magnetic microspheres ranging in diameter from 5 to 100 µm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) vinylbenzyl (PEO‐VB) macromonomer (MPEO) in the presence of Fe₃O₄ magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing styrene concentration and initiator concentration. It also increased with decreasing stabilizer concentration and molecular weight of MPEO. The content of the hydroxyl groups localized in the microspheres ranged from 0.01 to 0.2 mmol g^?1. © 2003 Society of Chemical Industry     

Recovery of gold cyanide using inherently conducting polymers

Removal of gold from basic solutions containing [Au(CN)₂]^? has been demonstrated using the inherently conducting polymer polypyrrole. Polymers containing sulfonated aromatic dopants have been found to display a significant ability to remove gold from such solutions. Experiments performed in solutions containing both gold and copper cyanide complexes indicate that the recovery process is not highly selective. However, the polypyrroles used display significantly faster rates of gold recovery than activated carbon. © 2003 Society of Chemical Industry     

High-performance MIM capacitor using ALD high-k HfO/sub 2/-Al/sub 2/O/sub 3/ laminate dielectrics

For the first time, we successfully fabricated and demonstrated high performance metal-insulator-metal (MIM) capacitors with HfO/sub 2/-Al/sub 2/O/sub 3/ laminate dielectric using atomic layer deposition (ALD) technique. Our data indicates that the laminate MIM capacitor can provide high capacitance density of 12.8 fF//spl mu/m/sup 2/ from 10 kHz up to 20 GHz, very low leakage current of 3.2 /spl times/ 10/sup -8/ A/cm/sup 2/ at 3.3 V, small linear voltage coefficient of capacitance of 240 ppm/V together with quadratic one of 1830 ppm/V/sup 2/, temperature coefficient of capacitance of 182 ppm//spl deg/C, and high breakdown field of /spl sim/6 MV/cm as well as promising reliability. As a result, the HfO/sub 2/-Al/sub 2/O/sub 3/ laminate is a very promising candidate for next generation MIM capacitor for radio frequency and mixed signal integrated circuit applications.     

具有阻力特性材料的σ_f－σ关系及一种新的阻力曲线测定方法

通过对相变增韧陶瓷及一种可切削玻璃－陶瓷动态疲劳（恒应力速率）试验中高应力速率区断裂应力下降现象的理论分析，发现这种现象与材料的阻力特性（Ｒ－ｃｕｒｖｅ）密切相关。确立的σ_ｆ－σ理论关系能够很好地描述整个应力速率区间内的动态疲劳试验结果。高应力速率区σ_ｆ－σ在双对数坐标下为负斜率直线，直线斜率为（ｍ为阻力曲线ＫＲ＝ｋ（△ａ）~ｍ的指数），断裂主要由材料阻力行为控制；低应力速率区，σ_ｆ－σ在双对数坐标下为正斜率直线，直线斜率为　（ｎ为应力腐蚀指数），断裂主要由材料应力腐蚀行为控制。建立了测定材料阻力特性的一种新方法，分别用这种方法及压痕／弯曲方法对一种可切削玻璃－陶瓷的阻力特性进行了实验测定，两种方法所得结果有很好的一致性。     

Transmission loss allocation based on a new quadratic loss expression

This paper presents a derivation of a new quadratic expression for the transmission loss in a power system. The main advantage of this expression is the improvement in accuracy over the other existing approximations. Furthermore, this improved quadratic form allows the transmission loss to be expressed in terms of nodal power injections. This paper builds on the derived loss expression and proposes a bus-loss matrix. This matrix is useful in quantifying the interactions among different bus power injections and establishing a loss allocation scheme for individual buses. Numerical examples are used to illustrate the accuracy of the derived quadratic form and its use in loss allocation.     

Finite-element analysis of hyperelastic thin shells with large strains

The objective of this contribution is the development of theoretical and numerical models applicable to large strain analysis of hyperelastic shells confining particular attention to incompressible materials. The theoretical model is developed on the basis of a quadratic displacement approximation in thickness coordinate by neglecting transverse shear strains. In the case of incompressible materials this leads to a three-parametric theory governed solely by mid-surface displacements. The material incompressiblity is expressed by two equivalent equation sets considered at the element level as subsidiary conditions. For the simulation of nonlinear material behaviour the Mooney-Rivlin model is adopted including neo-Hookean materials as a special case. After transformation of nonlinear relations into incremental formulation doubly curved triangular and quadrilateral elements are developed via the displacement method. Finally, examples are given to demonstrate the ability of these models in dealing with large strain as well as finite rotation shell problems.The present study is supported by a research grant of the German National Science Foundation (DFG) under Ba 969/3-1.dedicated to Prof. Dr. Dr. Erwin Stein for his 65th birthday anniversary     

Experimental studies of new ductile coupling beams and multi-storey shear walls

The span-depth ratios of coupling beams to interconnect shear walls are generally small, so that brittle shear failure may occur and lead to reduced ductility. In order to improve the ductility of coupling beams for earthquake loading, a new type of ductile coupling beam is proposed in this paper. Along the middle depth of this beam, a slit through the entire thickness (a narrow hole) near each end and two lateral keyways along the remaining middle part of the span are made. The reductions of the stiffness under service load and the ultimate carrying capacity of the beam due to the weakening mentioned above are small and the ductility is greatly increased. Tests of 4-storey walls interconnected by coupling beams in three different constructions (monolithic beams, beams with a through-slit and new-type beams) indicated that shear walls with the new coupling beams possess the best aseismic behaviours under cyclic loading. The proposed new coupling beam has been used in a high-rise building.