Experience in developing ultrahigh capacity compressor stages

Translated from Khimicheskoe i Neftyanoe Mashinostroenie, No. 2, pp. 4–7, February, 1992.     

Propagation of the Chain Explosive‐Decomposition Reaction in Silver Azide Crystals

The velocity of the chain explosivedecomposition reaction in silver azide whiskes has been measured (1500 m/sec). The measured velocity is identified as the propagation velocity of the diffusion front of holes generated in the course of explosive decomposition.     

Engineering of functional supramacromolecular complexes of proteins (enzymes) using reversed micelles as matrix microreactors

The size of the inner water cavity of reversed micelles formedin a triple system ‘water-surfactant-organic solvent’can be widely varied by changing the degree of surfactant hydration.This gives grounds to use reversed micelles as matrix microreactorsfor the design of supramolecular complexes of proteins. Usingultracentrifugation analysis, it has been demonstrated thatthe oligomeric composition of various enzymes (ketoglutaratedehydrogenase, alkaline phosphatase, lactic dehydrogenase, glyceraldehyde-3-phosphatedehydrogenase) solubilized in reversed micelles of Aerosol OT[sodium bis(2-ethylehexyl)sulfosuccinate] in octane changesupon variation of the degree of hydration. An oligomeric complexforms under conditions when the radius of the micelle innercavity is big enough to incorporate this complex as a whole.At lower degrees of hydration the micelles ‘uncouple’such complexes to their components. The catalytic propertiesof various oligomeric complexes have been studied. Possibilitiesof using reversed micelles for the separation of subunits ofoligomeric enzymes under non-denaturating conditions have beendemonstrated. In particular, the isolated subunits of alkalinephosphatase, lactic dehydrogenase and glyceralde-hyde-3-phosphatedehydrogenase have been found to be active in Aerosol OT reversedmicelles. The dependences of the catalytic activity of oligomericenzymes represent saw-like curves. The maxima of the catalyticactivity observed at these curves relate to the functioningof various oligomeric forms of an enzyme. The radii of the micelleinner cavity under conditions when these maxima are observedcorrelate with the linear dimensions of the enzyme oligomericforms. Correlation of the position of a maximum with the shapeof an oligomeric complex is discussed.     

Design of active and stable oxygen reduction reaction catalysts by embedding Co<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript><Emphasis Type="Italic">y</Emphasis></Subscript> nanoparticles into nitrogen-doped carbon

The oxygen reduction reaction (ORR) is essential in research pertaining to life science and energy. In applications, platinum-based catalysts give ideal reactivity, but, in practice, are often subject to high costs and poor stability. Some cost-efficient transition metal oxides have exhibited excellent ORR reactivity, but the stability and durability of such alternative catalyst materials pose serious challenges. Here, we present a facile method to fabricate uniform Co _x O _y nanoparticles and embed them into N-doped carbon, which results in a composite of extraordinary stability and durability, while maintaining its high reactivity. The half-wave potential shows a negative shift of only 21 mV after 10,000 cycles, only one third of that observed for Pt/C (63 mV). Furthermore, after 100,000 s testing at a constant potential, the current decreases by only 17%, significantly less than for Pt/C (35%). The exceptional stability and durability results from the system architecture, which comprises a thin carbon shell that prevents agglomeration of the Co _x O _y nanoparticles and their detaching from the substrate.

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Polymer solutions confined in slit-like pores with attractive walls: An off-lattice Monte Carlo study of static properties and chain dynamics

Summary Using a bead spring model of flexible polymer chains, the density profiles and chain configurational properties of polymer solutions confined between parallel plates were studied. A wide range of density , chain length N, and strength of a short-range attractive wall potential was investigated. Both a temperature T in the good solvent regime (T > , being the Theta temperature where a chain in unconfined bulk three-dimensional solution would behave ideally) and a temperature in the bad solvent regime (T < ) were considered. It is shown that phase separation in a polymer-rich and polymer-poor solution in the slit competes with polymer adsorption at the walls. A qualitative connection to the wetting behavior of semi-infinite polymer solutions is drawn. The acceptance rate for monomer motions was studied for various conditions, and profiles of monomer mobility across the slit were recorded. Also, average chain relaxation times were extracted from the time dependence of mean-square displacements. Although with increasing density the chain radii (at T > ) show a crossover from two-dimensional excluded volume behavior (R_g N² with = 3/4) to ideal random walk behavior ( = 1/2), the relaxation times show effective exponents Z_eff ( N^{Z eff}) that clearly deviate from the Rouse prediction in concentrated confined solutions.     

Vehicle license plate tilt correction based on the straight line fitting method and minimizing variance of coordinates of projection points

Tilt correction is a very crucial and inevitable task in the automatic recognition of the vehicle license plate (VLP). In this paper, according to the least square fitting with perpendicular offsets (LSFPO), the VLP region is fitted to a straight line. After the line slope is obtained, rotation angle of the VLP is estimated. Then the whole image is rotated for tilt correction in horizontal direction by this angle. Tilt correction in vertical direction by minimizing the variance of coordinates of the projection points is proposed. Character segmentation is performed after horizontal correction and character points are projected along the vertical direction after shear transform. Despite the success of VLP detection approaches in the past decades, a few of them can effectively locate license plate (LP), even when vehicle bodies and LPs have similar color. A common drawback of color-based VLP detection is the failure to detect the boundaries or border of LPs. In this paper, we propose a modified recursive labeling algorithm for solving this problem and detecting candidate regions. According to different colored LP, these candidate regions may include LP regions. Geometrical properties of the LP such as area, bounding box and aspect-ratio are then used for classification. Various LP images were used with a variety of conditions to test the proposed method and results are presented to prove its effectiveness.     

HDR Image Generation based on Intensity Clustering and Local Feature Analysis

This paper describes a cluster-based method for combining differently exposed images in order to increase their dynamic range. Initially an image is decomposed into a set of arbitrary shaped regions. For each region we compute a utility function which is based on the amount of presented information and an entropy. This function is used to select the most appropriate exposure for each region. After the exposures are selected, a bilateral filtering is applied in order to make the interregional transitions smooth. As a result we obtain weighting coefficients for each exposure and pixel. An output image is combined from clusters of input images using weights. Each pixel of the output image is calculated as a weighted sum of exposures. The proposed method allows recovering details from overexposed and underexposed parts of image without producing additional noise. Our experiments show effectiveness of the algorithm for the high dynamic range scenes. It requires no information about shutter speed or camera parameters. This method shows robust results even if the exposure difference between input images is 2-stops or higher.