一次盐水设备运行总结

介绍了内蒙古海吉氯碱化工股份有限公司6万t/a离子膜烧碱装置一次盐水设备的运行情况和运行过程中存在的问题及相应的技改措施.     

建筑电气设计中AutoCAD二次开发的研究

基于AutoCAD的二次开发环境下,建立幻灯片库,在AutoCAD本身所包含的程序帮助下,将已建好的幻灯片库嵌入到AutoCAD用户专用下拉菜单中.给设计者创造属于自己的开发环境,使AutoCAD在建筑电气设计中的使用更加灵活,极大的提高设计效率.     

Cu－MnO_2同槽电解半工业试验研究

提出了Ｃｕ－ＭｎＯ＿２同槽电解的新工艺，在同一电解槽同时得到电铜和电解二氧化锰两种产品，该新工艺具有低电耗、低酸雾污染和低酸耗等优点．     

TEM method for rapid and precise evaluation of continuous recrystallization

With the aid of a double-tilt holder in a transmission electron microscope, a new method for a rapid and precise determination of the misorientations of a large number of subgrain or grain boundaries is given in this article. By use of the method, the continuous recrystallization can be rapidly and precisely evaluated when compared to the other conventional methods.     

Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

Synthesis and aqueous solution behaviors of sodium sulfonate‐terminated dendritic poly(ester‐amine)

Sodium sulfonate‐terminated dendritic poly(ester‐amine) (SPEA) was synthesized by sulfonation of acrylic double bond‐terminated dendritic poly(ester‐amine) (APEA) with sodium hydrogen sulfite (NaHSO₃) in mixture of diglycol and 2‐butanone under normal pressure. The structure of SPEA was characterized by IR, ¹H‐NMR, and elemental analysis. SPEA was water‐soluble. 1.0–40.0% (mass) SPEA aqueous solutions appeared as dilatant fluid. When pH value varied from 1.5 to 12.0, the viscosity of 1–5% (mass) SPEA aqueous solutions changed very small, and the electric conductivity almost kept stable within pH 3.0–10.0. The relationship between the viscosity and the concentration of SPEA water solutions was similar to that of NaCl water solutions. The surface tension of SPEA water solutions was lower than that of polyethylene glycol 2000 water solutions with the same concentration. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

土钉加锚杆联合支护基坑的失稳分析及处理

根据具体工程实例,介绍了在基坑开挖时采用土钉加锚杆的联合支护方式后在施工过程中出现坍塌裂缝的现象,针对这一现象,分析了施工条件与环境,得出了事故发生的原因,并结合实际情况提出了处理措施.