全文获取类型
收费全文 | 2232篇 |
免费 | 58篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 33篇 |
综合类 | 1篇 |
化学工业 | 714篇 |
金属工艺 | 47篇 |
机械仪表 | 40篇 |
建筑科学 | 80篇 |
矿业工程 | 2篇 |
能源动力 | 70篇 |
轻工业 | 176篇 |
水利工程 | 12篇 |
石油天然气 | 6篇 |
无线电 | 221篇 |
一般工业技术 | 399篇 |
冶金工业 | 220篇 |
原子能技术 | 16篇 |
自动化技术 | 254篇 |
出版年
2022年 | 32篇 |
2021年 | 44篇 |
2020年 | 13篇 |
2019年 | 19篇 |
2018年 | 34篇 |
2017年 | 36篇 |
2016年 | 42篇 |
2015年 | 19篇 |
2014年 | 55篇 |
2013年 | 108篇 |
2012年 | 91篇 |
2011年 | 112篇 |
2010年 | 83篇 |
2009年 | 104篇 |
2008年 | 98篇 |
2007年 | 99篇 |
2006年 | 82篇 |
2005年 | 70篇 |
2004年 | 62篇 |
2003年 | 63篇 |
2002年 | 77篇 |
2001年 | 36篇 |
2000年 | 38篇 |
1999年 | 42篇 |
1998年 | 57篇 |
1997年 | 55篇 |
1996年 | 50篇 |
1995年 | 42篇 |
1994年 | 34篇 |
1993年 | 35篇 |
1992年 | 31篇 |
1991年 | 34篇 |
1990年 | 36篇 |
1989年 | 29篇 |
1988年 | 24篇 |
1987年 | 27篇 |
1986年 | 25篇 |
1985年 | 43篇 |
1984年 | 34篇 |
1983年 | 19篇 |
1982年 | 26篇 |
1981年 | 20篇 |
1980年 | 17篇 |
1979年 | 29篇 |
1978年 | 23篇 |
1977年 | 24篇 |
1976年 | 22篇 |
1975年 | 22篇 |
1974年 | 14篇 |
1973年 | 18篇 |
排序方式: 共有2291条查询结果,搜索用时 15 毫秒
1.
The extinction coefficient ? at 2.9 μm for OH in fluoride glasses is measured by determining the amount of HF evolved during heating of the glass under steam and the corresponding intensity of the OH absorption band. This coefficient is respectively equal to 31 litre mole?1 cm?1 for BTYbZ glass (15 BaF2 - 29 ThF4 - 28 YbF3 - 28 ZnF2) and 19.5 litre mole?1 cm?1 for BALLA glass (34 BaF2 - 57 ZrF4 - 4 AlF3 - 5 LaF3). 相似文献
2.
Tony Maillet Jacques Barbier Jr. Daniel Duprez 《Applied catalysis. B, Environmental》1996,9(1-4):251-266
A 1% Pd catalyst (38% dispersion) was prepared by impregnating a γ-alumina with palladium acetylacetonate dissolved in acetone. The behaviour of this catalyst in oxidation and steam reforming (SR) of propane was investigated. Temperature-programmed reactions of C3H8 with O2 or with O2 + H2O were carried out with different stoichiometric ratios S(S =[O2]/5[C3H8]). The conversion profiles of C3H8 for the reaction carried out in substoichiometry of O2 (S < 1) showed two discrete domains of conversion: oxidation at temperatures below 350°C and SR at temperatures above 350°C. The presence of steam in the inlet gases is not necessary for SR to occur: there is sufficient water produced in the oxidation to form H2 and carbon oxides by this reaction. Contrary to what was observed with Pt, an apparent deactivation between 310 and 385°C could be observed with Pd in oxidation. This is due to a reduction of PdOx into Pd0, which is much less active than the oxide in propane oxidation. Steam added to the reactants inhibits oxidation while it prevents the reduction of PdOx into Pd0. Compared to Pt and to Rh, Pd has a higher thermal resistance: no deactivation occurred after treatment up to 700°C and limited deactivation after treatment up to 900°C, provided that the catalyst is maintained in an oxygen-rich atmosphere during the cooling. 相似文献
3.
4.
5.
C Altman A Ladouch MJ Briantais T Rason E Martin L Jacques C Buffet 《Canadian Metallurgical Quarterly》1995,24(15):708-710
OBJECTIVES: Antral gastritis is frequent in alcoholics. The role of H. pylori in the pathogenesis of gastritis in these patients is not well known. The aim of our study was to study the role of H. pylori and cirrhosis in the pathogenesis of antral gastritis in alcoholic patients. METHODS: Seventy-nine patients were included in the study. All underwent upper gastrointestinal tract endoscopy with antral biopsies, independently of the presence of abdominal pain, and had serological examination for H. pylori antibodies. RESULTS: Cirrhosis and gastritis were present in 50 and 40 patients respectively, H. pylori serological assay and histological identification of the bacterium were positive in 35 (44%) and 19 (24%) patients respectively. Discrepancy between the 2 tests were observed more frequently in cirrhotic patients. A positive serology with a negative histologic examination for H. pylori was present for 18 cirrhotic and 4 noncirrhotic patients (p < 0.05). A gastritis without evidence of H. pylori was more frequent in cirrhotic than in noncirrhotic patients. H. pylori was histologically present in 11 of 29 cirrhotic patients and in 8 of the 11 noncirrhotic patients with a gastritis (p < 0.05). CONCLUSIONS: Discrepancies between histological examination and H. pylori serology in patients with cirrhosis might be due to the inhospitable environment for H. pylori in case of portal hypertension; the positive serology could be in relation with a past infection. 相似文献
6.
The paper proposes and describes several tools enabling their user to estimate the efficiency of Pascal or C-like programs. The approach consists of generating symbolic formulas expressing the efficiency of the programs being analyzed. The formulas are applicable to a variety of compiler-machine configurations. The actual numeric values of the variables in the symbolic formula are determined using linear programming techniques. The proposed approach reduces considerably the amount of benchmarking needed to analyze programs. Several examples are presented showing the applicability of the tools. The effort necessary to implement them is considerably reduced by the combined usage of Prolog and a symbolic formula manipulation package (Maple). 相似文献
7.
We solve the Kohn-Sham equations self-consistently in the local density approximation for spheroidal sodium clusters in the particle range 8 ≤ Z ≤ 40. We use a smooth fermi-like jellium density to simulate the influence of the ions in the surface region and obtain similar results as Ekardt and Penzar, but slightly different regions of prolate-to-oblate transitions. We present the systematics of potential energy curves with respect to transitions between oblate, prolate and spherical shapes. Shape transitions occur at particle numbers 12/14 (prolate/oblate), 18/20/22 (oblate/spherical/prolate) and 30/32 (prolate/oblate), which are in good agreement with experimental results. The quadrupole and hexadecupole overlap of the electron density with the jellium is investigated, showing a strong hexadecupole dependence for selected clusters. Collective dipole resonances are described in a simple sum rule approach, which reveals a double splitting according to the different resonance frequencies along the principal axes of the spheroid. The systematics of the resonance peaks for the larger clusters with Z ≥ 20 is in good agreement with experimental results. 相似文献
8.
Michel Dorbon Pierre Henri Bigeard Jacques Denis Christian Bernasconi 《Petroleum Science and Technology》1992,10(8):1313-1341
As established by several previous works, nitrogen compounds play a prominent role in the evolution of middle distillates containing cracked components, particularly regarding sediment formation and color evolution.
In a first part, this paper describes and compares stability properties of fuel blends using both an accelerated ageing method at 120°C (248°F ) and long term storage methods at 43°C(110°F) -ASTM 0 4625 - and at ambient temperature. Effectiveness of stabilizing additives is also evaluated. In mixtures containing LCOs, insoluble products are formed progressively during ageings, more or less rapidly according to the chemical constitution of the mixtures.
Then, it reports the complete identification of nitrogen compounds using gas chromatography equipped with a selective nitrogen detector and mass spectrometry showing that in light cycle oils, alkyl indoles and carbazoles are the main families.
Evolution of these compounds was followed kinetically during ageings in absence and presence of additives and alkyl indoles appeared as the moat evolutionary.
It appeared that some additives avoided evolutions of alkyl indoles without preventing sediment formation and color evolution. Oxidation mechanism involving nitrogen compounds should not be the only one to explain the storage evolutions of middle distillates.
Hydrotreatment converts all the alkyl indoles of LCO and prevents coloration end deposits in the storage of the mixtures of steaight-run distillates and LCOs. 相似文献
In a first part, this paper describes and compares stability properties of fuel blends using both an accelerated ageing method at 120°C (248°F ) and long term storage methods at 43°C(110°F) -ASTM 0 4625 - and at ambient temperature. Effectiveness of stabilizing additives is also evaluated. In mixtures containing LCOs, insoluble products are formed progressively during ageings, more or less rapidly according to the chemical constitution of the mixtures.
Then, it reports the complete identification of nitrogen compounds using gas chromatography equipped with a selective nitrogen detector and mass spectrometry showing that in light cycle oils, alkyl indoles and carbazoles are the main families.
Evolution of these compounds was followed kinetically during ageings in absence and presence of additives and alkyl indoles appeared as the moat evolutionary.
It appeared that some additives avoided evolutions of alkyl indoles without preventing sediment formation and color evolution. Oxidation mechanism involving nitrogen compounds should not be the only one to explain the storage evolutions of middle distillates.
Hydrotreatment converts all the alkyl indoles of LCO and prevents coloration end deposits in the storage of the mixtures of steaight-run distillates and LCOs. 相似文献
9.
Auguste Commeyras Hlne Collet Laurent Boiteau Jacques Taillades Odile Vandenabeele‐Trambouze Herv Cottet Jean‐Philippe Biron Raphaël Plasson Louis Mion Olivier Lagrille Herv Martin Franck Selsis Michel Dobrijevic 《Polymer International》2002,51(7):661-665
Addressing the still open question of the prebiotic origin of sequential macromolecules (peptides, nucleic acids) on the primitive Earth, we describe a molecular engine (the primary pump), which works at ambient temperature and continuously generates, elongates and complexifies sequential peptides. This new scenario is based on a cyclic reaction sequence, whose keystep is the activation of amino acids into their N‐carboxyanhydrides (NCA) through nitrosation by NOx. This process could have taken place on tidal beaches; it requires a buffered ocean, emerged land and a nitrosating atmosphere. With the help of geochemical studies and computer simulations of atmosphere photochemistry, we show that the primitive Earth during the Hadean may have satisfied all these requirements. © 2001 Society of Chemical Industry. 相似文献
10.
Jozef P H Linssen Anneloes L G M Janssens Hanneke C E Reitsma Wender L P Bredie Jacques P Roozen 《Journal of the science of food and agriculture》1993,61(4):457-462
Taste recognition threshold concentrations (TRTC) of styrene were determined in samples of oil-in-water emulsions (30–300 g kg?1 oil) and yoghurts (1–30 g kg?1 fat), spiked with styrene. The observed TRTC increased linearly with increasing fat content and ranged from 0–3 to 2–1 mg kg?1 for the emulsions and from 36 to 171 g kg?1 for the yoghurts. Styrene equilibrium partition coefficients between emulsions and their respective vapour phases were determined. The concentrations of styrene in the continuous aqueous phase of the emulsions and yoghurts were calculated at the TRTC. The styrene concentrations in the continuous phase had constant values of about 15 g kg?1 indicating that perception of styrene for oil-in–water emulsions is determined by the aqueous phase of the emulsion. The concentrations of styrene in the vapor phases above the emulsions and yoghurts were also calculated and were found to be constant at the TRTC. This relationship probably resulted from the equilibrium of distribution of styrene between the respective phases. Commercial yoghurt packed in polystyrene beakers contained styrene levels in the range 2–11 g kg?1, much lower then the TRTC reported. 相似文献