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1.
Hg1-xMnxTe semiconducting semimagnetic alloy has been examined in the context of its possible applications in infrared detectors.
For analysis of detector properties the intrinsic carrier concentration has been calculated as a function of temperature and
crystal composition. The starting material was In-doped Hg1-xMnxTe grown by the modified Bridgman method. The as-grown crystals with manganese content of 12-19% were p-type with carrier
concentration
and mobility of 100 cm2/ Vs at 77 K. An-type layer was formed on the surface by the annealing process in saturated Hg-vapour at 270-320° for 2 hrs. Capacitance-voltage
curves have C-3 dependence on applied voltage indicating that the junction is linearly graded. From standard electrical measurements and
spectral characteristics the main detector parameters were determined and compared to those of Hg1-xCdxTe devices. The influence of material properties on detector parameters was analyzed. In order to estimate the carrier transport
mechanisms, differential resistivities and current-voltage curves were measured over a wide range of temperaturesi.e. 25 to 300 K. From the temperature dependence of the R0A product, it was established that at high temperatures (150-300 K) the carrier transport is dominated by a recombination-generation
mechanism. In low temperature region the excess current at forward bias is probably attributed to carrier tunneling via energy
states distributed randomly within the forbidden gap. At reverse bias the leakage surface or volume currents dominate in the
carrier transport. 相似文献
2.
A Systematic Structure–Activity Study of a New Type of Small Peptidic Transfection Vector Reveals the Importance of a Special Oxo-Anion-Binding Motif for Gene Delivery
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Dr. Sandra Junghänel Sarah Karczewski Sandra Bäcker Prof. Dr. Shirley K. Knauer Prof. Dr. Carsten Schmuck 《Chembiochem : a European journal of chemical biology》2017,18(22):2268-2279
We discovered a new class of artificial peptidic transfection vectors based on an artificial anion-binding motif, the guanidiniocarbonylpyrrole (GCP) cation. This new type of vector is surprisingly smaller than traditional systems, and our previous work suggested that the GCP group was important for promoting critical endosomal escape. We now present here a systematic comparison of similar DNA ligands featuring our GCP oxo-anion-binding motif with DNA ligands only consisting of naturally occurring amino acids. Structure–activity studies showed that the artificial binding motif clearly outperformed natural amino acids such as histidine, lysine, and arginine. It improved the ability to shuttle foreign genetic material into cells, yet successfully mediated endosomal escape. Also, plasmids that were complexed by our artificial ligands were stabilized against cytosolic degradation to some extent. This resulted in the successful expression of plasmid information (comparable to gold standards such as polyethyleneimine). Hence, our study clearly demonstrates the importance of the tailor-made GCP anion-binding site for efficient gene transfection. 相似文献
3.
T. Miruszewski B. Trawiński M. Gałka J. Morzy B. Bochentyn J. Karczewski P. Gdaniec M. Gazda B. Kusz 《Materials Science-Poland》2014,32(3):331-340
In order to find a relationship between structural and electrical properties, niobium and yttrium doped SrTiO3 ceramics were prepared via solid-state reaction. The samples were sintered in hydrogen and air conditions. The samples were also fabricated with a pore-former to obtain highly porous specimens. The electrical properties of Nb-doped SrTiO3 samples and yttrium and niobium co-doped SrTiO3 were compared. The comparable electrical properties were observed and discussed according to previous literature reports. It was noticed that the synthesis in a reducing hydrogen atmosphere can increase the solubility of dopants. Moreover, the samples sintered in air presented lower conductivity level and worse structural properties than the samples sintered in hydrogen. The explanation of obtained results was also suggested and discussed. 相似文献
4.
Bruzda Grzegorz Polkowski Wojciech Polkowska Adelajda Nowak Rafał Kudyba Artur Książek Marzanna Lech Sebastian Karczewski Krzysztof Giuranno Donatella 《Journal of Materials Science》2022,57(28):13724-13735
Journal of Materials Science - Boron-doped molybdenum silicides have been already recognized as attractive candidates for space and ground ultra-high-temperature applications far beyond limits of... 相似文献
5.
Michał Chojnacki Stanisław Jóźwiak Krzysztof Karczewski Zbigniew Bojar 《Intermetallics》2011,19(10):1555-1562
An attempt to modify sintering of iron and aluminium elemental powders with use of small additions of Mg and MgH2 was presented in this paper. The kinetics of such modified sintering was investigated using DSC technique, XRD analysis and SEM observations. Significant changes in the mechanism of exothermal formation reaction of Fe–Al intermetallic phases in compositions doped with magnesium and its hydride was observed. Initiation temperature of Self-propagating High-temperature Synthesis (SHS) reaction was pronouncedly shifted to lower value as compared with undoped composition. Influence of additions on the SHS reaction kinetics parameters was also calculated with use of the JMA model and changes of the Avrami exponent value of specific phase formation was noticed. Positive effect of MgH2 addition on partial homogeneity of final product was also studied. 相似文献
6.
M.G. Brik P. Łach G. Karczewski T. Wojtowicz A. Kamińska A. Suchocki 《Materials Chemistry and Physics》2013
Luminescence of CdTe quantum dots embedded in ZnTe is quenched at pressure of about 4.5 GPa in the high-pressure experiments. This pressure-induced quenching is attributed to the “zinc-blende–cinnabar” phase transition in CdTe, which was confirmed by the first-principles calculations. Theoretical analysis of the pressure at which the phase transition occurs for CdTe was performed using the CASTEP module of Materials Studio package with both generalized gradient approximation (GGA) and local density approximation (LDA). The calculated phase transition pressures are equal to about 4.4 GPa and 2.6 GPa, according to the GGA and LDA calculations, respectively, which is in a good agreement with the experimental value. Theoretically estimated value of the pressure coefficient of the band-gap luminescence in zinc-blende structure is in very good agreement with that recently measured in the QDs structures. The calculated Debye temperature, elastic constants and specific heat capacity for the zinc-blend structure agree well with the experimental data; the data for the cinnabar phase are reported here for the first time to the best of the authors' knowledge. 相似文献
7.
V. F. Agekyan N. N. Vasil’ev A. Yu. Serov Yu. A. Stepanov U. V. Tazaev N. G. Filosofov G. Karczewski 《Semiconductors》2006,40(1):67-71
The luminescence spectra controlled by excitons and intracenter 3d emission of Mn2+ ions are studied for a series of Zn1-x MnxTe/Zn0.59Mg0.41 Te quantum well (QW) structures that differ in manganese content and QW width. It is shown that the relative intensities of exciton emission of the QWs and barriers and the dependences of the intensities on the optical excitation level are controlled mainly by the manganese content in the QWs that affect the efficiency of excitons transfer of to the 3d shell of the Mn2+ ions. The effects of QW width and manganese content on the decay kinetics of the intracenter luminescence of the Mn2+ ions are studied. 相似文献
8.
Niobium-doped strontium titanate synthesized via conventional solid-state reaction has been studied. Influence of niobium
content on the lattice parameters and electrical conductivity has been reported. Various reduction conditions have been investigated.
For samples reduced in hydrogen at 1400°C, a transition from thermally activated to metallic behavior has been observed. Maximum
electrical conductivity (ca. 55 Scm−1 at 650°C) has been observed for the SrTi0.98Nb0.02O3-δ sample. The relation of electrical conductivity with the porosity of the samples has been shown. 相似文献
9.
Hewaparakrama KP Mackowski S Jackson HE Smith LM Heiss W Karczewski G 《Nanotechnology》2008,19(12):125706
Using polarization-resolved photoluminescence imaging in external magnetic fields we measure statistically significant distributions of exchange splitting, diamagnetic shift and effective g-factor of excitons in tens of single CdTe quantum dots. Comparison between the as-grown and annealed structures shows strong suppression of ensemble inhomogeneities, with the average exchange splitting reduced by half and significant narrowing of the g-factor distribution. Remarkably, the average value of the excitonic g-factor remains unchanged. This unique ability to yield highly uniform quantum dot ensembles without hampering the exciton Zeeman splitting makes annealing a highly attractive means for tuning the spin properties of quantum dot excitons. 相似文献
10.
Zaleszczyk W Janik E Presz A Dłuzewski P Kret S Szuszkiewicz W Morhange JF Dynowska E Kirmse H Neumann W Petroutchik A Baczewski LT Karczewski G Wojtowicz T 《Nano letters》2008,8(11):4061-4065
It is shown that the growth of II-VI diluted magnetic semiconductor nanowires is possible by the catalytically enhanced molecular beam epitaxy (MBE). Zn(1-x)MnxTe NWs with manganese content up to x=0.60 were produced by this method. X-ray diffraction, Raman spectroscopy, and temperature dependent photoluminescence measurements confirm the incorporation of Mn(2+) ions in the cation substitutional sites of the ZnTe matrix of the NWs. 相似文献