Effect of film thickness on the evolution of annealing texture in sputtered copper films

Microstructural evolution during elevated temperature annealing of sputter deposited copper (Cu) films was investigated by electron backscatter diffraction (EBSD). Analysis of films was performed both in situ using a heating stage, and by ex-situ observation of microstructural evolution. It was noted that not only is the Cu film texture and grain size a function of film thickness, but also that the fraction of twin boundaries present in the material is strongly dependent upon film thickness. This is explained by means of a simple model that considers the energy of the system. Surface and interface energies, as well as grain boundary energies for random high angle boundaries and for twin boundaries (both coherent and incoherent planes) are used in the determination. The model was shown to accurately predict the twin boundary size in self-annealed films. This type of analysis also results in a texture map similar to that presented by Thompson,¹² but incorporates the development and effect of twin boundaries, so that additional texture components (in addition to 111 and 100 fibers) are included.     

Chromosome studies in "preleukemia". III. Myelofibrosis

Cytogenetic studies were done on 18 patients with myelofibrosis or the closely related syndrome, undifferentiated myeloproliferative disorder (MPD). Clones of cells with chromosome abnormalities were demonstrated in the blood of eight individuals, including two with a history of radiation therapy and two with "acute myelofibrosis". Trisomy 8 was present in the latter two patients, but otherwise, there was no consistent cytogenetic pattern or correlation with specific hematologic findings. Sixteen of these patients have been followed for more than 1 year or until death; none has progressed to leukemia. The results indicate that chromosome abnormalities are relatively common in this disorder, but as with polycythemia vera, and unlike some other "preleukemic" states, the aberrant clones in myelofibrosis do not appear to indicate that clinical leukemia is imminent.     

Grain Size and Texture of Cu<Subscript>2</Subscript>ZnSnS<Subscript>4</Subscript> Thin Films Synthesized by Cosputtering Binary Sulfides and Annealing: Effects of Processing Conditions and Sodium

We investigate the synthesis of kesterite Cu₂ZnSnS₄ (CZTS) polycrystalline thin films using cosputtering from binary sulfide targets followed by annealing in sulfur vapor at 500°C to 650°C. The films are the kesterite CZTS phase as indicated by x-ray diffraction, Raman scattering, and optical absorption measurements. The films exhibit (112) fiber texture and preferred low-angle and Σ3 grain boundary populations which have been demonstrated to reduce recombination in Cu(In,Ga)Se₂ and CdTe films. The grain growth kinetics are investigated as functions of temperature and the addition of Na. Significantly, lateral grain sizes above 1 μm are demonstrated for samples grown on Na-free glass, demonstrating the feasibility for CZTS growth on substrates other than soda lime glass.     

Three-dimensional cracks with Dugdale-type plastic zones

A general method for the determination of three-dimensional crack-front plastic zones is presented. The crack-model utilised is of the Dugdale-type, that is a plastic zone is assumed to spread in front of the crack, in the plane of the crack. The solution method relies on the eigenstrain approach to crack-problem solving. Using this approach, the elastic and plastic regions of the crack are first discretised into triangular elements and the stress arising over the crack due to a constant or linear crack-surface displacement in each element is obtained. The stresses are given in terms of hyper-singular integrals, which may be solved numerically. The boundary conditions in the elastic portion (traction-free) and in the plastic zones (Tresca or some other yield condition) are encompassed in an object function in such a way that the boundary conditions are satisfied if and only if the object function is zero. The resulting quadratic programming problem is solved numerically, and hence the crack displacements, and other important quantities, are obtained. Results agree well with some known analytic results regarding the penny shaped crack in tension.     

Systematic Investigation of Metabolic Oligosaccharide Engineering Efficiency in Intestinal Cells Using a Dibenzocyclooctyne-Monosaccharide Conjugate

Metabolic oligosaccharide engineering (MOE) of cells with synthetic monosaccharides can introduce functionality to the glycans of cell membranes. Unnatural sugars (e. g., peracetylated mannose-azide) can be expressed on the cell surface with the azide group in place. After MOE, the azide group can participate in a copper-free click reaction with an alkyne (e. g., dibenzocyclooctyne, DBCO) probe. This allows the metabolic fate of monosaccharides in cells to be understood. However, in a drug delivery context it is desirable to have azide groups on the probe (e. g. a drug delivery particle) and the alkyne (e. g. DBCO) on the cell surface. Consequently, the labelling efficiency of intestinal cell lines (Caco-2 and HT29-MTX-E12) treated with N-dibenzocyclooctyne-tetra-acetylmannosamine, and the concentration- and time-dependent labelling were determined. Furthermore, the labelling of mucus in HT29-MTX-E12 cells with DBCO was shown. This study highlights the potential for using MOE to target azide-functionalised probes to intestinal tissues for drug delivery applications.     

Performance of smart lightwave receivers with linear equalization

Signal processing techniques can be used to reduce linear and nonlinear distortion in high-speed lightwave systems caused by fiber dispersion and nonideal responses of optoelectronic and electronic components. The improvement in the performance of 2.5 and 10 Gb/s intensity modulation, direct detection systems is assessed for receivers which utilize an analog taped delay line equalizer to compensate for signal distortion. Synchronous and fractionally spaced equalizers are evaluated. Smart receivers that jointly optimize the decision time, decision threshold, and equalizer tap weights under a minimum bit error ration criterion are considered. This yields the optimum system performance and allows consideration of both reduced distortion and enhanced noise arising from the signal processing. The effectiveness of the equalization is determined as a function of several important system parameters. Three-tap and five-tap synchronous equalizers yield virtually the same improvement in receiver sensitivity. Depending on the system, a five-tap fractionally spaced equalizer with half-bit-period tap spacing may or may not be significantly more effective than a three-tap synchronous equalizer     

Dynamic analysis of radiation and side-mode suppression in asecond-order DFB laser using time-domain large-signal traveling wavemodel

In this paper, we have developed a relatively simple algorithm to calculate the large-signal dynamic response of DFB lasers by solving the time-dependent coupled wave equations directly in the time domain. The spontaneous emission noise, longitudinal variations of carrier (hole burning) and photon densities as well as that of the refractive index are taken into consideration. To demonstrate the power of this straightforward algorithm, the model shows how the side-mode suppression ratio in devices with high κL and a λ/4: phase shift is significantly affected by the radiation in the second-order DFB laser. The time-dependent radiation pattern in grating-coupled surface-emitting lasers is also calculated for the first time     

Orientation effects on indexing of electron backscatter diffraction patterns

Automated Electron Backscatter Diffraction (EBSD) has become a well-accepted technique for characterizing the crystallographic orientation aspects of polycrystalline microstructures. At the advent of this technique, it was observed that patterns obtained from grains in certain crystallographic orientations were more difficult for the automated indexing algorithms to accurately identify than patterns from other orientations. The origin of this problem is often similarities between the EBSD pattern of the correct orientation and patterns from other orientations or phases. While practical solutions have been found and implemented, the identification of these problem orientations generally occurs only after running an automated scan, as problem orientations are often readily apparent in the resulting orientation maps. However, such an approach only finds those problem orientations that are present in the scan area. It would be advantageous to identify all regions of orientation space that may present problems for automated indexing prior to initiating an automated scan, and to minimize this space through the optimization of acquisition and indexing parameters. This work presents new methods for identifying regions in orientation space where the reliability of the automated indexing is suspect prior to performing a scan. This methodology is used to characterize the impact of various parameters on the indexing algorithm.