Effects of SiC particles codeposition and ultrasound agitation on the electrocrystallisation of nickel-based composite coatings

This study analysed the influence of the codeposition of SiC particles with different sizes: 50 nm, 500 nm and 5 μm, and the type of bath agitation (stirring or ultrasonic) on the electrocrystallisation of nickel coatings. The composites matrix microstructure was analysed by means of SEM, EBSD and XRD, to evaluate the grain size, crystal orientation, and internal stresses and was benchmarked against pure nickel samples electrodeposited in equivalent conditions. The codeposition of nano- and microsize particles with an approximate content of 0.8 and 4 vol.%, respectively, caused only a minor grain refinement and did not vary the dominant?<?100?>?crystal orientation observed in pure Ni. The internal stress was, however, increased by particles codeposition, up to 104 MPa by nanoparticles and 57 MPa by microparticles, compared to the values observed in pure nickel (41 MPa). The higher codeposition rate (11 vol.%) obtained by the addition of submicron-size particles caused a change in the grain growth from columnar to equiaxial, resulting in deposits with a fully random crystal orientation and pronounced grain refinement. The internal stress was also increased by 800% compared to pure nickel. The ultrasound (US) agitation during the deposition caused grain refinement and a selective particle inclusion prompting a decrease in the content of the particles with the larger particles. The deposits produced under US agitation showed an increase in the internal stresses, with double values compared to stirring. The increase in the deposits microhardness, from 280 HV in pure Ni to 560 HV in Ni/SiC submicron-US, was linked to the microstructural changes and particles content.

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Mine inonoations

The paper describes the types of inundations affecting underground mining operations together with their safety, operational, and stability implications. A critical analysis has highlighted three major causes of inundations. These have been classified as event controlled, accidental or spontaneous. The event controlled inundations are associated with the development of fracture zones around a longwall working and followed by main and periodic roof falls in caved mine workings, particularly in coal mines. An approximate theory to predict the event of main and periodic roof falls in the goaf behind the long wall face is given. These types of inundations have been illustrated with several case histories.     

Estimate of Stress-Strain State of Rocks in the Area of Drilling Kola Ultradeep Well

The values of horizontal tectonic stresses are estimated up to depth of 11 500 m by the measurement of velocities of longitudinal and transverse waves in rock samples extracted from various depths when drilling Kola Ultradeep Well.