Off-Site Exposure to Respirable Aerosols Produced during the Disk-Incorporation of Class B Biosolids

Field experiments were conducted at a Class B biosolids land application site in central Arizona to measure, model, and source-track the off-site transport of aerosols emitted when biosolids were disk-incorporated into soils. Real-time PM10 monitoring provided time-resolved aerosol information sufficient for verifying both off-site concentration and off-site exposure time model results. Under the conditions considered and at a distance of 165?m from the aerosol source, biosolids disk-incorporation resulted in an intermittent exposure to biosolids-derived aerosol concentration between 15 and 40?μg/m3 and an inhalable biosolids dose between 2 and 8?μg. Transport modeling predicted that these doses will decrease with increasing wind speed. In addition, three DNA sequence-based biosolids source tracking methods were applied to aerosol samples and confirmed the presence of biosolids in aerosols at 5, 65, and 165?m from the aerosol source. Field measurements and modeling indicate that the nature of biosolids-derived aerosol exposure is a series of intermittent high concentration puffs, rather than a continuous low concentration.     

MXene Functionalized,Highly Breathable and Sensitive Pressure Sensors with Multi-Layered Porous Structure

Breathable, flexible, and highly sensitive pressure sensors have drawn increasing attention due to their potential in wearable electronics for body-motion monitoring, human-machine interfaces, etc. However, current pressure sensors are usually assembled with polymer substrates or encapsulation layers, thus causing discomfort during wearing (i.e., low air/vapor permeability, mechanical mismatch) and restricting their applications. A breathable and flexible pressure sensor is reported with nonwoven fabrics as both the electrode (printed with MXene interdigitated electrode) and sensing (coated with MXene/silver nanowires) layers via a scalable screen-printing approach. Benefiting from the multi-layered porous structure, the sensor demonstrates good air permeability with high sensitivity (770.86–1434.89 kPa⁻¹), a wide sensing range (0–100 kPa), fast response/recovery time (70/81 ms), and low detection limit (≈1 Pa). Particularly, this sensor can detect full-scale human motion (i.e., small-scale pulse beating and large-scale walking/running) with high sensitivity, excellent cycling stability, and puncture resistance. Additionally, the sensing layer of the pressure sensor also displays superior sensitivity to humidity changes, which is verified by successfully monitoring human breathing and spoken words while wearing a sensor-embedded mask. Given the outstanding features, this breathable sensor shows promise in the wearable electronic field for body health monitoring, sports activity detection, and disease diagnosis.     

A general stochastic clustering method for automatic cluster discovery

Finding clusters in data is a challenging problem. Given a dataset, we usually do not know the number of natural clusters hidden in the dataset. The problem is exacerbated when there is little or no additional information except the data itself. This paper proposes a general stochastic clustering method that is a simplification of nature-inspired ant-based clustering approach. It begins with a basic solution and then performs stochastic search to incrementally improve the solution until the underlying clusters emerge, resulting in automatic cluster discovery in datasets. This method differs from several recent methods in that it does not require users to input the number of clusters and it makes no explicit assumption about the underlying distribution of a dataset. Our experimental results show that the proposed method performs better than several existing methods in terms of clustering accuracy and efficiency in majority of the datasets used in this study. Our theoretical analysis shows that the proposed method has linear time and space complexities, and our empirical study shows that it can accurately and efficiently discover clusters in large datasets in which many existing methods fail to run.     

一种社交网络虚假信息传播控制方法

针对社交网络中日渐泛滥的虚假信息,提出了一种社交网络虚假信息传播控制方法Fidic,针对社交网络中虚假信息传播时途经的用户序列,该方法基于PageRank的思想并结合用户传播虚假信息时的指向关系来对用户进行评级,用户的评级越高表明其在虚假信息传播过程中起到的作用越大.该方法通过控制高评级用户的传播行为从而缩小虚假信息传播的覆盖面,最终达到遏制甚至消除虚假信息传播的目的.实验证明该方法既可以获得较高的精度,而且方便可行,具有较高实用价值.     

Photophysical and photochemical investigations on triazole ring linked chalcone containing polymethacrylates

A series of polymethacrylates containing triazole ring linked chalcone were designed and synthesized. These conjugated chalcone polymers are modulate under the light depending on the pendant substituents (–N(CH₃)₂, CH₃, OCH₃, Br, H & NO₂). The steady-state absorption and emission spectroscopic techniques have been used to investigate intramolecular charge transfer (ICT) behaviour of the polymers. Absorption spectra in different organic solvents demonstrate the presence of ICT in polymer 5a. On the other hand, its excited singlet state exhibits high ICT characters as manifested by polarity of solvents. Interestingly, ICT emission maximum is strongly red shifted (53 nm). The emission intensities of fluorophore are compared with those measured after crosslinking, suggesting that the statically quenched fluorophores are entirely non-emissive. The emission decay of polymer 5a displays bi-exponentially with life time of 0.52 and 1.62 ns ascribed to presence of locally excited ICT state. Cyclic voltammogram demonstrates irreversible oxidation potential at 0.9 V indicates formation mono-radical cation.     

Synthesis and Characterization of NiO Nano‐Spheres by Templating on Chitosan as a Green Precursor

In this study, nickel oxide was prepared through the calcination of extrusion dripped chitosan/nickel nitrate beads. The morphology and structural properties of the products were studied using various characterization techniques. Uniformly distributed nickel oxide was formed as observed from the studies of surface morphology where the processing parameters play a huge role on the resulting morphology. TEM results have shown that nickel oxide with crystallite sizes of 10–30 nm was obtained. The Fourier‐transform infrared spectra studies show an intense peak at 525 cm^?1, which is attributed to the vibration of Ni–O bond. Furthermore, the XRD results show NiO diffraction peaks correspond to (111), (200), (220), (311), and (222) which indicates that a bunsenite structure with a face‐centered cubic phase was produced in this study. The usage of 500°C as the lower limit in this study is justified due to the complete removal of the templating material as seen in the thermalgravimetric analysis studies. Furthermore, it was obtained that the largest surface area of nickel oxide synthesized using this technique is 48.024 m²/g with pore sizes of 19.843 nm. The usage of chitosan as a green template for the synthesis of nanoparticles has shown promising results which allows a more economical and sustainable approach for the fabrication of nanomaterials.     

Microbial fuel cell-based sensor for Enterobacter sp. KBH6958 activity monitoring during hydrogen production: the effects of pH and glucose concentration

Journal of Applied Electrochemistry - A microbial fuel cell (MFC) is an electricity-generating device utilising electrochemically active microorganisms as biocatalysts. Using MFC as a biosensor to...     

Superabsorbent polymer prepared using carboxymethyl cellulose derived from Ceiba pentandra (L.) Gaertn. (kapok) cotton

Superabsorbent polymers (SAPs) were synthesized by grafting acrylic acid and butyl acrylate onto carboxymethyl cellulose (CMC) modified from Ceiba pentandra (L.) Gaertn. (kapok) cotton, with N,N′‐methylenebisacrylamide as a crosslinker and ammonium persulphate as initiator. The effect of distilled water, saline solution, and applied pressure on superabsorbent was investigated. The product exhibited the maximum water absorbency of 554 g/g in distilled water and 96 g/g in saline solution. The SAP achieved the highest water absorbency under load of 83 g/g under applied pressure of 7.6 g/cm². The kapok cotton modified cellulose‐based SAP exhibited stronger gel strength than the SAP based on commercial CMC. This is probably due to the higher grafting efficiency (78.3%) of the former. The SAP was characterized by FTIR analysis, thermogravimetric analysis, and scanning electron microscopy. Thermogravimetric analysis results showed that the SAP, with AA and BA grafted onto CMC, had better thermal stability than CMC alone. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40808.     

COSMO-RS:An ionic liquid prescreening tool for gas hydrate mitigation

Recently ionic liquids(ILs) are introduced as novel dual function gas hydrate inhibitors. However, no desired gas hydrate inhibition has been reported due to poor IL selection and/or tuning method. Trial error as well as selection based on existing literature are the methods currently employed for selecting and/or tuning ILs. These methods are probabilistic, time consuming, expensive and may not result in selecting high performance ILs for gas hydrate mitigation. In this work, COSMO-RS is considered as a prescreening tool of ILs for gas hydrate mitigation by predicting the hydrogen bonding energies(E_(HB)) of studied IL inhibitors and comparing the predicted E_(HB) to the depression temperature(?) and induction time. Results show that, predicted EHBand chain length of ILs strongly relate and significantly affect the gas hydrate inhibition depression temperature but correlate moderately(R = 0.70) with average induction time in literature. It is deduced from the results that, ? increases with increasing IL EHBand/or decreases with increasing chain length. However, the cation–anion pairing of ILs also affects IL gas hydrate inhibition performance. Furthermore, a visual and better understanding of IL/water behavior for gas hydrate inhibition in terms of hydrogen bond donor and acceptor interaction analysis is also presented by determining the sigma profile and sigma potential of studied IL cations and anions used for gas hydrate mitigation for easy IL selection.