The catalytic deacidification of acidic crude oil using Cu-doped alkaline earth metal oxide catalysts

Naphthenic acids (NAs) tend to cause operational problems that can lead to the deactivation of catalysts. To overcome the problem, catalytic deacidification was introduced utilizing an ammonia solution in ethylene glycol with the aids of alkaline earth metal catalyst with alumina as a support. The initial total acid number observed for NAs in n-dodecane was 4.21 mg KOH/g. In total, 1,000 mg/L of 0.4% NH₃-EG were used as the acid removal agent. Calcium, barium, and magnesium catalysts were tested in this study. The results showed Cu/Ca/Al₂O₃ was found to be the best catalyst that could be used to enhance the reaction.     

Bacillus subtilis: As an Efficient Bacterial Strain for the Reclamation of Water Loaded with Textile Azo Dye,Orange II

The azo dye orange II is used extensively in the textile sector for coloring fabrics. High concentrations of it are released into aqueous environments through textile effluents. Therefore, its removal from textile wastewater and effluents is necessary. Herein, initially, we tested 11 bacterial strains for their capabilities in the degradation of orange II dye. It was revealed in the preliminary data that B. subtilis can more potently degrade the selected dye, which was thus used in the subsequent experiments. To achieve maximum decolorization, the experimental conditions were optimized whereby maximum degradation was achieved at: a 25 ppm dye concentration, pH 7, a temperature of 35 °C, a 1000 mg/L concentration of glucose, a 1000 mg/L urea concentration, a 666.66 mg/L NaCl concentration, an incubation period of 3 days, and with hydroquinone as a redox mediator at a concentration of 66.66 mg/L. The effects of the interaction of the operational factors were further confirmed using response surface methodology, which revealed that at optimum conditions of pH 6.45, a dye concentration of 17.07 mg/L, and an incubation time of 9.96 h at 45.38 °C, the maximum degradation of orange II can be obtained at a desirability coefficient of 1, estimated using the central composite design (CCD). To understand the underlying principles of degradation of the metabolites in the aliquot mixture at the optimized condition, the study steps were extracted and analyzed using GC-MS(Gas Chromatography Mass Spectrometry), FTIR(Fourier Transform Infrared Spectroscopy), ¹H and carbon 13 NMR(Nuclear Magnetic Resonance Spectroscopy). The GC-MS pattern revealed that the original dye was degraded into o-xylene and naphthalene. Naphthalene was even obtained in a pure state through silica gel column isolation and confirmed using ¹H and ¹³C NMR spectroscopic analysis. Phytotoxicity tests on Vigna radiata were also conducted and the results confirmed that the dye metabolites were less toxic than the parent dye. These results emphasize that B. subtilis should be used as a potential strain for the bioremediation of textile effluents containing orange II and other toxic azo dyes.     

Green Tea Catechins: Nature’s Way of Preventing and Treating Cancer

Green tea’s (Camellia sinensis) anticancer and anti-inflammatory effects are well-known. Catechins are the most effective antioxidants among the physiologically active compounds found in Camellia sinesis. Recent research demonstrates that the number of hydroxyl groups and the presence of specific structural groups have a substantial impact on the antioxidant activity of catechins. Unfermented green tea is the finest source of these chemicals. Catechins have the ability to effectively neutralize reactive oxygen species. The catechin derivatives of green tea include epicatechin (EC), epigallocatechin (EGC), epicatechin gallate (ECG) and epigallocatechin gallate (EGCG). EGCG has the greatest anti-inflammatory and anticancer potential. Notably, catechins in green tea have been explored for their ability to prevent a variety of cancers. Literature evidence, based on epidemiological and laboratory studies, indicates that green tea catechins have certain properties that can serve as the basis for their consideration as lead molecules in the synthesis of novel anticancer drugs and for further exploration of their role as pharmacologically active natural adjuvants to standard chemotherapeutics. The various sections of the article will focus on how catechins affect the survival, proliferation, invasion, angiogenesis, and metastasis of tumors by modulating cellular pathways.     

Toxicity and Metabolism of Layered Double Hydroxide Intercalated with Levodopa in a Parkinson’s Disease Model

Layered hydroxide nanoparticles are generally biocompatible, and less toxic than most inorganic nanoparticles, making them an acceptable alternative drug delivery system. Due to growing concern over animal welfare and the expense of in vivo experiments both the public and the government are interested to find alternatives to animal testing. The toxicity potential of zinc aluminum layered hydroxide (ZAL) nanocomposite containing anti-Parkinsonian agent may be determined using a PC 12 cell model. ZAL nanocomposite demonstrated a decreased cytotoxic effect when compared to levodopa on PC12 cells with more than 80% cell viability at 100 μg/mL compared to less than 20% cell viability in a direct levodopa exposure. Neither levodopa-loaded nanocomposite nor the un-intercalated nanocomposite disturbed the cytoskeletal structure of the neurogenic cells at their IC₅₀ concentration. Levodopa metabolite (HVA) released from the nanocomposite demonstrated the slow sustained and controlled release character of layered hydroxide nanoparticles unlike the burst uptake and release system shown with pure levodopa treatment.     

Synthesis of Boron Nitride Microtubes and Formation of Boron Nitride Nanosheets

Boron nitride microtubes are synthesized in a dual zone quartz tube furnace at 1200°C with ammonia as a reaction atmosphere. Field emission scanning electron microscopy (FE-SEM) results show a unique cone-like morphology of the tubes with larger internal space and thin walls structure. The diameters of the tubes were found to be in the range of 1 to ～2 µm with the walls thickness estimated to be from 10 to 100 nm. XPS survey shows N 1 s and B 1 s peaks at 398.7 and 191 eV, respectively, that represent h-BN in the sample. Raman spectroscopy indicates a high-intensity peak at 1372.53 (cm^?1) that corresponds to the E_2g mode of h-BN. Along with the novel tubular morphology of boron nitride microtubes, the present work also explains a mechanism for the formation of boron nitride nanosheets (from boron nitride microtubes) found in the FE-SEM results of the current sample.     

EIS study of corrosion behavior of metallic materials in ethanol blended gasoline containing water as a contaminant

In the present paper, the effects of ethanol as a gasoline additive and water as a contaminant on the corrosion behavior of metallic components of a fuel delivery system were investigated. Electrochemical impedance spectroscopy (EIS) testing was performed in both water-free and water contaminated gasoline containing 0%, 5%, 10% and 15% ethanol without the addition of any supporting electrolyte. The surface of the specimens examined in 10% ethanol blended gasoline was observed by scanning electron microscope to understand what types of corrosion attack occurred. The results revealed that the addition of ethanol to gasoline fuel decreased the solution resistance and polarization resistance values of the specimens, resulting in an increase in the corrosion rates of these specimens in ethanol blended gasoline. Water contaminant caused a decrease in the polarization resistance of the ferrous specimens, whereas the observed behavior in others was reversed. Among the investigated metallic materials, the brazing alloy fared the best while Al 6061 alloy showed satisfactory corrosion resistance compared to the rest of the materials in both water-free and water-contaminated ethanol blended gasoline. Moreover, no localized attack was observed in corrosion products.     

Application of Taguchi method for the optimization of Fe2+ removal from contaminated synthetic groundwater using a rotating packed bed contactor

Malaysia contains elevated levels of iron in shallow groundwater in the range of 3–7 mg Fe/L compared to the USEPA safe limit of 0.3 mg Fe/L. Air Kelantan Sdn Bhd in Malaysia uses the ‘River Bank Filtration’ (RBF) technology to harvest hyporheic water. The RBF treatment removes the turbidity of the river water through the river bed acting as a filter, but is unable to remove the Fe from the harvested water. This work proposes a technology to reduce Fe concentration in the extracted water using granular activated carbon in a laboratory‐scale rotating packed bed contactor (RPBC). The Taguchi method was used for optimizing the operating conditions for the adsorption of Fe onto activated carbon in the RPBC system. Taguchi optimization results showed that a removal efficiency of 87% Fe from a 50 mg Fe/L concentration could be achieved by a RPBC at an initial pH of 6.5, a feed rate of 40 L/h, a rotating speed of 1600 rpm and a packing density of 357 kg/m³.     

Rheological properties of poly(vinyl chloride) / epoxidized natural rubber blends. Part II: The effect of processing variables

The effect of processing variables on the rheological properties of PVC/ENR blends was investigated. The role of crosslinking in determining the flow behavior of blends was also examined by means of dynamically cured blends. It was found that PVC/ENR blends yield melts that are power law fluids. The flow of the melts improves with an increase in temperature and shear rate. However, the introduction of crosslinks reverses this trend, although under more rigorous conditions, the influence of crosslinks is superseded, and subsequently, flow becomes shear rate and temperature dependent. PVC/ENR systems also manifested elastic phenomena. The dependence of the elastic phenomena such as die swell and melt fracture on L/D ratio of the die was demonstrated.     

A literatu rereview on the improvement strategies of passive design for the roofing system of the modern house in a hot and humid climate region

Increase of indoor temperature compared with outdoor temperature is amajor concern in modern house design. Occupants suffer from this uncomfortable condition because of over-heating indoor temperature. Poor passive design causes heat to be trapped, which influences the rise in indoor temperature. The upper part, which covers the area of the roof, is the most critical part of the house that is exposed to heat caused by high solar radiation and high emissivity levels. During daytime, the roof accumulates heat, which increases the indoor temperature and affects the comfort level of the occupants. To maintain the indoor temperature within the comfort level, most house designs usually depend on mechanical means by using fans or air conditioning systems. The dependence on amechanical ventilation system could lead to additional costs for itsinstallation, operation, and maintenance. Thus, this study concentrates on reviews on passive design and suggests recommendations for future developments. New proposals or strategies are proposed to improve the current passive design through ventilated and cool roof systems. It is possible to achieve the comfort level inside a house throughout the day by reducing the transmitted heat into the indoor environment and eliminating the internal hot air. These recommendations could become attractive strategies in providing a comfortable indoor temperature to the occupants as well as inminimizing energy consumption.