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1.
Andrea Mariela Araya-Sibaja Valdir Soldi Carlos Eduardo Maduro Campos Simone Gonçalves Cardoso 《Drug development and industrial pharmacy》2015,41(5):851-858
Progesterone is a natural hormone steroid used in humans for several treatments and in livestock for artificial insemination, which exhibits two polymorphic forms at ambient conditions: form 1 and form 2. Form 2 is metastable and more soluble than form 1; however, it is not suitable to use as powder raw material because it transforms into form 1 by the effects of grinding. A polymorphic screening of progesterone based on polymer-induced heteronucleation method was performed as an alternative to prepare the metastable form. Polyvinyl alcohol, hydroxypropyl methylcellulose (HPMC), dextran, gelatin, polyisoprene (PI) and acrylonitrile-butadiene (NBR) copolymer were used. Crystals were prepared from 0.5, 10 and 40?mg/mL solutions in acetone at room temperature by solvent evaporation. The samples were characterized by X-ray powder diffraction, differential scanning calorimetry (DSC), scanning electron microcopy and attenuated total reflectance infrared Fourier transform spectroscopy. Form 1 was nucleated from 40?mg/mL solutions on the six polymers and from 10?mg/mL solutions on PI and NBR. The mixture of form 1 and form 2 was obtained from 10?mg/mL solution on HPMC, dextran and gelatin and from 0.5?mg/mL solution crystallizations. Therefore, the polymeric devices, which crystallized the metastable and more soluble polymorph (2) of progesterone, would be a promissory alternative for the pharmaceutical applications. 相似文献
2.
Jun Okamoto Jr. Valdir Grassi Jr. Paulo Faria Santos Amaral Benedito Geraldo Miglio Pinto Daniel Pipa Gustavo Pinto Pires Marcus Vinicius Maciel Martins 《Journal of Intelligent and Robotic Systems》2012,66(1-2):23-35
Inspection for corrosion of gas storage spheres at the welding seam lines must be done periodically. Until now this inspection is being done manually and has a high cost associated to it and a high risk of inspection personel injuries. The Brazilian Petroleum Company, Petrobras, is seeking cost reduction and personel safety by the use of autonomous robot technology. This paper presents the development of a robot capable of autonomously follow a welding line and transporting corrosion measurement sensors. The robot uses a pair of sensors each composed of a laser source and a video camera that allows the estimation of the center of the welding line. The mechanical robot uses four magnetic wheels to adhere to the sphere’s surface and was constructed in a way that always three wheels are in contact with the sphere’s metallic surface which guarantees enough magnetic atraction to hold the robot in the sphere’s surface all the time. Additionally, an independently actuated table for attaching the corrosion inspection sensors was included for small position corrections. Tests were conducted at the laboratory and in a real sphere showing the validity of the proposed approach and implementation. 相似文献
3.
Andrea M. A. Araya‐Sibaja Cinira Fandaruff Carlos E. M. Campos Valdir Soldi Simone G. Cardoso Silvia L. Cuffini 《Scanning》2013,35(4):213-221
In this article, morphology of progesterone polymorphs prepared by polymer‐induced heteronucleation (PIHn) technique was studied. Hydroxypropyl methylcellulose(HPMC), such as dextran T‐500 and gelatin G‐9382, polyisoprene (PI), and acrylonitrile/butadiene copolymer (NBR) were used as substrates. The crystallizations were performed by solvent evaporation at room temperature from 0.5, 10, and 40 mg/ml solutions in chloroform and acetone. Progesterone polymorphs were identified by X‐ray diffraction. Differential scanning calorimetry and total attenuated reflectance infrared spectroscopy were used as complementary techniques in the identification. Depending on the polymeric matrix and the concentration used, form 1, form 2, or mixture of both polymorphs were obtained. Scanning electron microscopy pictures evidenced difference in morphology and in homogeneity of the two progesterone polymorphs. These polymorphs prepared by PIHn, did not present a distinctive morphology that allows identifying polymorph by its crystal habit. Hence, polymeric matrix induced the crystallization, affecting polymorphism and morphology. SCANNING 35:213‐221, 2013. © 2012 Wiley Periodicals, Inc. 相似文献
4.
Albuquerque Gabriela B. M. L. Silva Valdir P. Rodrigues Joo Paulo C. 《Fire Technology》2022,58(2):737-775
Fire Technology - Reinforced concrete beams lose resistance at high temperatures and so as to guarantee their good performance, it is mandatory to consider this accidental action in design. As an... 相似文献
5.
Valdir Mano Maria Elisa Scarpelli Ribeiro e Silva Niccoletta Barbani Paolo Giusti 《应用聚合物科学杂志》2004,91(1):501-505
Blends of poly(N‐isopropylacrylamide) (PNIPAM) and an ethylene/vinyl alcohol copolymer (EVAL) were obtained through casting from dimethyl sulfoxide (DMSO) solutions and phase inversion in 50/50 DMSO/H2O solutions. The miscibility and morphology of the PNIPAM/EVAL blends were investigated with thermal and morphological analysis. Differential scanning calorimetry indicated that the crystallinity of EVAL decreased with increasing PNIPAM content and that the blends cast from DMSO/H2O solutions were miscible in the melt state. Measurements of the melting point depression allowed the determination of the interaction energy density (B) and Flory–Huggins interaction parameter (χ12) with the Nishi–Wang equation. The negative B and χ12 values obtained were examined in terms of the specific intermolecular interactions between the polymers. Scanning electron micrographs revealed that blends obtained by the casting method led to dense membranes, whereas the phase‐inversion method rendered typical macroporous membranes. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 501–505, 2004 相似文献
6.
Andrea Granada Issei Otsuka Thiago Caon Marcos Antonio Segatto Silva Valdir Soldi Redouane Borsali 《Journal of Polymer Research》2017,24(12):226
Nanoparticles based on block copolymers of oligosaccharides [β-cyclodextrin (βCyD) and maltoheptaose (Mal7)] and poly(ε-caprolactone) (PCL) were prepared by microphase inversion method. Zeta-potential, particle size measurements and morphological analysis of drug-free and drug-loaded nanoparticles were performed by using, respectively, laser-doppler anemometry, dynamic and static light scattering and transmission electron microscopy. ρ-Ratio values were correlated with transmission electron microscopy observations. Both types of amphiphilic block copolymers, βCyD-b-PCL5k and Mal7-b-PCL5k, self-assembled in water to form spherical vesicles, presented a hydrodynamic diameter of 72 and 34 nm, respectively. The incorporation of drugs into nanoparticles did not affect significantly the particle size for βCyD-b-PCL5k-based nanoparticles with progesterone, unlike the other tested systems. On the other hand, all nanoparticles (with and without drug) were negatively charged. Both nanoparticulate systems showed high drug loading efficiency (higher than 95%), confirming their suitability as delivery system for lipophilic drugs. 相似文献
7.
8.
Extended generalized shuffle (EGS) networks are a wide class of interconnection networks introduced by Richards (1993). In this work, we study the blocking performance of EGS networks under point-to-multipoint traffic. Two new routing algorithms for multicast connections in EGS networks are defined, and a theorem proving that these algorithms construct minimum-cost connection trees is enclosed. Simulation results show that the blocking performance of EGS networks under multicast traffic is much better than that of three-stage Clos networks of equal complexity 相似文献
9.
Jos R. S. Rodrigues Akira Kaito Valdir Soldi Alfredo T. N. Pires 《Polymer International》1998,46(2):138-142
The microscopic behaviour of blends of poly(ethylene oxide) with two different low molecular weight liquid crystals (LC) was studied in order to evaluate miscibility. One of the liquid crystal components had a phase transition temperature lower than the melting temperature of poly(ethylene oxide) (PEO), and the other a higher value. The low molecular weight liquid crystal components were 4-cyano-4′-n-heptylbiphenyl (7CB) and p-cyanophenyl p-pentyloxybenzoate (pCP). Thermal analysis and polarized optical and scanning electron microscopy were employed. The melting temperature (Tm) depression of PEO increased with LC content in the blend, suggesting that the PEO was miscible with both liquid crystals in the isotropic phase. The spherulitic structural morphology of the semicrystalline components is affected by the presence of liquid crystals. © 1998 SCI. 相似文献
10.
In this study gliadin solutions were crosslinked with 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride/N-hydroxysuccinimide (EDC/NHS) and cysteine. The filmogenic solutions were studied through rheological, sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) and FTIR analysis. Gliadin modified by EDC/NHS showed lower viscosity values when compared with the gliadin/cysteine system and the non-modified gliadin system. Determination of amino groups in gliadin modified by EDC/NHS was carried out through the trinitrobenzenesulfonic acid (TNBS) method. The cast films were evaluated by FTIR analysis in order to detect structural changes in the secondary structure of protein. SDS-PAGE showed the formation of higher protein aggregates, indicating that cysteine promotes gliadin polymerization through covalent bonds (disulfide bonds). The TNBS analysis showed that non-chemically modified gliadin had higher amounts of ε-amino groups when compared with gliadin treated with EDC/NHS; however, both systems revealed similar amounts of amino groups for the whole range of glycerol content. The FTIR spectra for the films showed that the two crosslinking agents act by different mechanisms, promoting changes in the secondary structure of gliadin. 相似文献