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1.
The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m?2 and 45 W m?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m?1 to 30.2 MPa and 158 J m?1, respectively. Copyright © 2003 Society of Chemical Industry 相似文献
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BaFe12O19/SiO2-B2O3微晶玻璃陶瓷的制备和微波性能 总被引:1,自引:0,他引:1
采用柠檬酸sol-gel工艺合成了BaFe12O19/SiO2-B2O3微晶玻璃陶瓷,研究了SiO2-B2O3玻璃的含量,Ba/Fe原子比和热处理温度对体系析出晶相的影响,以及介电常数和磁异率在1MHz-6GHz频率范围的变化规律,结果表明,休系中SiO2-B2O3玻璃的含量和Ba/Fe比越高,BaF312O19相的析出越困难,前驱体合适的热处理温度为1000℃,介电常数和磁导率基本上随测试频率的增而加下降;介电损耗的最大值为0.43,磁损耗较小。 相似文献
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The cooling and solidification of melted drops during their movement in an immiscible cooling medium is widely employed for granulation in the chemical industry, and a study of these processes to provides a basis for the design of the granulation tower height and the temperature of the cooling medium is reported. A physical model of the cooling and solidification of the drop is established and the numerical calculation is performed. The influences of the key factors in the solidification, i.e., Bi number, drop diameter, temperature of the cooling medium, etc. are presented. The cooling and solidification during wax granulation in a water‐cooling tower and during urea granulation in an air‐cooling tower (spraying tower) are described in detail. Characteristics of the solidification and temperature distribution within the particle at different times are shown. The model and calculations can be used for structure design of the granulation tower and optimization of the operation parameters. 相似文献
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Wei Li Zhang Wei Pan Bin Luo Xi Hua Zou Meng Yao Wang 《Photonics Technology Letters, IEEE》2008,20(9):712-714
A theoretical construction of one-to-many (OTM) and many-to-one (MTO) chaos synchronization communications using semiconductor lasers is presented. One center laser provides strong injections (strong link) to other side lasers, and the side lasers also provide weak injections (weak link) to the center one. Simulation results show that the side lasers synchronize with the center laser through injection-locking. In addition, messages transmitted via the strong links or the weak links experience strong chaos pass filtering, enabling us to realize OTM and MTO communications. 相似文献
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本文对八种新型功能晶体Li2B4O7、Bi12TiO20、Bi12GeO20、Bi12GeO20、Bi4Ge3O12、Sr1-xBaxNb2O6(x=0.33,0.48)、LiTaO3等在130~973K范围内的比热行为及其与相变、组分之间的关系进行了实验研究,给出了比热的多项式拟合方程,并与用纽曼-卡普定律及用Wikelmann经验方程的比热计算值作了对比,为晶体比热的估算提供了依据和方法。 相似文献