Reaction environment self-modification on low-coordination Ni2+ octahedra atomic interface for superior electrocatalytic overall water splitting

Large scale synthesis of high-efficiency bifunctional electrocatalyst based on cost-effective and earth-abundant transition metal for overall water splitting in the alkaline environment is indispensable for renewable energy conversion. In this regard, meticulous design of active sites and probing their catalytic mechanism on both cathode and anode with different reaction environment at molecular-scale are vitally necessary. Herein, a coordination environment inheriting strategy is presented for designing low-coordination Ni²⁺ octahedra (L-Ni-8) atomic interface at a high concentration (4.6 at.%). Advanced spectroscopic techniques and theoretical calculations reveal that the self-matching electron delocalization and localization state at L-Ni-8 atomic interface enable an ideal reaction environment at both cathode and anode. To improve the efficiency of using the self-modification reaction environment at L-Ni-8, all of the structural features, including high atom economy, mass transfer, and electron transfer, are integrated together from atomic-scale to macro-scale. At high current density of 500 mA/cm², the samples synthesized at gram-scale can deliver low hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) overpotentials of 262 and 348 mV, respectively.

     

羧甲基纤维素在铌矿物选别中抑制行为的研究

讨论了弱磁尾矿中的铌矿物浮选产物中羧甲基纤雏素对各种脉石矿物的抑制行为，建立了铌矿物选别的脉石抑制剂——羧甲基纤维素的吸附模型。     

《方正智绘》系统编辑地质图图件浅析

本文介绍用《方正智绘》系统成功地编辑地质图图件的过程,总结了采用该系统编辑地质图的特点和体会     

斜井提升钢丝绳的主要损伤及维护

刘桥一矿是一座产量1.4Mt/a的大型煤矿,分两个水平进行开采,其中二水平分南北翼.北翼二水平至一水平装备了一套JKY2.5/1.2-BS双滚筒串车提升绞车,钢丝绳型号为6T×7+NF-26-1670-光面-右互交.钢丝绳在使用后不久发现表面有均匀的点蚀麻坑,并慢慢扩大.针对这些现象,一矿进行了分析、研究,制定了相对应的管理办法,确保了运输提升的安全.     

改革秦砖汉瓦利废造地节能--烧结砖瓦功过评说

文章以翔实的史料证明烧结砖是中华文化的重要组成部分。以事实和数据分析了烧结砖的优异性能和不足，提出应以科学发展观的态度，实事求是的对待烧结砖和对其进行不断的改革，扬长避短．使其向利废、造田、节能、环保、大块的方向发展。     

中国尾矿坝地震安全度（5）──大石河尾矿坝现场测试成果及各测试方法间的相关研究

本文基于对中国大石河尾矿坝所完成的现场勘察，给出了三种原位测试数据（ＳＰＴ，ＣＰＲ和ＳＷＶ）的分析结果及其相关性研究成果。     

广州华厦大酒店改造

本案设计在注意避免过度装饰的设计的同时，巧妙运用华夏文化特色与现代手段结合．以符合酒店特定的文化语言要求，并注重以人为本，在现有的建筑条件下对酒店室内设计加以了改造。     

多阶变截面杆弯曲自由振动的计算

本文通过引入一组用矩阵形式表示的基本函数,分解了单阶杆的精确解,导出了相应于多阶变截面杆的频率方程和振型函数的通式,并通过计算机处理得到了精确数字解。最后还给出了数值解与理论解的比较。     

GE板形模型的功能及应用

梅钢热轧板厂于2002年引进了先进的凸度仪、平直度仪及GE板形模型,采用模型对窜辊量与弯辊力进行设定与闭环控制,板形质量有了量化指标与控制手段,通过几年的应用与实践,对板形模型的工作原理有了一定了解,文章论述了模型的设定策略、分配策略及控制策略,并阐述了该模型在负荷分配的优化、轧辊磨损量的优化、F4～F6工作辊原始辊型的优化及轧制计划的优化等方面的应用.     

Time-dependent reliability of ageing structures: an approximate approach

Concrete structures may deteriorate over time due to aggressive service environments, leading to a reduction in their strengths, stiffnesses and reliabilities. In general, the assessment of time-dependent reliability of ageing structures must consider uncertainties in structural deterioration as well as non-stationarities in the structural load processes. This paper develops an approximate method for assessing the impact of structural deterioration and non-stationary live loads on structures, which requires only low-dimensional integration and reduces the cost of assessing time-dependent reliability over a service life extending to 50 years significantly. This approximate method is demonstrated through several examples. The importance of non-stationarities in the resistance and load processes on time-dependent reliability is illustrated and the accuracy of the method is confirmed in several cases utilising Monte Carlo simulation.