Modification of structure and conductivity of nanohorns by toluene addition in carbon arc

Abstract

In the present work, we compare the structure and transport properties of carbon nanohorns (CNHs) synthesized by arc evaporation of graphite alone and with the addition of some portion of toluene. The materials have been investigated using transmission electron microscopy, Raman and infrared spectroscopies, thermogravimetric and BET analyses. The addition of a small amount of toluene during the evaporation of graphitic rod increases the length of CNHs, affects their hierarchical arrangement in aggregates and results in surface functionalization. All these features significantly enhance the conductivity of CNHs obtained with toluene additive in comparison with the pristine CNHs.     

The stability of a balloon support subjected to blasting

Journal of Mining Science -     

Prediction of High Methane-Recovery Regions and Gas Extraction Technology Based on Geodynamic Zoning of Bowels

An analysis is performed for the existing hypotheses and theories used for calculating the technological parameters of operations on methane extraction from coal seams. The priority of geodynamic processes in methane collector formation, as well as the methods applied for the morphometry and processing of the remote probing data are substantiated. The urgency is shown for the investigation into the autooxidation and other exothermic reactions proceeding in coal seams and leading to methane transition to the free state.