Synthesis and characterisation of a submicrometre silicon carbide powder

A beta-silicon carbide powder with a surface area of 30m²g^?l and a mean particle size of < 1μm was produced from the thermal conversion of silicon resin in an atmosphere of hydrogen. The amount of product increased with increasing iron content (0–2.1 wt%) and firing temperature (1200–1500°C). Chemical analysis, X-ray diffraction and i.r. absorption spectrometry were used to follow the conversion reaction.     

Synthesis and Physical Studies of the Organic Salts of Pindolol: Pindolol Benzoate and Pindolol 2-Methoxyphenylacetate

In order to investigate the formation of organic salts of drugs, two salts of pindolol were prepared using salt-forming agents which were crystalline and suitable for physical studies in the solid state. The stoichiometry of the products, pindolol benzoate and pindolol 2-methoxyphenylacetate, was established by elemental analysis. The precipitates formed were assessed by differential scanning calorimetry (DSC), thermogravimetry (TG), x-ray powder diffractometry (XRPD) and Fourier transform-infrared spectrometry (FT-IR). According to the TG and DSC curves, there was no water of crystallization in the precipitates, and the products were thermally stable. Both precipitates gave one sharp melting endotherm which differed from the endotherms of the starting compounds. The x-ray dipaction pattern of the precipitates direred clearly from those of the starting materials, acid and base. The products showed absorption by FT-IR typical of carboxylic acid salts at about 1640-1540 cm^-1. The carbonyl absorption indicative of the carboxylic acid group of benzoic acid or 2-methonyphenylacetic acid was not detectable in the spectra of the precipitates. All this indicates that two new crystalline organic salts (1:1) were formed during the syntheses.     

Electrical conductivity of concrete containing silica fume

The influence of silica fume on concrete properties represents an important technical research. In general, silica fume tends to improve both mechanical characteristics and durability of concrete. Thus the electrical properties of concrete containing silica fume can be studied to clarify its physical performance during hydration. The electrical conductivity of neat cement, mortar and concrete pastes was measured during setting and hardening. The ordinary Portland cement was partially replaced by different amounts of silica fume by weight. The changes in the electrical conductivity were reported during setting and hardening after gauging with water. The results of this study showed that the electrical conductivity can be used as an indication for the setting characteristics as well as the structural changes of the hardened pastes made with and without silica fume.     

Study of specific absorption rate (SAR) induced in two child head models and in adult heads using mobile phones

This paper gives a first comparison of specific absorption rate (SAR) induced in a child-sized (CS) head and an adult head using a dual-band mobile phone. In the second study, the visible human head is considered and comparison of SAR induced in a CS or child-like (CL) head and an adult head using a dual-band mobile phone is given. All the peaks of average SAR over a mass of 10 and 1 g in the head and the power budget are determined in the two comparisons using the finite-difference time-domain method. The differences between the results for adult and CS or CL heads are given at 900 and 1800 MHz. No important differences are noted for the peak SAR averaged over 10 g (SAR10 g), between the two adult head models, as well as between the two child head models. The peak SAR10 g in the brain of the CS or CL head is slightly more significant than that for the adult one.     

Room-Temperature Mid-, and Far-Infrared Absorption and Electrical Properties of Intercalated GaSe and TlInS<Subscript>2</Subscript> Crystals

We report room-temperature measurements of the mid- and far-IR absorption throughout the 400 – 4000 cm^?1 and 10 – 700 cm^?1 spectral ranges and the resistivity of layered p-GaSe and p-TlInS2 intercalated with Li⁺. Intercalation was performed by immersing Bridgman grown crystals in 0.5 M solutions of LiCl in distilled water at ambient conditions. The crystal structure and the stoichiometry of the grown crystals were determined by X-ray diffraction and XRF methods. It is shown that intercalation does not change the frequency of the IR-, and Raman active low-frequency“rigid layer” mode (GaSe), the space symmetry group or the lattice parameters of the crystals. It was found that for both crystals, the resistivity versus time dependencies are nearly the same. Three ranges in the resistivity-intercalation time dependencies were explained qualitatively. The resistivity increase due to intercalation was explained by assuming that the intercalated lithium ions act as ionized donors and compensate the host p-type crystal. The highest degree of compensation for GaSe and TlInS₂ crystals was achieved after intercalation during 12 and 10 days, respectively.     

Numerical modeling of energy balance equations in quantum well AlxGa1-xAs/GaAs p-i-n photodiodes

The energy balance equations coupled with drift diffusion transport equations in heterojunction semiconductor devices are solved modeling hot electron effects in single quantum well p-i-n photodiodes. The transports across the heterojunction boundary and through quantum wells are modeled by thermionic emission theory. The simulation and experimental current-voltage characteristics of a single p-i-n GaAs/Al _xGa_1-xAs quantum well agree over a wide range of current and voltage, The GaAs/Al_xGa_1-xAs p-i-n structures with multi quantum wells are simulated and the dark current voltage characteristics, short circuit current, and open circuit voltage results are compared with the available experimental data, In agreement with the experimental data, simulated results show that by adding GaAs quantum wells to the conventional cell made of wider bandgap Al_x Ga_1-xAs, short circuit current is improved, but there is a loss of the voltage of the host cell, In the limit of radiative recombination, the maximum power point of an Al_0.35Ga_0.65As/GaAs p-i-n photodiode with 30-quantum-well periods is higher than the maximum power point of similar conventional bulk p-i-n cells made out of either host Al_0.35Ga_0.65As or bulk GaAs material     

Photonic bandgap fibre oscillators and amplifiers

In the search for ever higher output power or energy from fibre oscillators or amplifiers a nowadays mature technology relies on enlarging the fibre mode area. Broadening of the core diameter, all other things being equal, inevitably yields a multimode fibre, thereby dramatically limiting the device usefulness. Various strategies have been deployed to design and manufacture single transverse mode fibre oscillators and amplifiers, among which making use of the so-called photonic bandgap effect to restrict the modal population seems promising. Helped by efficient and reliable numerical tools the design of large mode area singlemode photonic bandgap fibres is presented. Two fibres with 20-μm and 40-μm core diameter, both of them heavily doped with Yb³⁺ ions, have been fabricated by the widespread modified chemical vapour deposition process and are shown to behave properly when used as the core element of either continuous wave oscillators or femtosecond amplifiers. Good output beam quality (M² parameter spanning from 1.12 to 1.5 for the set of fibres studied) and high slope efficiency of 80% in cw oscillation regime are demonstrated. Furthermore the 40-μm core diameter fibre is shown to be resilient to tight bending down to 7.5-cm radius. The stack-and-draw process makes it easy to tailor the outer cladding so that a large numerical aperture can be reached. Subsequently, from this air-clad fibre, 500 fs 47 W pulses at 35 MHz are obtained from a two-stage chirped pulse amplification system.