Structure of polyurethane elastomers. X-ray diffraction and conformational analysis of MDI-propandiol and MDI-ethylene glycol hard segments

X-ray diffraction and conformational analysis have been used to investigate the structure of polyurethane hard segments prepared from diphenylmethane 4,4′-diisocyanate (MDI) with propandiol (PDO) and ethylene glycol (EDO) as chain extenders. The results are compared with those obtained previously for MDI-butandiol (BDO) hard segments. In the latter system, the poly(MDI-BDO) chains are fully extended with an all-trans conformation for the O(CH₂)₄O unit, and a monomer repeat of 18.95 Å. The unit cell is triclinic with a tilted base plane such that adjacent chains are staggered along the fibre axis. In contrast both poly(MDI-PDO) and poly(MDI-EDO) adopt unstaggered structures, i.e. the chains are in register and the unit cell base planes are perpendicular to the chain axis. The monomer repeats of 16.2 Å for poly(MDI-PDO) and 15.0 Å for poly(MDI-EDO) are shorter than the predicted repeats for fully-extended chains, indicating that these polymers have contracted conformations containing some gauche CH₂ groups. Conformational analysis shows that the 16.2 Å repeat for poly(MDI-PDO) can be achieved with the O(CH₂)₃O unit in the trans-gauche⁺-gauche⁺-trans or gauche⁺-trans-trans-gauche⁺ conformations. Similarly the 15.0 Å repeat for poly(MDI-EDO) is predicted for the gauche⁺-trans-gauche^? conformation for the O(CH₂)₂O unit. These conformations are of higher energy than the all-trans fully-extended chains. This may explain the higher crystalline perfection of the poly(MDI-BDO) hard segments, for which crystallization in the all-trans form will probably provide a greater driving force for phase separation.     

The prevalence of hepatitis B surface antigen in commercially prepared plasma products

Commercially available lots of plasma derivatives prepared between 1957 and 1975 were tested for hepatitis B surface antigen (HBsAg) by radioimmunoassay. In all, 69 per cent of lots of plasma protein fraction, 40 per cent of factor IX concentrate, 20 per cent of normal serum albumin, 13 per cent of antihemophilic factor, 3 per cent of fibrinogen, and 0.7 per cent of immune serum globulin lots tested were HBsAg-positive. There was great variation in the prevalence of HBsAg-positive lots of each product among the different manufacturers, reflecting not only differences in methods of processing plasma, but also differences in donor populations. Those manufacturers relying upon volunteer donor plasma or placental source material demonstrated lower rates of HBsAg-positive lots of final products than those relying upon commercial donor plasma. There was a marked decrease in the prevalence of positive lots during the period 1971 to 1973, coincident with the onset of routine plasma donor screening for HBsAg. However, current requirements for plasma screening have not resulted in totally HBsAg-free plasma products. Use of more sensitive and more reliable tests for HBsAg will probably reduce contamination of plasma pools with HBsAg to undetectable levels. Despite HBsAg-status, however, the "high-risk" plasma products (fibrinogen, antihemophilic factor, factor IX concentrate) must still be considered capable of transmitting hepatitis and used only with the strictest indications.     

Password memorability and security: empirical results

Users rarely choose passwords that are both hard to guess and easy to remember. To determine how to help users choose good passwords, the authors performed a controlled trial of the effects of giving users different kinds of advice. Some of their results challenge the established wisdom.     

A preliminary assessment of high speed tool steels manufactured from powder for rolling bearing materials

High speed tool steels manufactured from powder were assessed under arduous conditions of rolling contact and compared with conventional materials using an accelerated service simulation test. Metallographic investigations revealed factors influencing performance. Material manufactured from powder was generally found to be inferior to vacuum-remelted material due to poor structure, porosity, high interstitial nitrogen content and other manufacturing variables. Sound homogeneous material with uniform fine carbide distribution and gas content comparable with those of conventionally cast material appears potentially suitable for rolling bearings. The improved performance at elevated temperature may be due to metallographic changes, deleterious interstitial nitrogen content being reduced by a precipitation process.     

Long wavelength infrared 128×128 AlxGa1-xAs/GaAs quantum well infrared camera and imaging system

The authors discuss the development of a long-wavelength (8-14-μm) 128×128 Al_xGa_1-xAs/GaAs multiquantum well infrared (MQW IR) imaging system. Highly uniform, high-yield GaAs focal plane arrays, incorporating an integral grating structure for efficient optical coupling, were hybridized to CMOS multiplexers. Excellent imagery, with low noise, a noise equivalent differential temperature (NEΔT) of less than 10 mK, and a high image contrast signal-to-noise ratio, has been achieved. It is shown that figures of merit concerning array uniformity, such as yield, NEΔT, and maximum deliverable charge to the CMOS multiplexer are much more relevant variables that affect image quality than D*     

A neural-network technique for the retrieval of atmospheric temperature and moisture profiles from high spectral resolution sounding data

A novel statistical method for the retrieval of atmospheric temperature and moisture profiles has been developed and evaluated with simulated clear-air and observed partially cloudy sounding data from the Atmospheric InfraRed Sounder (AIRS) and the Advanced Microwave Sounding Unit (AMSU). The algorithm is implemented in two stages. First, a projected principal components (PPC) transform is used to reduce the dimensionality of and optimally extract geophysical profile information from the cloud-cleared infrared radiance data. Second, a multilayer feedforward neural network (NN) is used to estimate the desired geophysical parameters from the PPCs. For the first time, NN temperature and moisture retrievals are presented using actual microwave and hyperspectral infrared observations of cloudy atmospheres, over both ocean and land (with variable terrain elevation), and at all sensor scan angles. The performance of the NN retrieval method (henceforth referred to as the PPC/NN method) was evaluated using global Earth Observing System Aqua orbits colocated with European Center for Medium-range Weather Forecasting fields for seven days throughout 2002 and 2003. Over 350,000 partially cloudy footprints were used in the study, and retrieval performance was compared with the AIRS Science Team Level-2 retrieval algorithm (version 3). Performance compares favorably with that obtained with simulated clear-air observations from the NOAA88b radiosonde set of approximately 7500 profiles. The PPC/NN method requires significantly less computation than traditional variational retrieval methods, while achieving comparable performance.