Molar absorptivity of poly(methyl methacrylate) in the near-ultraviolet region

The molar absorptivities of methyl methacrylate monomer and of thermally polymerized, monomer-free poly(methyl methacrylate) have been measured in the range 2200–3000 Å, and smoothed values are presented at wavelength intervals of 20 Å over much of this range. Typical amounts of monomer present in a thermally polymerized bulk polymer and in films cast from CH₂Cl₂ solutions of the bulk polymer have been ascertained. The use of such absorptivity values to determine the amount of monomer present in polymer samples is evaluated.     

Properties of the glycerol acylating enzymes in microsomal preparations from the developing seeds of safflower (Carthamus tinctorius) and turnip rape (Brassica campestris) and their ability to assemble cocoa-butter type fats

Microsomal membrane preparations from the developing seeds of safflower (Carthamus tinctorius, var. Gila) and turnip-rape (Brassica campestris, var. Bele) catalyzed the assembly of triacylglycerols (triglycerides) from sn-glycerol 3-phosphate and acyl-CoA. The membrane preparations were used to assess the acyl specificity properties of the initial acylating enzymes—glycerol 3-phosphate acyltransferase (GPAT) and 1-acylglycerol 3-phosphate acyltransferase (lysophosphatidic acid acyltransferase, LPAAT)—that are responsible for the fatty acids at positions sn-1 and sn-2 of the sn-triacylglycerol, respectively. In spectrophotometric assays it was possible to evaluate, to some extent, how these enzymes will utilize unusual and foreign fatty acids that are not normally found in these particular plant species. The acylating enzymes from both plants used, to varying extents, a comprehensive range of acyl-CoA donor species and some kinetic properties of the substrates involved are presented. The enzymes from safflower, however, were generally the more selective, whereas the turnip-rape was less particular and could utilize a range of acyl substrates. The enzymes from both plants hardly utilized erucate (C22∶1), and the significance of this is discussed in terms of mechanisms which have evolved in order to exclude certain, perhaps detrimental, fatty acids from structural membrane lipids and dedicate them to storage lipid assembly. The ability of the microsomal preparations, from the developing seeds of both plants, to synthesize cocoabutter type fats was investigated. Microsomal membranes were incubated with glycerol 3-phosphate and equimolar amounts of palmitate, oleate and stearate. Safflower preparations catalyzed the construction of sn-triacylglycerol with largely palmitate, oleate and stearate in positions sn-1, 2 and 3, respectively. The selectivity for acyl species in rape was less pronounced, however, substantial saturated-unsaturated-saturated oils were still produced. The results are discussed in terms of the acyl selectivity properties of the glycerol acylating enzymes. It is evident that given the correct composition of fatty acids, the plant can produce cocoabutter or other exotic fats.     

The Story of Collective Action: The Emergence of Ideological Leaders,Collective Action Network Leaders,and Cross-Sector Network Partners in Civil Society

Collective action and community ecology theories frame this study of longitudinal interorganizational networks in Croatia during the country's political transition. As time progresses toward political stability, grass-roots organizing activities shift through participation in new networks. Although engaged cross-sector communication was important in early stages of the transformation, homophilous partnering emerged as the system stabilized. System stability left room for organizations to exit the collective action network but with costs associated with centralized organizing. Over time, organizations embodied roles as ideological leaders, collective action network leaders, and within-sector network partners. We offer a unique contribution to community ecology and collective action theories with a communication-centered framework that emphasizes the nature of communication in interorganizational networks over a 4-year period.     

Public Relations: State of the Field

Public relations is both a professional practice and a subfield of communication with its own research and theory base. Public relations is relatively young as an academic field, however, having developed identifiable theory in only about the last 50 years. The field of public relations is developing into a theoretically based area of applied communication that has the potential to inform several areas of communication/mass communication and to offer theoretic and conceptual tools useful in health, risk, and political communication, among others. Because many readers are unfamiliar with public relations theory and research, this article first reviews and summarizes theory-related scholarship in public relations, then categorizes and explains the theoretic trends in the field. The article concludes by demonstrating how one of public relations' theoretic/conceptual tools, issues management, can apply across all areas of applied communication.     

Thermoreversible Siloxane Networks: Soft Biomaterials with Widely Tunable Viscoelasticity

Polysiloxane elastomers represent a widely utilized soft material with excellent rubber‐like elasticity, biocompatibility, and biodurability; however, there is a lack of an effective and straightforward approach to manipulate the material's viscoelastic response. A facile hydrosilylation reaction is employed to integrate ureidopyrimidinone hydrogen‐bonding side‐groups into linear and crosslinked siloxane polymers to achieve biocompatible soft materials with a highly tunable viscoelastic relaxation timescale. Stacking of H‐bonded moieties is avoided in the designed macromolecular architectures with tight, side‐groups substituents. The obtained siloxane network features the presence of both covalent crosslinks and truly thermoreversible crosslinks, and can be formulated across a broad material design space including elastic solids, recoverable viscoelastic solids, and viscous liquids. The elastomers exhibit unique temperature‐dependent shape‐memory capability and show good cytocompatibility. Importantly, a deformed material's shape‐recovery occurs regardless of external triggering, and through manipulation of network formulations, the shape‐recovery timescale can be easily tuned from seconds to days, opening new possibilities for biomedical, healthcare, and soft material applications.     

Incompressible deformation estimation algorithm (IDEA) from tagged MR images

Measuring the 3D motion of muscular tissues, e.g., the heart or the tongue, using magnetic resonance (MR) tagging is typically carried out by interpolating the 2D motion information measured on orthogonal stacks of images. The incompressibility of muscle tissue is an important constraint on the reconstructed motion field and can significantly help to counter the sparsity and incompleteness of the available motion information. Previous methods utilizing this fact produced incompressible motions with limited accuracy. In this paper, we present an incompressible deformation estimation algorithm (IDEA) that reconstructs a dense representation of the 3D displacement field from tagged MR images and the estimated motion field is incompressible to high precision. At each imaged time frame, the tagged images are first processed to determine components of the displacement vector at each pixel relative to the reference time. IDEA then applies a smoothing, divergence-free, vector spline to interpolate velocity fields at intermediate discrete times such that the collection of velocity fields integrate over time to match the observed displacement components. Through this process, IDEA yields a dense estimate of a 3D displacement field that matches our observations and also corresponds to an incompressible motion. The method was validated with both numerical simulation and in vivo human experiments on the heart and the tongue.     

Effect of mixer geometry and operating conditions on mixing efficiency of a non-Newtonian fluid in a twin screw mixer

The effect of mixer speed, fluid inflow rate, and paddle angle was examined in a shortened geometry. 3D FEM simulation of non-Newtonian 2 g/100 mL carboxymethyl cellulose aqueous solution in the mixing region of a Readco continuous mixer was performed. Data gathered included velocity vectors, shear rate, and mixing index. Increasing mixer speed increased velocity magnitudes in the horizontal and vertical directions. Fluid inflow rate had little impact on velocity in the horizontal and vertical directions, but increased velocity in the axial direction and elongational contribution to the mixing index. All configurations showed areas of simple shear flow where the fluid experienced high shear rates. Staggering paddles increased the maximum axial velocity and shear rate. When successive paddles on the same screw are parallel, a zone was seen between the center of the paddle and the barrel wall which demonstrated efficient dispersive mixing.