Study of the effect of BDMA catalyst in the epoxy novolac curing process by isothermal DSC

Epoxy novolac/anhydride cure kinetics has been studied by differential scanning calorimetry under isothermal conditions. The system used in this study was an epoxy novolac resin (DEN431), with nadic methyl anhydride as hardener and benzyldimethylamine as accelerator. Kinetic parameters including the reaction order, activation energy and kinetic rate constants, were investigated. The cure reaction was described with the catalyst concentration, and a normalized kinetic model developed for it. It is shown that the cure reaction is dependent on the cure temperature and catalyst concentration, and that it proceeds through an autocatalytic kinetic mechanism. The curing kinetic constants and the cure activation energies were obtained using the Arrhenius kinetic model. A suggested kinetic model with a diffusion term was successfully used to describe and predict the cure kinetics of epoxy novolac resin compositions as a function of the catalyst content and temperature. Copyright © 2003 Society of Chemical Industry     

Tellurium clusters in channels of the porous silica ZSM-11

The distribution and structure of tellurium nanoclusters synthesized in crystal channels of the porous silica ZSM-11 are investigated using the maximum-entropy method and the Rietveld analysis. It is shown that the intercalated tellurium atoms are arranged in channels of the ZSM-11 zeolite not randomly but in the form of scraps of infinite chains similar to those observed in massive tellurium. The distances between the nearest neighbor tellurium atoms vary in the range 2.53(4)–2.70(3) ?. The clusters Te₄ are formed at the intersections of channels in the structure. These clusters have the form of distorted tetrahedra in which the tellurium atoms are separated by distances of 2.53(4) and 2.90(4) ?. Original Russian Text ? A.E. Lapshin, Yu.F. Shepelev, Yu.I. Smolin, E.A. Vasil’eva, 2008, published in Fizika i Khimiya Stekla.     

Thermodesorption of samarium from oxidized tungsten surface

Thermodesorption of samarium (Sm) atoms and samarium oxide (SmO) molecules from samarium films deposited in vacuum onto tungsten substrates covered with thin (<1 nm thick) layers of tungsten oxides has been studied. It is established that samarium reduces tungsten from its oxides. The parameters of Sm and SmO desorption from an oxidized tungsten surface are determined.     

Terbium-doped garnet single crystals as X-ray-sensitive phosphors

The spectra of luminescence induced by synchrotron radiation in the fundamental absorption range were measured at 10 and 300 K for Czochralski-grown bulk Y₃Al₅O₁₂ single crystals doped with Tb³⁺ ions and for (Tb,La,Gd)₃Ga₅O₁₂ single crystal films grown by liquid phase epitaxy from a PbO-B₂O₃ based supercooled solution melt on Gd₃Ga₅O₁₂ substrates.     

Is prostate specific antigen density an important prognostic indicator for patients with prostate cancer treated with external beam therapy?

The purpose of this study was to determine if prostate specific antigen density (PSAD) is a predictor of outcome following external beam radiotherapy for prostate cancer, and to compare it with other prognostic factors. Between January 1990 and December 1993, 205 patients with T1-T3 adenocarcinoma of the prostate received a radical course of external beam irradiation, with no prior or adjuvant hormonal therapy. All patients had pre- and post-treatment serum prostate specific antigen (PSA) evaluation. They were followed up for at least 24 months. PSAD was defined as the ratio of pre-treatment serum PSA to the prostate volume, as determined from CT treatment planning scans. Prostate volumes were calculated using the prostate ellipse formula. Median PSA density was 0.37, with a range 0.01-6.7. Biochemical failure was defined as three consecutive rises in serum PSA, regardless of the magnitude of elevation. 4-year biochemical disease-free survival (BDFS) for patients with PSAD < or = 0.3 was 60%, compared with 22% for patients with PSAD > 0.3 (p = < 0.001). In a multivariate analysis, pre-treatment PSA (p = < 0.001), Gleason score (p = 0.002), and stage (p = 0.03) were independent predictors of BDFS, while PSAD was not an important prognosticator (p = 0.62). Pre-treatment serum PSA is the most important prognosticator of BDFS, following external beam radiotherapy, for patients with prostate cancer. PSA density did not predict treatment outcome.     

The structure and function of platelet-activating factor acetylhydrolases

Platelet-activating factor acetylhydrolases (PAF-AHs, EC 3.1.1.47) constitute a unique and biologically important family of phospholipase A2s. They are related to neither the well-characterized secretory nor cytosolic PLA2s, and unlike them do not require Ca2+ for catalytic activity. The distinguishing property of PAF-AHs is their unique substrate specificity: they act on the phospholipid platelet-activating factor (PAF), and in some cases on proinflammatory polar phospholipids, from which they remove a short acyl moiety--acetyl in the case of PAF--located at the sn-2 position. Because PAF is found both in the plasma and in the cytosol of many tissues, PAF-acetylhydrolases are equally widely distributed in an animal organism. Recent crystallographic studies shed new light on the complex structure-function relationships in PAF-AHs.     

Structure formation in production of yttrium-silicate materials by the sol-gel method

Materials made from yttrium silicates were synthesized by the sol-gel method. The effect of the amount of yttrium oxide, which varied from 10 to 50% (molar content), and the water:alcoholate molar ratio was investigated. Structure formation and the character of crystallization of gels in heat treatment in the 650–1300°C range were investigated. __________ Translated from Steklo i Keramika, No. 1, pp. 3–6, January, 2007.     

Limit theorems for queueing systems with doubly stochastic poisson arrivals (Heavy traffic conditions)

We consider a single-server queueing system with a doubly stochastic Poisson arrival flow under heavy traffic conditions. We prove the convergence of the limiting stationary or periodic distribution to the exponential distribution. In a scheme of series, we consider the C-convergence of the waiting time process to a diffusion process with constant coefficients and reflection at the zero boundary. Examples of computation of the diffusion coefficient in terms of characteristics of the arrival flow and service time are given.