Microwave-Assisted Graphite-Support Synthesis of Imidazolones

5(4H)-Oxazolones react with ammonium acetate under microwave irradiation and using graphite as support in an eco-friendly process. The reaction was carried out under solvent-free conditions and the imidazolones were obtained quantitatively. Moreover the reaction time was reduced too.     

An adaptive tracking problem for a family of retarded time-delay plants

Most of the existing switching control techniques are developed specifically for finite-dimensional linear time-invariant (LTI) systems. In many practical applications, however, it is essential to take time delay into consideration in the modelling as the control system can be highly sensitive to delay. In this paper, a multi-model switching control algorithm is proposed for retarded time-delay systems. It is assumed that the plant is represented by a family of known multi-input multi-output, observable, LTI models with multiple delays in the states, and that corresponding to each model in the known family, there exists a high-performance finite-dimensional LTI controller. In addition, it is supposed that a bound on the magnitude of the external inputs and disturbances is available. It is then shown that the proposed switching controller can stabilize the uncertain system, and that under some mild conditions, output tracking can be achieved in the given problem setting. Copyright © 2007 John Wiley & Sons, Ltd.     

Preparation and properties of silicone‐containing poly(methyl methacrylate) gels

Poly(methyl methacrylate) (PMMA) gels with varying amounts of silicone and solvent and constant amounts of crosslinker were prepared by solution free radical crosslinking copolymerization of methyl methacrylate (MMA), ethylene glycol dimethacrylate (EGDM), tetraethoxysilane (TEOS) and vinyltriethoxysilane (VTES) comonomer systems. They were then studied in benzene at a total monomer concentration of 3.5 mol L^?1 and 70 °C. The conversion of monomer, volume swelling ratio, weight fraction and gel point were measured as a function of the reaction time, silicone concentration and benzene content up to the onset of macrogelation. Structural characteristics of the gels were examined by using equilibrium swelling in benzene, gel fraction and Fourier‐transform infrared (FTIR) analysis. The morphology of the copolymers was also investigated by SEM. Based on the obtained results, it was concluded that the FTIR data did not have the capacity to show the presence of the VTES or TEOS moiety in these kinds of copolymers. On the other hand, the variation of weight fraction of gel, W_g, and its equilibrium volume swelling ratio in benzene, q_v, exhibited the same behaviour as that of MMA/EGDM copolymers. Also, the dilution of the monomer mixture resulted in an increase in the gel point and swelling degree and a decrease in the percent of conversion and gel fraction. Finally, TEOS is not an ideal silicone compound for reaction in the MMA/EGDM copolymerization system, whereas VTES is a suitable silicone comonomer for this system and it has been proved useful. Copyright © 2005 Society of Chemical Industry     

Power-delay-product optimal repeater design for horizontal and vertical multilayer graphene nanoribbon interconnects

Journal of Computational Electronics - Power-delay-product optimal design of repeater size and number design for both horizontal and vertical multilayer graphene nanoribbon (MLGNR) interconnects is...     

An ant colony optimization algorithm for the bi-objective shortest path problem

Multi-objective shortest path problem (MOSP) is an extension of a traditional single objective shortest path problem that seeks for the efficient paths satisfying several conflicting objectives between two nodes of a network. MOSP is one of the most important problems in network optimization with wide applications in telecommunication industries, transportation and project management. This research presents an algorithm based on multi-objective ant colony optimization (ACO) to solve the bi-objective shortest path problem. To analyze the efficiency of the algorithm and check for the quality of solutions, experimental analyses are conducted. Two sets of small and large sized problems that generated randomly are solved. Results on the set problems are compared with those of label correcting solutions that is the most known efficient algorithm for solving MOSP. To compare the Pareto optimal frontiers produced by the suggested ACO algorithm and the label correcting algorithm, some performance measures are employed that consider and compare the distance, uniformity distribution and extension of the Pareto frontiers. The results on the set of instance problems show that the suggested algorithm produces good quality non-dominated solutions and time saving in computation of large-scale bi-objective shortest path problems.     

Prediction of hydrate equilibrium conditions using k-nearest neighbor algorithm to CO2 capture

Gas or clathrate hydrates are an important issue when they form in the oil and gas pipelines. Since the determination of the hydrate formation temperature and pressure is very difficult experimentally for every gas system and it is impossible in terms of cost and time approximately, mathematical models can be useful tools to overcome these difficulties. In this study, k-nearest neighbor model was used to predict the equilibrium conditions of hydrate formation in absorption and separation of carbon dioxide from flue gas mixture, containing carbon dioxide and nitrogen. At the training phase, temperature and composition data of nitrogen and carbon dioxide in the flue gas mixture at equilibrium conditions and the equilibrium pressures of hydrate formation were used as input and output, respectively. The error percentage less than 0.38% indicates the high accuracy of the proposed model. In this study, 80%, 85%, and 90% of the training data are examined for three numbers of nearest. For three numbers of used nearest (k = 1, k = 2 and k = 3), the value of k = 1 leads to the lowest error; so, it is selected as the best nearest in the presented model.     

Experimental investigation into Fe3O4/SiO2 nanoparticle performance and comparison with other nanofluids in enhanced oil recovery

Nanofluids because of their surface characteristics improve the oil production from reservoirs by enabling different enhanced recovery mechanisms such as wettability alteration, interfacial tension (IFT) reduction, oil viscosity reduction, formation and stabilization of colloidal systems and the decrease in the asphaltene precipitation. To the best of the authors’ knowledge, the synthesis of a new nanocomposite has been studied in this paper for the first time. It consists of nanoparticles of both SiO₂ and Fe₃O₄. Each nanoparticle has its individual surface property and has its distinct effect on the oil production of reservoirs. According to the previous studies, Fe₃O₄ has been used in the prevention or reduction of asphaltene precipitation and SiO₂ has been considered for wettability alteration and/or reducing IFTs in enhanced oil recovery. According to the experimental results, the novel synthesized nanoparticles have increased the oil recovery by the synergistic effects of the formed particles markedly by activating the various mechanisms relative to the use of each of the nanoparticles in the micromodel individually. According to the results obtained for the use of this nanocomposite, understanding reservoir conditions plays an important role in the ultimate goal of enhancing oil recovery and the formation of stable emulsions plays an important role in oil recovery using this method.     

A New Method Modifying Single Miller Feedforward Frequency Compensation to Drive Large Capacitive Loads: Putting an Attenuator in the Path

A new method to compensate three-stage amplifier to drive large capacitive loads is proposed in this paper. Gain Bandwidth Product is increased due to use an attenuator in the path of miller compensation capacitor. Analysis demonstrates that the gain bandwidth product will be improved significantly without using large compensation capacitor. Using a feedforward path is deployed to control a left half plane zero which is able to cancel out first non-dominant pole. A three stage amplifier is simulated in a 0.18 μm CMOS technology. The purpose of the design is to compensate three-stage amplifier loading 1000 pF capacitive load. The simulated amplifier with a 1000 pF capacitive load is performed in 3.3 MHz gain bandwidth product, and phase margin of 50. The compensation capacitor is reduced extremely compared to conventional nested miller compensation methods. Since transconductance of each stage is not distinct, and it is close to one another; as a result, this method is suitable low power design methodology.     

Improved Message Forwarding for Multi-Hop HaRTES Real-Time Ethernet Networks

Nowadays, switched Ethernet networks are used in complex systems that encompass tens to hundreds of nodes and thousands of signals. Such scenarios require multi-switch architectures where communications frequently occur in multiple hops. In this paper we investigate techniques to allow efficient multi-hop communication using HaRTES switches. These are modified Ethernet switches that provide real-time traffic scheduling, dynamic bandwidth management and temporal isolation between real-time and non-real-time traffic. This paper addresses the problem of forwarding traffic in HaRTES networks. Two methods have been recently proposed, namely Distributed Global Scheduling (DGS) that buffers traffic between switches, and Reduced Buffering Scheme (RBS), that uses immediate forwarding. In this paper, we discuss the design and implementation of RBS within HaRTES and we carry out an experimental validation with a prototype implementation. Then, we carry out a comparison between RBS and DGS using worst-case response time analysis and simulation. The comparison clearly establishes the superiority of RBS concerning end-to-end response times. In fact, with sample message sets, we achieved reductions in end-to-end delay that were as high as 80 %.