Detection of Pinosylvins in Solid Wood of Scots Pine Using Fourier Transform Raman and Infrared Spectroscopy

Abstract

Diffuse reflectance Fourier transform infrared (DRIFT) and near infrared (NIR) FT-Raman spectroscopy were used to detect pinosylvins in the wood of Pinus sylvestris L. trees. NIR FT-Raman spectroscopy offered the possibility of revealing pinosylvins simply by visual inspection of Raman spectra whereas DRIFT spectra needed a more complicated evaluation. Pinosylvin and resin acids from Scots pine were examined as to the possibility of their being the cause of observed spectral differences between sapwood and heartwood. Since pinosylvins are important compounds for the decay resistance of Scots pine wood, the detection of pinosylvins with Raman spectroscopy might be used to assess durability of wood products.     

Food selection associated with sense of coherence in adults

Background  

Favorable dietary habits promote health, whereas unfavorable habits link to various chronic diseases. An individual's "sense of coherence" (SOC) is reported to correlate with prevalence of some diseases to which dietary habits are linked. However, understanding what determines an individual's dietary preferences and how to change his/her behavior remains limited. The aim of the present study was to evaluate associations between dietary intake and SOC in adults.     

UVB Radiation Variably Affects n-3 Fatty Acids but Elevated Temperature Reduces n-3 Fatty Acids in Juvenile Atlantic Salmon (Salmo salar)

Temperature and ultraviolet B radiation (UVB 290–320?nm) are inextricably linked to global climate change. These two variables may act separately, additively, or synergistically on specific aspects of fish biochemistry. We raised Atlantic Salmon (Salmo salar) parr for 54?days in outdoor tanks held at 12 and 19?°C and, at each temperature, we exposed them to three spectral treatments differing in UV radiation intensity. We quantified individual fatty acid (FA) mass fractions in four tissues (dorsal muscle, dorsal and ventral skin, and ocular tissue) at each temperature?×?UV combination. FA composition of dorsal muscle and dorsal and ventral skin was not affected by UV exposure. Mass fractions of 16:0, 18:0, and saturated fatty acids (SFA) were greater in dorsal muscle of warm-reared fish whereas 18:3n-3, 20:2, 20:4n-6, 22:5n-3, 22:6n-3, n-3, n-6, polyunsaturated fatty acids (PUFA), and total FA were significantly higher in cold-reared fish. Mass fractions of most of the FA were greater in the dorsal and ventral skin of warm-reared fish. Cold-reared salmon exposed to enhanced UVB had higher ocular tissue mass fractions of 20:2, 20:4n-6, 22:6n-3, n-3, n-6, and PUFA compared to fish in which UV had been removed. These observations forecast a host of ensuing physiological and ecological responses of juvenile Atlantic Salmon to increasing temperatures and UVB levels in native streams and rivers where they mature before smolting and returning to the sea.     

Occupational posture exposure among construction electricians

The aim of this study is to record, objectively describe and compare working postures of Brazilian and Norwegian construction electricians. Postures of the upper arms, head, and neck during work and breaks were quantified by means of inclinometry for a representative sample of 12 Brazilian and 12 Norwegian electricians in the construction industry during a full work-shift. Despite that differences were found between specific work-related factors, Brazilian and Norwegian workers revealed a high and very similar level and pattern of postures for all evaluated body regions, suggesting that results could be extrapolated to other electricians. Upper arm elevation was high and similar for both groups and head flexion and extension was pronounced compared to other occupations. Thus, extreme postures were identified for construction electricians in both countries, with similar exposure pattern also for defined tasks (planning, support and wiredraw), suggesting that this job is risky regardless organizational differences.     

Strain‐induced deformation mechanisms of polylactide plasticized with acrylated poly(ethylene glycol) obtained by reactive extrusion

This work aimed at identifying the tensile deformation mechanisms of an original grade of plasticized polylactide (pPLA) obtained by reactive extrusion. This material had a glass transition temperature of 32.6 °C and consisted of a polylactide (PLA) matrix grafted with poly(acryl‐poly(ethylene glycol)) (poly(Acryl‐PEG)) inclusions. pPLA behaved like a rubber‐toughened amorphous polymer at 20 °C, and its tensile behavior evolved toward a rubbery semicrystalline polymer with increasing temperature. The drawing of pPLA involved orientation of amorphous and crystalline chains, crystallization, and destruction of crystals. It was found that crystal formation and crystal destruction were in competition below 50 °C, resulting in a constant or slightly decreasing crystallinity with strain. Increasing temperature enhanced crystal formation and limited crystal destruction, resulting in an increased crystallinity with the strain level. Drawing yielded a transformation of the initial spherical poly(Acryl‐PEG) inclusions into ellipsoids oriented in the tensile direction. This mechanism may engender the formation of nanovoids within the inclusions due to a decreased density, assumed to be responsible for the whitening of the specimen. © 2015 Society of Chemical Industry     

Scheduling parallel jobs to minimize the makespan

We consider the NP-hard problem of scheduling parallel jobs with release dates on identical parallel machines to minimize the makespan. A parallel job requires simultaneously a prespecified, job-dependent number of machines when being processed. We prove that the makespan of any nonpreemptive list-schedule is within a factor of 2 of the optimal preemptive makespan. This gives the best-known approximation algorithms for both the preemptive and the nonpreemptive variant of the problem. We also show that no list-scheduling algorithm can achieve a better performance guarantee than 2 for the nonpreemptive problem, no matter which priority list is chosen. List-scheduling also works in the online setting where jobs arrive over time and the length of a job becomes known only when it completes; it therefore yields a deterministic online algorithm with competitive ratio 2 as well. In addition, we consider a different online model in which jobs arrive one by one and need to be scheduled before the next job becomes known. We show that no list-scheduling algorithm has a constant competitive ratio. Still, we present the first online algorithm for scheduling parallel jobs with a constant competitive ratio in this context. We also prove a new information-theoretic lower bound of 2.25 for the competitive ratio of any deterministic online algorithm for this model. Moreover, we show that 6/5 is a lower bound for the competitive ratio of any deterministic online algorithm of the preemptive version of the model jobs arriving over time.     

Increasing the Reactivity of Amides towards Organometallic Reagents: An Overview

The nucleophilic addition of carbon nucleophiles to amides has traditionally been a difficult task, both due to reactivity and selectivity problems. When successful, these processes would represent straightforward routes towards carbonyl‐type or amine compounds, depending on the fate of the generated tetrahedral intermediate. The direct addition of nucleophiles to amides for the preparation of ketones has been studied and applied to the syntheses of several natural products. On the other hand, the addition of nucleophiles to amides to obtain substituted amines represented a major challenge, and only scattered applications on particular substrates have appeared. Initial improvements were based on the activation of amides by introduction of particular substituents, such as in N‐methoxy amides (Weinreb amides) or electron‐withdrawing groups able to increase the carbon nucleophilicity. Although these strategies facilitate the introduction of nucleophiles, chemoselectivity issues arise when additional electrophilic moieties (i.e., carbonyls) are present, thus decreasing the versatility of the methods. In recent years, important advancements towards fully chemoselective methods have been realized. The capture of tetrahedral intermediates with acids generates highly electrophilic iminium species able to undergo chemoselective additions of various nucleophiles, thus accessing substituted amines. Alternatively, the in situ generation of an iminium triflate ion allows highly chemoselective additions of nucleophiles, yielding amines, ketones or ketimines. Also thioamides can be used as precursors of ketones or α‐substituted amines. The success of the above methodologies is further showcased by the application in various syntheses of natural products or biologically active molecules.