Is Chlorogenic Acid Bitter?

Chlorogenic acid at 5° published threshold concentration (100 mg/ L) in aqueous 0.2% potassium acid tartrate was not significantly more bitter than aqueous 0.2% potassium tartrate alone when evaluated by taste panel.     

Electronic Sensing of Aromatic Volatiles for Quality Sorting of Blueberries

An electronic sniffer using semi-conductor gas sensors that nondestructively measured aromatic volatile gas emissions from fruit was developed to assess blueberry quality. The sniffer detected soft and damaged fruit in packaged containers at a 5% level of damage and distinguished four of five fruit ripeness classes: (1) mature-green and green-pink; (2) blue-pink; (3) blue; and (4) ripe fruit. Sniffer response increased as fruit ripened, as did total concentration of aromatic volatiles. Sniffer response correlated with berry firmness, pH, titratable acidity, and color, and detected differences among 10 cultivars, as did impact response analysis. The electronic sniffer is rapid, nondestructive and may be used to sort and quality check for presence of unripe or damaged fruit in closed packs of fresh berries.     

Flavor and Stability of "Horchata De Chufas"

Horchata is a sweetened water extract of chufa tubers (Cyperus esculentus) which is very popular in Spain, and has potential in the U.S. The objectives of this research were to characterize horchatas from different types of chufa, and to monitor flavor and stability of unheated and pasteurized horchatas during storage (2°C). Trained panelists rated the following attributes: color, chalkiness, sweetness, vanilla-like, nutty, earthiness, bitterness, and off-flavor. Horchatas made with chufa grown in Spain and chufa from Spain but grown in Florida showed higher vanilla and nutty levels than horchata from the Florida type. During storage (2°C), vanilla, nutty, and sweetness decreased, and other attributes increased. Heating to 70 and 95°C for 1 min did not alter sensory attributes initially, prevented off-flavor development, and slowed changes in desirable attributes for 35 days.     

Chemistry of Uranium in Glass-Forming Melts: Redox Interactions of Uranium with Chromium and Iron in Aluminosilicates

The mutual interactions by internal redox reactions of uranium and chromium and uranium and iron in two aluminosilicate glass-forming melts were studied by optical spectrophotometry. Cr(VI) was found to oxidize completely all available U(V) and U(IV) to U(VI), whereas Fe(III) was not a strong enough oxidizing agent to affect the uranium redox states. Cr(II) totally reduced all the U(V) and U(VI) in the system to U(IV); Fe(II) did not reduce any of the uranium redox species. Cr(III) coexisted with U(VI), U(V), and U(IV) in the melts. The degree of mutual interaction was governed not only by the difference in redox potentials between the respective redox couples, but also by the stability of molecular associations between the redox ions within the melt microstructure.     

Fracture Induced in Al2O3 Bicrystals by Anisotropic Thermal Expansion

Bicrystals of Al₂O₃ were fabricated to study the effects of thermal expansion anisotropy on fracture in a model system containing one grain boundary. Fractures occurred perpendicular to the directions of maximum tensile stress in bicrystals with thermal expansion coefficient differences as low as 0.31×10⁻⁶⁰C⁻¹ and originated at the boundary, probably in areas of high residual stress associated with pores. Numerical stress analysis of two-dimensional model bicrystal configurations showed that stresses induced by thermal expansion anisotropy are maximal in a region localized along the bicrystal boundary.     

Thermal Expansion of Pb3O4

Thermal expansion of Pb₃O₄ was investigated by high-temperature X-ray diffraction. The coefficient in the a ₀ direction is 14.6×10⁻⁶/°C. Expansion in the c₀ direction is 32% greater, with a coefficient of 19.3×10⁻⁶/°C. Coefficients of expansion are linear from 25° to 490°C and are comparable with those of tetragonal and orthorhombic PbO.     

Suggested Chemistry of Zinc Oxychloride Cements

Solutions of ZnCl₂ were prepared from ZnCl₂· n H₂O and by reaction of zinc metal with HCl. Specific gravities and pH values were determined as a function of composition. A ternary phase, 4ZnO·ZnCl₂·5H₂O, was precipitated when the ZnCl₂ solutions were diluted to a pH of 5.48 ± 0.05. Mixtures of ZnO with ZnCl, and HCI solutions were equilibrated in sealed containers and analyzed by X-ray diffraction. The resulting phase diagram shows 2 ternary phases, 4ZnO·ZnCl₂·5H₂O (4·1·5) and ZnO·ZnCl₂·2H₂O (1.1.2), both of which are soluble to the extent of < 1 wt% in ZnCl₂ solutions. Thermogravimetric data indicate that the 1.1.2 phase loses half the constituent H₂O at ∼230°C and the remainder, with ZnCl₂, at higher temperatures. The 4.1.5 phase dissociates to ZnO and 1.1.2 at ∼160°C. The system ZnCl₂-H₂O is not binary, but is a section through the ternary system ZnO-HCl-H₂O, with the solubility curve of the 4.1.5 phase intersecting the ZnCl₂-H₂O section in dilute solutions.     

Singular perturbation analysis of high-frequency filter design

The control design of systems with lightly damped high frequency oscillatory modes is treated. Systems exhibiting these lightly damped modes include turbine generators and large flexible structures. Frequently the dynamics of these high-frequency modes are not known very accurately. As a result, the design objective is to improve the slow dynamics without destabilizing the high-frequency modes. From a classical frequency domain design viewpoint, this is in part a filtering problem requiring some kind of high-frequency filter. The singular perturbation method is used to systematically develop a two-time-scale method to design these high-frequency filters and provides guidelines on the kind of high-frequency filter to be used. In addition, the method provides an asymptotic error analysis. The design is illustrated with an example representative of a power system model with a two-mass turbine-generator model.     

A GENERAL APPROACH TO THE STUDY OF SPATIAL SYSTEMS II. Two Examples of Application

The emphasis in this work is on the practical application of ideas set forth in Part I. Two studies involving spatial distribution are discussed: the distribution of human population in the Indianapolis, Indiana Region, and the world distribution of mammals. In the first, populations over the period 1890–1980 of Ihe 393 townships making up the study area are used to produce classifications involving various numbers of classes of township types. A test of the theoretical structure posed in Part I is then detailed. On the theory that the underlying relations involved cannot sustain a real world structure involving more than five functional classes, it is hypothesized that classifications involving more than five classes will be associated with township distribution patterns that conflict with Central Place Theory. This is shown to be clearly so. In the second study, the derivation of a five region partitioning of world mammalian distribution patterns is described. Discussion includes the introduction of a wholly new rationale for taxonomic revision based on biogeographic criteria (and ultimately the principles described in Part I). The study closes with a short argument regarding why the model described in Part I should not be labelled as either social physics or anti-humanistic.     

Modelling of an automated guided vehicle system (AG VS) in a just-in-time (JIT) environment

Like other production systems, just-in-time (JIT) systems need to address the issue of material transport between workstations such as those served by automated guided vehicles (AGVs). Unlike other production systems, however, the JIT philosophy imposes strict requirements on inventory levels and supply-demand protocols which render conventional AGV delivery strategies ineffective and counter-productive. This paper describes the modelling of an AGV system (AGVS) in a JIT environment in a way that is consistent with JIT principles. The influence of a ‘JIT perspective’ is emphasized throughout the model by introducing threshold values for both input and output queues, performance measures that emphasize lower inventories in addition to transport efficiency, and a new dispatching rule that implements better inventory and transport control. The dispatching rule is shown to perform better in a JIT environment than previously developed AGV dispatching rules in both transport and logistic criteria.