Dynamic response and safety assessment of a batch process on cooling breakdown

Cooling breakdown in highly exothermic reaction processes may lead to runaway. The sensitivity and the safety assessment of a batch process on cooling breakdown are studied. The dependence of the minimum cooling time and the maximum allowable time of cooling breakdown for safe operation on the process parameters is investigated.     

Performance of TCP extensions on noisy high BDP networks

Experiments on high bandwidth delay product (BDP) networks assist in the design and understanding of future global networks. This paper describes the results of experiments with different implementations of TCP on a high speed ATM/SONET network over high delay and noisy channels. Comparisons are also made with host/traffic configurations over various smaller BDP systems, experimental comparisons of three different implementations of TCP; TCP Reno, TCP new Reno, and TCP SACK as a function of bit error rates (BER) and round-trip times (RTT) are presented     

Dependence of off-leakage current on channel film quality in poly-Si thin-film transistors and analysis using device simulation

The dependence of off-leakage current on channel film quality in poly-Si thin-film transistors has been analyzed using two-dimensional device simulation. It is found that the off-leakage current decreases as the intragrain trap density decreases for the low V_gs. This is because the Phonon-assisted tunneling with Poole-Frenkel effect is the dominant mechanism of the carrier generation and the generation rate of carrier pair decreases as the intragrain trap density decreases. On the other hand, the off-leakage current slightly increases as the intragrain trap density decreases for the high V_gs. This is because the band-to-band tunneling is the dominant mechanism and the influence of the intragrain trap density to the carrier conductance is larger than that to the generation rate.     

Si nanowires by a single-step metal-assisted chemical etching process on lithographically defined areas: formation kinetics

In this paper, we investigate the formation kinetics of Si nanowires [SiNWs] on lithographically defined areas using a single-step metal-assisted chemical etching process in an aqueous HF/AgNO₃ solution. We show that the etch rate of Si, and consequently, the SiNW length, is much higher on the lithographically defined areas compared with that on the non-patterned areas. A comparative study of the etch rate in the two cases under the same experimental conditions showed that this effect is much more pronounced at the beginning of the etching process. Moreover, it was found that in both cases, the nanowire formation rate is linear with temperature in the range from 20°C to 50°C, with almost the same activation energy, as obtained from an Arrhenius plot (0.37 eV in the case of non-patterned areas, while 0.38 eV in the case of lithographically patterned areas). The higher etch rate on lithographically defined areas is mainly attributed to Si surface modification during the photolithographic process.PACS: 68; 68.65-k.     

Probing Protein Folding with Sequence-Reversed α-Helical Bundles

Recurrent protein folding motifs include various types of helical bundles formed by α-helices that supercoil around each other. While specific patterns of amino acid residues (heptad repeats) characterize the highly versatile folding motif of four-α-helical bundles, the significance of the polypeptide chain directionality is not sufficiently understood, although it determines sequence patterns, helical dipoles, and other parameters for the folding and oligomerization processes of bundles. To investigate directionality aspects in sequence-structure relationships, we reversed the amino acid sequences of two well-characterized, highly regular four-α-helical bundle proteins and studied the folding, oligomerization, and structural properties of the retro-proteins, using Circular Dichroism Spectroscopy (CD), Size Exclusion Chromatography combined with Multi-Angle Laser Light Scattering (SEC-MALS), and Small Angle X-ray Scattering (SAXS). The comparison of the parent proteins with their retro-counterparts reveals that while the α-helical character of the parents is affected to varying degrees by sequence reversal, the folding states, oligomerization propensities, structural stabilities, and shapes of the new molecules strongly depend on the characteristics of the heptad repeat patterns. The highest similarities between parent and retro-proteins are associated with the presence of uninterrupted heptad patterns in helical bundles sequences.     

Experimental investigation on the combustion behaviour of pre-dried Greek lignite

The present paper includes the results of the combustion tests with Greek dried lignite performed at a 1 MWth semi industrial scale pulverized coal combustion facility. Scope of the campaign is the investigation of the combustion behaviour of Greek lignite, i.e. temperature fields, ignition, burnout, emissions, as well as slagging and fouling tendency, while firing with varying levels of recirculated flue gas. Dry coal co-firing conditions in a large scale boiler are simulated by adjusting the volume flow of recirculated flue gas.Two test series representing different boiler operation modes are performed. During the first series the maximum flue gas temperature increase, when co-firing dry coal, is determined, while in the second test series the needed load decrease, in order to keep constant furnace outlet temperature in dry coal co-firing conditions is recorded. A detailed measurement set is carried out including temperature profiles, emissions, fuel, fly ash sampling and slagging and fouling investigations through the installation of dedicated deposition probes.The anticipated increase of the furnace temperature profiles by decreasing the inserted recirculated flue gas is confirmed by the experimental results. No clear trend of dry coal co-combustion on the emissions' behaviour is noticed, while dry coal firing appears to have a moderate effect on the deposition behaviour of Greek lignite. These preliminary investigations indicate that no significant operational problems are expected during a potential future demonstration of dry lignite co-firing in a Greek large scale boiler.     

Measurements and predictions of electric and magnetic fields from power lines

Electric and magnetic field measurements around overhead and underground power lines have been performed extensively within a transmission and distribution electric grid. Measurements have been performed at different heights of the human body close to such transmission and distribution power lines that operate at a frequency of 50 Hz, at different currents and at three different voltages of 11, 66 and 132 kV. These measurements were performed in an attempt to firstly verify that the existing measurements fall within the signified guidelines for electric and magnetic field exposure, published in 1998 by the International Commission on Non-Ionizing Radiation Protection. Furthermore, and most importantly, were used to validate/develop a model capable of predicting the magnetic field produced in both overhead and underground transmission and distribution power lines using experimental measurements. This is achieved by establishing a linear correlation between the current load of one of the two three phase circuits and the magnetic field, in an attempt to predict the magnetic fields produced in power lines using the SCADA system at overloaded periods.     

Decentralized optimality conditions of stochastic differential decision problems via Girsanov’s measure transformation

In this paper, we apply two methods to derive necessary and sufficient decentralized optimality conditions for stochastic differential decision problems with multiple Decision Makers (DMs), which aim at optimizing a common pay-off, based on the notions of decentralized global optimality and decentralized person-by-person (PbP) optimality. Method 1: We utilize the stochastic maximum principle to derive necessary and sufficient conditions which consist of forward and backward Stochastic Differential Equations (SDEs), and conditional variational Hamiltonians, conditioned on the information structures of the DMs. The sufficient conditions for decentralized PbP optimality are local conditions, closely related to the necessary conditions for decentralized PbP optimality. However, under certain convexity condition on the Hamiltonian, and a global version of the sufficient conditions for decentralized PbP optimality, we show decentralized global optimality. Method 2: We utilize the value processes of decentralized PbP optimal policies, we relate them to solutions of backward SDEs, we identify sufficient conditions for decentralized PbP optimality, and we show these are precisely those derived via the maximum principle. For both methods, as usual, we utilize Girsanov’s theorem to transform the initial decentralized stochastic optimal decision problems, to equivalent decentralized stochastic optimal decision problems on a reference probability space, in which the controlled process and the information processes which generate part of the information structures of the DMs, are independent of any of the decisions.