Economic evaluation of long-distance hydrogen transmission by chemical closed-loop cycle

All over the world there are enormous unexploited renewable energy reserves (hydro, geothermic, solar, wind, etc.). Most originate far from the location of the users, so their exploitation would greatly benefit from the disclosure of new, more economical, and technically feasible transmission systems.A possible alternative to electricity is the use of hydrogen as a medium for transportation of energy. This work proposes a chemical closed-loop cycle based upon catalytic reversible reactions as a means to transmit hydrogen. A real example for the application of the proposed system for transportation of secondary energy was considered. In particular, choosing a large hydro-electric source as reference, a comparison was made between costs and efficiencies in transferring energy as hydrogen (in its different forms) over long distances, with respect to transportation of the same energy as electricity.     

Use of the ARPE-19 cell line as a model of RPE polarity: basolateral secretion of FGF5

PURPOSE: To determine the polarity of fibroblast growth factor 5 (FGF5) secretions from retinal pigment epithelium (RPE) cells and to examine the viability and utility of the ARPE-19 cell line as a model for the study of RPE polarity. METHODS: Influenza infection and adenovirus-mediated gene transfer were used to deliver and express genes encoding influenza hemagglutinin (HA), p75-NTR (a neurotrophin receptor), low-density lipoprotein (LDL) receptor (LDLR), and FGF5 in confluent monolayers of ARPE-19 cells. The localization of HA, p75-NTR, and LDLR was determined by confocal microscopy. Domain selective biotinylation assays were used to quantitatively determine the polarities of p75-NTR and LDLR. The secretion of FGF5 into the apical and basal media of ARPE-19 cultures was examined by immunoblot analysis of conditioned media. RESULTS: Hemagglutinin and p75-NTR were found to be localized on the apical surface of infected and transduced ARPE-19 cells. In contrast, LDLR was associated preferentially with the basolateral membrane of ARPE-19 cells. Biotinylation studies indicated that 84% of p75-NTR was present on the apical surface, and 79% of LDLR was basolaterally polarized. Over the course of 6 hours, more than 90% of the total secreted FGF5 protein accumulated in the basolateral media. CONCLUSIONS: ARPE-19 cells exhibit a polarized distribution of cell surface markers when examined by either confocal microscopy or surface-labeling assays. This indicates that the ARPE-19 cell line is a valid model for studies of RPE cell polarity. FGF5, a secreted protein normally produced by RPE cells, is accumulated preferentially in the basal media after only 6 hours, suggesting that it is vectorially secreted from the basolateral surface of ARPE-19 cells.     

An integrated computer-controlled system for assisting researchers in cortical excitability studies by using transcranial magnetic stimulation

Transcranial magnetic stimulation (TMS) is the most important technique currently available to study cortical excitability. Additionally, TMS can be used for therapeutic and rehabilitation purposes, replacing the more painful transcranial electric stimulation (TES). In this paper we present an innovative and easy-to-use tool that enables neuroscientists to design, carry out and analyze scientific studies based on TMS experiments for both diagnostic and research purposes, assisting them not only in the practicalities of administering the TMS but also in each step of the entire study's workflow. One important aspect of this tool is that it allows neuroscientists to specify research designs at will, enabling them to define any parameter of a TMS study starting from data acquisition and sample group definition to automated statistical data analysis and RDF data storage. It also supports the diagnosing process by using on-line support vector machines able to learn incrementally from the diseases instances that are continuously added into the system. The proposed system is a neuroscientist-centred tool where the protocols being followed in TMS studies are made explicit, leaving to the users flexibility in exploring and sharing the results, and providing assistance in managing the complexity of the final diagnosis. This type of tool can make the results of medical experiments more easily exploitable, thus accelerating scientific progress.     

Synthesis of crystalline metal nitride and metal carbide nanostructures by sol–gel chemistry

Attention toward nanosized metal nitrides and carbides is rapidly increasing thanks to their chemical characteristics that make them as valid and sustainable alternatives to noble metals in catalysis and to air-sensitive metals or oxides for applications under harsh conditions. They are mostly used as bulk phase or micron sized powders, due to an intrinsic difficulty to synthesize them as nanoparticles in a systematic and scalable fashion. However, nanosized metal nitrides and carbides could exhibit improved performances, e.g. in catalysis due to a higher surface area, and can be shaped more easily than corresponding larger grains for further specific applications. Recently, sol–gel chemistry has closed this gap and now enables the simple, cheap, and sustainable production of metal nitride and carbide nanoparticles.In the present review we give an overview on recent sol–gel based pathways for the synthesis of metal nitride and carbide nanoparticles, believing that a better knowledge of the potentialities of these still hardly touched materials stimulates research interest and applications.     

Game theory and time utility functions for a radio aware scheduling algorithm for WiMAX networks

In WiMAX systems the Base Station scheduler plays a key role as it controls the sharing of the radio resources among the users. The goal of the scheduler is multiple: achieve fair usage of the resources, satisfy the QoS requirements of the users, maximize goodput, and minimize power consumption, and at the same time ensuring feasible algorithm complexity and system scalability. Since most of these goals are contrasting, scheduler designers usually focus their attention on optimizing one aspect only. In this scenario, we propose a scheduling algorithm (called GTS_Nmathrm{GTS_N}) whose goal is to contemporaneously achieve efficiency and fairness, while also taking into account the QoS requirements and the channel state. GTS_Nmathrm{GTS_N} exploits the properties of Time Utility Functions (TUFs) and Game Theory. Simulations prove that the performance of GTS_N,mathrm{GTS_N}, when compared to that of several well-known schedulers, is remarkable. GTS_Nmathrm{GTS_N} provides the best compromise between the two contrasting objectives of fairness and efficiency, while QoS requirements are in most cases guaranteed. However, the exponential complexity introduced by the game theory technique makes it rather impractical and not computationally scalable for a large number of users. Thus we developed a suboptimal version, named sub-GTS_N.mathrm{GTS_N}. We show that this version retains most of the features and performance figures of its brother, but its complexity is linear with the number of users.     

Microstructured fibre Bragg gratings: analysis and fabrication

A microstructured fibre Bragg grating that relies on a partial and localised etching of the cladding layer along the grating region is proposed. The main effect is the formation of defect states inside the bandgap depending on surrounding refractive index. This leads to the possibility of realising novel optoelectronic devices for sensing and telecommunication applications.     

Optimal design of Service Overlay Networks with economic and performance constraints

In the last years, Service Overlay Networks (SONs) have emerged as a promising means to address some of the issues (e.g. end‐to‐end QoS) affecting the current Internet and to favor the development and deployment of new value‐added Internet services. The deployment of an SON is a capital‐intensive investment, since bandwidth with certain QoS guarantees must be purchased from the individual network domains through bilateral Service Level Agreements. Thus, minimizing the economic cost of the logical end‐to‐end service delivery infrastructure is one of the key objectives for the SON provider. When a SON is aimed at end‐to‐end QoS provisioning, its topology must be designed so as to also satisfy the specific requirements of QoS‐sensitive applications. This paper deals with the problem of planning the SON topology in order to take into account both cost and QoS constraints. More specifically, the paper proposes a set of new algorithms for the design of an optimized SON topology, which minimizes the economic cost while simultaneously meeting bandwidth and delay constraints. A performance comparison among such algorithms is finally carried out. Copyright © 2009 John Wiley & Sons, Ltd.     

Dual carrier suppression interferometer for measurement of phasenoise

A new scheme for phase noise measurement is presented, based on dual stage suppression of the carrier and synchronous detection of the noise sidebands of the device being tested. This scheme features real time output and intrinsically low instrument flicker. A prototype shows a residual flicker as low as -160 dBrad²/Hz at 1 Hz off the 100 MHz carrier. Other implementations are possible, from 1 MHz to several gigahertz. Applications include the noise characterisation of components and the design of innovative ultrastable oscillators     

Temperature compensated sapphire-rutile microwave whisperinggallery mode resonator

A 2 μm-thick film of rutile (TiO₂) was deposited on a sapphire disk using a sol-gel method to realise a temperature compensated microwave resonator operating in whispering gallery mode configuration. The resonator, though not yet completely optimised, shows turnover temperatures ranging from 40 to 60 K depending on the mode azimutal number. For the WGH_7,0,0 mode at 9.4 GHz, the Q-factor is of the order of 1.5×10⁶ at 46 K. The technique appears easy to implement and can be used for the design of a high-frequency stability microwave source