Formation of Hybrid Inorganic/Organic Nanocomposites

Hybrid inorganic/organic nanocomposites were produced by the exposure of spun films of octa-(benzo-15-crown-5)-substituted phthalocyanine of Cd(II) to an environment of hydrogen sulfide gas. The formation of cadmium sulfide (CdS) quantum dots in the metal free phthalocyanine matrix was identified in the phthalocyanine matrix from atomic force microscopy images. The mean size of CdS quantum dots was estimated to be 2–3 nm, from optical absorption and Raman spectra for the nanocomposites.     

Subjective wear trials to evaluate thermal comfort of the foot clothing system including a sweat pad

Subjective wear trials were conducted to evaluate effects of disposable antibacterial sweat pads on foot thermal comfort. Sweat pads were produced with polypropylene and polylactic acid nonwoven topsheet layers which were treated with different herbal antibacterial materials. Trials were carried out with 10 male subjects under 10 °C and 50% relative humidity simulating sweating during a moderate activity in cold environments. Besides microclimate temperature and relative humidity measurements, subjective thermal (coolness, dampness, and comfort) and other sensations (stickiness, slippiness, etc.) were obtained by five point rating scales. Bending rigidity, friction coefficients, and moisture management properties of the topsheet fabrics and pads were tested. Results show that foot sweat pads enabled drier microclimate, warmer sensations, and higher comfort evaluations. Antibacterial treatments did not affect bending rigidity values of the nonwoven topsheet fabrics, but some applications decreased spreading speed, increased roughness of the pad surfaces, and wetting time values which are not preferable.     

Detection of the frequency, antimicrobial susceptibility, and genotypic discrimination of Aeromonas strains isolated from municipally treated tap water samples by cultivation and AP-PCR

The frequency, antibiotic susceptibility, and genotypic discrimination of Aeromonas strains isolated from municipally treated drinking tap water distribution systems were investigated in this study. We have analyzed 148 tap water samples collected from 8 different locations by bacterial cultivation and arbitrarily primed polymerase chain reaction (AP-PCR). Gram negative, hemolytic, oxidase (+) and catalase (+) bacterial colonies were applied to the study. Identification of bacterial colonies was done by conventional biochemical method and API ID 20E panel (BioMerieux-France). Molecular epidemiological discrimination of the isolates was done by AP-PCR. Aeromonas spp. was detected in 6 of 148 (4%) tap water samples from 8 different locations. Five isolates were identified as Aeromonas hydrophila and one isolate was identified as Vibrio fluvialis by conventional biochemical method. These data were also confirmed by API 20E panel. One of 6 isolates was resistant to gentamicin, 2 of 6 isolates were resistant to trimethoprim/sulfamethoxazole, 4 of 6 isolates were resistant to ampicillin and ampicillin-sulbactam and all of 6 isolates were resistant to cephalothin. All isolates were found to be susceptible to amikacin, aztreonam, ceftazidime, ceftriaxone, ciprofloxacin. All 6 strains of Aeromonas were discriminated by AP-PCR and were determined that all isolates were from different genotypic sources. Although the frequency of the isolates was under the standard limits, the results indicate that hemolytic A. hydrophila are present in municipally treated tap water samples in Mersin City. While all strains were genotypically distinct, all of them were resistant to first generation beta lactam antibiotics tested in this study.     

National-scale implementation of mandatory freshwater farm plans: a mechanism to deliver water quality improvement in productive catchments in New Zealand?

Nutrient Cycling in Agroecosystems - Reducing agriculturally derived diffuse contaminant losses (via non-point sources) from land to water has proven difficult for decades. Owing to the diversity...     

Natural-based polymers for antibacterial treatment of absorbent materials

In this study, polypropylene (PP) nonwoven fabric which can be used as topsheet layer of an absorbent hygienic product was modified by natural based antibacterial agents. Antibacterial herbal agents (cinnamaldehyde, geraniol, phenylethyl alcohol) were sprayed by ethanol or applied by means of polylactic acid (PLA) and polycyclohexene oxide (PCHO) based polymers prepared by three different chemical methods. Characterization of synthesized materials was conducted via thermogravimetric analysis (TGA), differential thermal analysis (DTA), and scanning electron microscopy–energy dispersive X–ray spectroscopy (SEM-EDX). Besides characterization, antibacterial and pH buffering performances of antibacterial polymers alone and on PP fabric were tested by antibacterial and pH tests. Effects of antibacterial treatments on air permeability and absorption period of nonwoven fabrics were also analyzed. According to the results, biopolymers changed the thermal stability of PP nonwoven fabric. Antibacterial performances can be ranked as cinnamaldehyde, geraniol, and phenylethyl alcohol from the best. Besides a slight decrease about liquid absorption performance, all of the treated topsheet fabrics are sufficient for an absorbent hygienic product. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48302.     

Dependency of removal efficiency on electrode arrangements in the treatment of oily wastewaters by electrocoagulation

Turbidity and chemical oxygen demand (COD) removal efficiencies were analyzed depending on electrode layouts by performing electrocoagulation experiments using horizontal and vertical electrochemical cells. Multiple aluminum plate electrodes were placed into different sections of the electrochemical cells. Removal efficiencies at the horizontal electrochemical cell were always higher than the one’s obtained from the vertical electrochemical cell. But the use of vertical electrochemical cell consumed less energy during the electrocoagulation tests. The highest COD removal efficiencies were 97% and 88% in the horizontal and vertical electrochemical cells, respectively. However, the energy consumption for COD removal in the horizontal electrochemical cell was 47% higher than the energy consumed in the vertical electrochemical cell.     

Lipoprotein Subfraction Profile and HDL-Associated Enzymes in Sickle Cell Disease Patients

Although hypocholesterolemia is a reported finding in sickle cell disease (SCD), low-density lipoprotein (LDL)/high-density lipoprotein (HDL) subfractions and HDL-associated enzymes have not been determined in SCD patients. Blood was collected from 38 hemoglobin (Hb)A volunteers and 45 homozygous HbSS patients who had not received blood transfusions in the last 3 months. Serum lipids were measured by automated analyzer while LDL and HDL subfraction analysis was done by continuous disc polyacrylamide gel electrophoresis. Serum levels of cholesteryl ester transfer protein (CETP), lecithin-cholesterol acyltransferase (LCAT), apolipoprotein B (apoB) and apolipoprotein A-1 (apoA-I) were determined by enzyme-linked immunosorbent assay (ELISA). Total cholesterol (TC), low-density lipoprotein cholesterol (LDL-C) and high-density lipoprotein cholesterol (HDL-C) levels were significantly decreased, while TG levels were significantly increased in SCD patients compared to controls. A significant decrease in intermediate-density lipoprotein (IDL)-C, IDL-B, IDL-A and LDL-1 fractions were seen in SCD patients, while no significant difference was observed in small dense LDL particles. A significant decrease was seen in HDL-large, HDL-intermediate and HDL-small fractions in SCD patients versus controls. Levels of LCAT and ApoA-1 protein measured in SCD patients were significantly lower while no significant difference was observed in CETP and ApoB protein levels compared to controls. The reduction observed in LDL- and HDL-C in SCD patients was reflected as significantly decreased IDL, LDL-1 and HDL-subfractions. Decreased HDL subfractions may possibly lead to the reduced ApoA-1 and LCAT protein levels observed in SCD patients.     

Performance Assessment of a Potato Crisp Frying Process

Frying is a common and popular cooking method, which has been widely used in food manufacturing, though it is a very energy-intensive process. Energy analysis has been commonly used to assess the performance of fryers. In this study, we attempted to exergetically assess the performance of a potato crisp frying system, which consists of three main components, a combustor, a heat exchanger, and a fryer. In the analysis, we utilized the actual operational data obtained from the literature. We determined exergy destruction in each system component and the whole system. We calculated universal and functional exergy efficiency values for the system components and compared them with each other. We also undertook a parametric study to investigate how the overall cycle performance was affected by changing the reference environment temperature and some operating conditions. We illustrated the exergy results through the Grassmann (exergy loss and flow) diagram. We calculated the universal exergetic efficiency values of 58, 82, and 77% for the combustor, heat exchanger, and fryer, respectively, with a universal exergetic efficiency value of 4% for the whole frying system. We found that the fryer had the highest functional exergetic efficiency value of 74%, followed by the heat exchanger with 47% and the combustor with 0.08%.