Ab initio determination of heavy oxide perovskite related structures from precession electron diffraction data

Two complex perovskite-related structures were solved by ab initio from precession electron diffraction intensities. Structure models were firstly derived from HREM images and than have been confirmed independently using two and three-dimensional sets of precession intensities. Patterson techniques prove to be effective for ab initio structure resolution, specially in case of projections with no overlapping atoms. Quality of precession intensity data may be suitable enough to resolve unknown heavy oxide structures.     

Influence of Y~(3+),Yb~(3+),Gd~(3+) cations on structural and electromagnetic properties of CuFe_2O_4 nanoferrites prepared via one step sol-gel method

Rare earths(REs) play a key role in distorting spinel structure by creating some defects at the lattice sites and make them suitable for magnetodielectric applications.In the present study,the nanoferrites of CuRE_(0.02)Fe_(1.98)O_4,where REs=Y~(3+),Yb~(3+),Gd~(3+),were prepared using one step sol-gel method.The prepared samples are copper ferrite(CFO),yttrium doped copper ferrite(Y-CFO),ytterbium doped copper ferrite(Yb-CFO) and gadolinium doped copper ferrite(Gd-CFO),respectively.The single-phase structure of all the REs doped nanoferrites was determined by X-ray diffraction(XRD) analysis.The porosity,agglomerations and grain size of the REs doped copper ferrite were examined using field emission scanning electron microscopy(FESEM) analysis.Fourier transform infrared spectroscopy(FTIR)elaborates the phase formation and environmental effects on the REs doped nanoparticles(NPs).The recorded room temperature M-H loops from a vibrating sample magnetometer(VSM) elucidate the magnetic properties of the REs doped spinel nanoferrites.The magnetic saturation(M_s) was calculated in the range of 23.08 to 51.78 emu/g.The calculated coercivity values(272.6 to 705.60 Oe) confirm the soft magnetic behavior of REs doped copper ferrites.Furthermore,the electromagnetic and dielectric properties were assessed using a Vector network analyzer(VNA) from 1 to 6 GHz.The permeability,permittivity,dielectric tangent loss and electric modulus of the REs doped spinel ferrites illustrate that the prepared NPs may be suitable for microwave and high frequency applications.     

Evaluation and testing of internet firewalls

In this article we propose a testing methodology for evaluating Internet firewalls and apply it to compare two popular firewalls. Copyright © 1999 John Wiley & Sons, Ltd.     

Investigation of LSPR Coupling Effects toward the Rational Design of CsxWO3–δ Based Solar NIR Filtering Coatings

The optical range of localized surface plasmon resonance (LSPR) is extended into the infrared region, thanks to the development of highly doped semiconductor nanocrystals. Particularly, the near-infrared (NIR) range holds a significant interest in managing solar radiation. However, practical applications necessitate the arrangement of particles, which is known to possibly impact their optical properties through LSPR coupling effects. How such coupling modifies the LSPR response in semiconductor hosts remains largely unexplored. In this study, a protocol for producing composite coatings composed of cesium-doped tungsten bronze nanocrystals embedded in a silica matrix is presented. Achieving individual dispersion of nanocrystals is made possible through careful selection of a surface polyglycerol ligand exchange. This allows to tune the interparticle distance by adjusting the nanocrystal volume fraction in the composite. The findings demonstrate that LSPR coupling effects significantly influence the LSPR intensity of nanocrystals in the composite when the nanocrystal-to-nanocrystal distance matches their size. Beyond elucidating the LSPR coupling effect, this study provides insights into the potential use of Cs-HTB nanocrystals for solar control applications. Through the optimization of morphology and film structure, remarkable selectivity is obtained in terms of maintaining good transparency in the visible range while achieving high absorption in the NIR.     

Political correctness and academic principles: a reply to Simpson

The author discusses Christopher Simpson's (1996) article, 'Elisabeth Noelle-Neumann's 'Spiral of Silence' and the Historical Context of Communication Theory.' He questions the relevance of biographical data for the evaluation of scientific theories and methods, and analyzes the rhetorical structure of Simpson's arguments. He concludes that Simpson's claims about the influence of Noelle's biography on her scholarly work are not grounded in evidence.     

Narrative analysis of sexual etiquette in teenage magazines

Expanding on existing research on women's magazines, this essay examines the sexual etiquette developed in advice columns in magazines popular among teenage women. Over a span of 20 years, the advice has changed very little. Serving the rhetorical function of field guides and training manuals, teen magazines limit women's sociality and sexuality within narrowly defined heterosexual norms and practices. The rhetoric of sexual etiquette encourages young women to be sex objects and teachers of interpersonal communication rather than lovers, friends, and partners. Young women are being taught to subordinate self for others and to be contained.     

Efficient PFD-Based Networking and Buffering Models for Improving Video Quality over Congested Links

Video traffic over the Internet becomes increasingly popular and is expected to comprise the largest proportion of the traffic carried by wired and wireless networks. On the other hand, videos are usually compressed by exploiting spatial and temporal redundancy for the reason of increasing the number of video streams that can be simultaneously carried over links. Unfortunately, receiving high-quality video streaming over the Internet remains a challenge due to the packet loss encountered in the congested wired and wireless links. In addition, the problem is more apparent in wireless links due to not only employing limited system capacity, but also some of the major drawbacks of wireless networks, out of which the bandwidth limitations and link asymmetry which refers to the situation where the forward and reverse paths of a transmission have different channel capacities. Therefore, the wireless hops may be congested which result in dropping many video frames. Additionally, as a result of compressing videos, dependencies among frames and within a frame arise. Consequently, the overall video quality tends to be degraded dramatically. The main challenge is to support the growth of video traffic while keeping the perceived quality of the delivered videos high. In this paper, we extend our previous work concerning improving video traffic over wireless networks through professionally studying the dependencies between video frames and their implications on the overall network performance. In other words, we propose very efficient network and buffer models proportionately to novel algorithms that aim to minimize the cost of aforementioned possible losses by selectively discarding frames based on their contribution to picture quality, namely, partial and selective partial frame discarding policies considering the dependencies between video frames. The performance metrics that are employed to evaluate the performance of the proposed algorithms include the rate of non-decodable frames, peak signal-to-noise ratio, frameput, average buffer occupancy, average packet delay, as well as jitter. Our results are so promising and show significant improvements in the perceived video quality over what is relevant in the current literature. We do not end up to this extent, but rather the effect of producing different bit-stream rates by the FFMPEG codecs on aforementioned performance metrics has been extensively studied.