Cathodoluminescence and Field-Emission Properties of β-Ga2O3 Nanobelts

β-Ga₂O₃ nanobelts were synthesized using a vapor transport process in a controlled ambient. Structural characterization revealed that the as-synthesized samples consisted of monoclinic β-Ga₂O₃ nanobelts, and the presence of gallium-associated defects was verified using cathodoluminescence (CL). The formation of gallium-associated defects was explained by the insufficiency of the supply of cations, generating gallium vacancies on the (010) facet during growth. Furthermore, field-emission measurements indicated that β-Ga₂O₃ nanobelts exhibited defect-related electron emission. The turn-on fields of β-Ga₂O₃ nanobelts increased significantly with the degree of structural defects. For a sample prepared under 15% ambient oxygen, Fowler–Nordheim (F–N) analysis revealed two distinct field-enhancement factors of 1194 and 276, respectively. A correlation between field emission and structural defects was proposed. The experimental results demonstrate the presence of gallium-associated defects, which behave as electron traps, degrading the electron field-emission properties of β-Ga₂O₃ nanobelts.     

High quality interpoly dielectrics deposited on thenitrided-polysilicon for nonvolatile memory devices

High quality interpoly dielectrics have been fabricated by using NH₃ and N₂O nitridation on polysilicon and deposition of tetra-ethyl-ortho-silicate (TEOS) oxide with N₂O annealing. The surface roughness of polysilicon is improved and the value of weak bonds is reduced due to nitrogen incorporation at the interface, which improves the integrity of interpoly dielectrics. The improvements include a higher barrier height, breakdown strength, and charge-to-breakdown, and a lower leakage current and charge trapping rate than counterparts. It is found that this method can simultaneously improve both charge-to-breakdown (up to 20 C/cm² ) and electric breakdown field (up to 17 MV/cm)     

Transmission characteristics of finite-width conductor-backedcoplanar waveguide

This paper presents theoretical and experimental results for a finite-width conductor-backed coplanar waveguide (FW-CBCPW). The guiding characteristics of FW-CBCPW are investigated first by the rigorous method of mode matching. An FW-CBCPW through line is then placed within a test fixture commonly used in laboratories, and the scattering parameters of the through line are obtained theoretically by approximating the FW-CBCPW as a simple system of coupled transmission lines. Experimental results are shown to agree very well with the theoretical ones. In particular, the anomalous behavior observed in the transmission characteristic of the through line is related to the resonant phenomenon of the terminated side planes which are short-circuited at both input and output ends due to the test fixture. Finally, a technique of mode suppression in the side-plane regions is suggested for the improvement of signal transmission over a broad band of frequency spectrum. The effects of extra higher order modes on the transmission characteristics at high frequencies are also discussed     

On the effects of a spacecraft subcarrier unbalanced modulator

This paper presents mathematical models with associated analysis of the deleterious effects which a spacecraft's subcarrier unbalanced modulator has on the performance of a phase-modulated residual carrier communications link. The undesired spectral components produced by the phase and amplitude imbalances in the subcarrier modulator can cause (1) potential interference to the carrier tracking and (2) degradation in the telemetry bit signal-to-noise ratio (SNR). A suitable model for the unbalanced modulator is developed and the threshold levels of undesired components that fall into the carrier tracking loop are determined. The distribution of the carrier phase error caused by the additive White Gaussian noise (AWGN) and undesired component at the residual RF carrier is derived for the limiting cases. Further, this paper analyses the telemetry bit signal-to-noise ratio degradations due to undesirable spectral components as well as the carrier tracking phase error induced by phase and amplitude imbalances. Numerical results which indicate the sensitivity of the carrier tracking loop and the telemetry symbol-error rate (SER) to various parameters of the models are also provided as a tool in the design of the subcarrier balanced modulator.     

The effects of substrate bias,substrate temperature,and pulse frequency on the microstructures of chromium nitride coatings deposited by pulsed direct current reactive magnetron sputtering

Recently, great attention has been devoted to the pulsed direct current (DC) reactive magnetron sputtering technique, due to its ability to reduce arcing and target poisoning, and its capability of producing insulating thin films. In this study, chromium nitride (CrN) coatings were deposited by the bipolar symmetric pulsed DC magnetron reactive sputtering process at different pulse frequency, substrate bias voltage, and the substrate temperature. It was observed that the texture of CrN changed from (111) to (200) as substrate temperature increased to 300°C as deposited at 2 kHz without substrate bias. With increasing pulsing bias and pulse frequency of target, predominated (200) orientation of CrN film was shown due to the ion bombardment/channeling effect to preferentially sputter those unaligned planes. For the CrN coatings deposited with pulsed biasing, the grain size decreased with increasing pulse frequency and substrate bias, whereas the surface roughness showed a reverse trend. The deposition rate of the CrN films decreased with increasing pulse frequency. It was concluded that the pulse frequency, substrate bias, and substrate temperature played important role in the texture, microstructure, and surface roughness of the CrN coatings deposited by the pulsed DC magnetron sputtering process.     

Intelligent voice smoother for silence-suppressed voice overInternet

When transporting voice data with silence suppression over the Internet, the problem of jitter introduced from the network often renders the speech unintelligible. It is thus indispensable to offer intramedia synchronization to remove jitter while retaining minimal playout delay (PD). We propose a neural network (NN)-based intravoice synchronization mechanism, called the intelligent voice smoother (IVoS). The IVoS is composed of three components: (1) the smoother buffer; (2) the NN traffic predictor; and (3) the constant bit rate (CBR) enforcer. Newly arriving frames, assumed to follow a generic Markov modulated Bernoulli process (MMBP), are queued in the smoother buffer. The NN traffic predictor employs an online-trained back propagation NN (BPNN) to predict three traffic characteristics of every newly encountered talkspurt period. Based on the predicted characteristics, the CBR enforcer derives an adaptive buffering delay (ABD) by means of a near-optimal simple closed-form formula. It then imposes the delay on the playout of the first frame in the talkspurt period. The CBR enforcer in turn regulates CBR-based departures for the remaining frames of the talkspurt, aiming at assuring minimal mean and variance of distortion of talkspurts (DOT) and mean PD. Simulation results reveal that, compared to three other playout approaches, the IVoS achieves superior playout, yielding negligible DOT and PD, irrespective of traffic variation     

Phase Relationships in the ZrO2-Sc2O3 and ZrO2-In2O3 Systems

Zirconia-rich subsolidus phase relationships in the ZrO₂–Sc₂O₃ and ZrO₂–In₂O₃ systems were investigated. Phase inconsistencies in the ZrO₂–Sc₂O₃ system resulted from a diffusionless cubic-to-tetragonal ( t' ) phase transformation not being recognized in the past. Through three different measuring techniques, along with microstructural observations, the solubility limits of the tetragonal and cubic phases were determined.     

Chromium(III) compounds as catalysts for Hydrocarbon Oxidation and hydroperoxide decomposition

Chromium stearate and chromium acetylacetonate are very active catalysts both for the oxidation of hydrocarbons by molecular oxygen and for the decomposition of organic hydroperoxides. During these reactions they also catalyze the oxidation of secondary alcohols to the corresponding ketones by organic hydroperoxides. From organic hydroperoxides and chromium(III)compounds chromium (VI) compounds are formed which are probably the effective agents oxidizing secondary alcohols to ketones.     

Subsolidus Phase Relationships in Si3N4–AlN–Rare-Earth Oxide Systems

The subsolidus phase relationships in Si₃N₄–AlN–rare-earth oxide (Me₂O₃ where Me=Nd, Sm, Gd, Dy, Er, and Yb) systems were studied. Solid-solution regions with the α-Si₃N₄ structure were delineated along the Si₃N₄–"Me₂O₃:9AIN" joins for all of the rare-earth oxide systems studied. The solubility limits of these solid solutions increased with decreasing size of the rare-earth ions.     

Induced liquid phase mixing due to bubble motion at low gas velocity

Liquid phase mixing induced by gas bubbles at low gas velocities was studied experimentally. An experimental technique based on the principle of spectrophotometry was developed and applied in the experimental work. Experimental evidence suggests that the mixing phenomenon can be described as a diffusive process characterized by an effective diffusivity which is found to be a linear function of superficial gas velocity.