What is a crystal to the new chemical crystallographer,after that first,automated structure analysis?

This educational review postulates the importance of maintaining an adequate level of crystallographic education among structure-dependent scientists whose interests are not primarily in crystallography, at a time when automation and validation have made it possible to obtain high-quality structure analyses in many cases with a minimum of crystallographic background. The topics addressed are intended to form a second round of crystallographic education for a novice user whose first round involved hands-on experience with structure solution and an introduction to elementary concepts. The specific topics, chosen for their relevance as basic knowledge and their lack of emphasis in many formal treatments, are (1) crystallographic reference frames and the utility of the reciprocal cell in geometrical calculations; (2) the relationship between the two concepts that constitute our model of the crystal, namely the unit cell and the lattice; (3) the manner in which an atom is represented in concept and in practice; (4) the importance of interleaved symmetry elements required by the presence of additional symmetry on a lattice; (5) the harnessing of the natural properties of the crystalline state for the potential manipulation of properties of synthetic crystals; and (6) useful terminology for navigating a crystal structure.     

TRACES OF THE TERRITORY IN SPANISH PHOTOGRAPHY SINCE THE 1990s

This paper proposes a reading of the cultural and social aspects associated with sundry notions of territory through Spanish photography at the end of the twentieth century and the beginning of the twenty-first. An analysis of a series of case studies reveals a new awareness of the common space through the concept of trace, being understood beyond the material imprint, as it falls under the influence of the cultural aspects that clarify the account of the conflict and consciousness of the suburbs and peripheries. Contemporary ruins arising from unbridled urban growth, or the invisible wounds associated with certain places, converge in a series of images that have their own tradition in the conceptual experiments of the 70s and the aesthetics of the “non-site” displayed in the 90s. As background, the economic and political avatars of recent years in Spain – also linked to a global crisis – are manifested in a series of photographic musings whose images portray the scenarios of a premature ruin linked to property speculation and the traces of a collective memory.     

Modification of structure and conductivity of nanohorns by toluene addition in carbon arc

Abstract

In the present work, we compare the structure and transport properties of carbon nanohorns (CNHs) synthesized by arc evaporation of graphite alone and with the addition of some portion of toluene. The materials have been investigated using transmission electron microscopy, Raman and infrared spectroscopies, thermogravimetric and BET analyses. The addition of a small amount of toluene during the evaporation of graphitic rod increases the length of CNHs, affects their hierarchical arrangement in aggregates and results in surface functionalization. All these features significantly enhance the conductivity of CNHs obtained with toluene additive in comparison with the pristine CNHs.     

An evaluation of Acacia mearnsii tannin as an aluminum corrosion inhibitor in acid,alkaline, and neutral media

The electrochemical behavior of aluminum in tannin from Acacia mearnsii bark was evaluated by potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) in media under three different pH conditions: acid, alkaline, and neutral. A relationship among pH, polymerization grade (PG), zeta potential, surface, and electrochemical properties was observed in the inhibition performance of the tannin. At high pH, the oligomer structure of the tannin was affected, resulting in a low PG (4) and high zeta potential (−75 mV), and consequently, the inhibition efficiency decreased (68%) in comparison with that in acid (99%) and neutral media (96%). The values obtained indicate a physisorption mechanism for the aluminum corrosion inhibition in the studied conditions.     

Effects of SiC particles codeposition and ultrasound agitation on the electrocrystallisation of nickel-based composite coatings

This study analysed the influence of the codeposition of SiC particles with different sizes: 50 nm, 500 nm and 5 μm, and the type of bath agitation (stirring or ultrasonic) on the electrocrystallisation of nickel coatings. The composites matrix microstructure was analysed by means of SEM, EBSD and XRD, to evaluate the grain size, crystal orientation, and internal stresses and was benchmarked against pure nickel samples electrodeposited in equivalent conditions. The codeposition of nano- and microsize particles with an approximate content of 0.8 and 4 vol.%, respectively, caused only a minor grain refinement and did not vary the dominant?<?100?>?crystal orientation observed in pure Ni. The internal stress was, however, increased by particles codeposition, up to 104 MPa by nanoparticles and 57 MPa by microparticles, compared to the values observed in pure nickel (41 MPa). The higher codeposition rate (11 vol.%) obtained by the addition of submicron-size particles caused a change in the grain growth from columnar to equiaxial, resulting in deposits with a fully random crystal orientation and pronounced grain refinement. The internal stress was also increased by 800% compared to pure nickel. The ultrasound (US) agitation during the deposition caused grain refinement and a selective particle inclusion prompting a decrease in the content of the particles with the larger particles. The deposits produced under US agitation showed an increase in the internal stresses, with double values compared to stirring. The increase in the deposits microhardness, from 280 HV in pure Ni to 560 HV in Ni/SiC submicron-US, was linked to the microstructural changes and particles content.

Graphical abstract

     

A Compact Semi-circular Slot MIMO Antenna with Enhanced Isolation for Sub-6 GHz 5G WLAN Applications

In this paper, a novel compact semi-circular slot (SCS) 2 × 2 MIMO antenna is presented for 5G NR sub-6 GHz applications with high isolation. The proposed antenna consists of a semi-circular slot in ground plane, U-shaped stub, and 50-ohm microstrip feed line. The novelty of this paper are the Semi-Circular Slot acts a radiator, the port isolation  is enhanced using a simple conductor strip as a neutralization line, very compact in size, low ECC, and good impedance matching. The overall size of the proposed SCS MIMO antenna is 16 mm x 21 mm, and FR4 substrate is used with thickness of 1.6 mm. The two SCS antenna elements are separated by edge-to-edge distance of 1mm (\(=0.019\lambda _{0}\)). The proposed compact MIMO antenna design is simulated using Ansys HFSS. To validate SCS MIMO antenna, a prototype was fabricated and tested. The measured results are attained at 5.5 GHz with isolation greater than 25dB, impedance bandwidth (S11\(<-10\) dB) covers from 5.10 GHz to 5.80 GHz with return loss of ? 39.5 dB. The MIMO antenna parameters, ECC, CCL, TARC, and MEG are studied, and the values are obtained within acceptable limits. The measured and simulated antenna results are almost similar. This compact MIMO antenna is suitable for 5G communications in sub-6 GHz wifi-5 band applications.