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排序方式: 共有358条查询结果,搜索用时 15 毫秒
1.
Chenhui Ding Marion Breunig Jana Timm Roland Marschall Jürgen Senker Seema Agarwal 《Advanced functional materials》2021,31(49):2106507
Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m2 g−1), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future. 相似文献
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Seema Hiranandani Joel Saltz Piyush Mehrotra Harry Berryman 《Journal of Parallel and Distributed Computing》1991,12(4)
Many researchers approach the problem of programming distributed memory machines by assuming a global shared name space. Thus the user views the distributed memory of the machine as though it were shared. A major issue that arises at this point is how to manage the memory. When a processor accesses data stored on another processor's memory, data must be moved between the two processors. Once these data are retrieved from another processor's memory, several interesting issues are raised. Where should these data be stored locally? What transformations must be performed to the code to guarantee that the nonlocal accesses reference the correct memory location? What optimizations can be performed to reduce the time spent in accessing the nonlocal data? In this paper we examine various data migration mechanisms that allow an explicit and controlled mapping of data to memory. We describe, experimentally evaluate, and model a set of schemes for storing and retrieving off-processor array elements. The schemes are all based on using hash tables for efficient access of nonlocal data. The three different techniques evaluated are the basic hashed cache, partial enumeration, and full enumeration, the details of which are described in the paper. In all three schemes, nonlocal data are stored in hash tables—the difference is in the amount of memory used by the schemes and the retrieval mechanisms for nonlocal data. 相似文献
5.
The photoconductive properties of a carotenoid polyene,β-Apo-8′ carotenal in polycrystalline form has been studied. The growth of the photocurrent shows an overshoot in the growth-time
curve before steady state value is attained. This behaviour of photocurrent is proposed to be due to higher value of recombination
coefficient than trapping coefficient. From the temperature dependence study it is observed that the steady state photocurrent,
at first increases with increase of temperature, attains a maximum at a particular temperatureT
max and then decreases with temperature. TheT
max value agrees with the temperature above and below which steady state photocurrent is attained differently. Monomolecular
and bimolecular recombination processes at two temperature regimes are proposed to account for the observed behaviour. The
dependence of photocurrent with excitation light intensity and wavelength study provide information on the carrier generation
processes. The fast decay of photocurrent have been observed at different temperatures and from this study the decay constant
is calculated and it is found to be temperature independent. 相似文献
6.
Johnsy George R. Kumar C. Jayaprahash A. Ramakrishna S. N. Sabapathy A. S. Bawa 《应用聚合物科学杂志》2006,102(5):4514-4522
Rice bran was incorporated into low‐density polyethylene (LDPE) at different concentrations by compounding in a twin‐screw extruder and blown into films of uniform thickness. The rice bran incorporation influenced physical, mechanical, barrier, optical, thermal properties, and biodegradation of LDPE. The mechanical and optical properties decreased as the percentage of rice bran increased. The effect of rice bran on the morphology of LDPE blends was examined using scanning electron microscopy. Oxygen transmission rate and water vapor transmission rate increased with the increased content of rice bran. Addition of rice bran did not alter the melting temperature (Tm) of the blends; however the thermal stability decreased, while glass transition temperature (Tg) increased. Kinetics of thermal degradation was also investigated and the activation energy for thermal degradation indicated that for up to 10% filler addition, the dispersion and interfacial adhesion of rice bran particles in LDPE was good. Aerobic biodegradation tests using municipal sewage sludge and biodegradation studies using specific microorganism (Streptomyces species) revealed that the films are biodegradable. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4514–4522, 2006 相似文献
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Ozonation of purine and pyrimidine bases and of carbohydrates was studies in laboratory experiments. The results showed that nucleobases are much more reactive with molecular ozone in aqueous solution than carbohydrates. Second order rate constants for direct reaction of ozone on purines (adenine and guanine) and on pyrimidines (cytosine, thymine and uracil) ranged from 0.76 × 103 to 6.8 × 103 M-1s-1at 2°C. The difference of reactivity between these solutes may be attributed to their substituents. As far as carbohydrates are concerned, direct reactions of ozone are very slow k03 ? 0.1 – 0.3 M-1s-1 at 20°C, and the results indicated that free radical reactions are predominant in the degradation pathway of carbohydrates by ozone. Some ozonation by-products of monosaccharides (glucose, xylose) and disaccharides (cellobiose) also were identified in this study by means of GC/MS analyses. 相似文献
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Let There be Light: Polymeric Micelles with Upper Critical Solution Temperature as Light‐Triggered Heat Nanogenerators for Combating Drug‐Resistant Cancer
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Yongyan Deng Florian Käfer Tingting Chen Qiao Jin Jian Ji Seema Agarwal 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(37)
Complete drug release and efficient drug retention are two critical factors in reversing drug resistance in cancer therapy. In this regard, polymeric micelles with an upper critical solution temperature (UCST) are designed as a new exploration to reverse drug resistance. The amphiphilic UCST‐type block copolymers are used to encapsulate photothermal agent IR780 and doxorubicin (DOX) simultaneously. The integrated UCST‐type drug nanocarriers show light‐triggered multiple synergistic effects to reverse drug resistance and are expected to kill three birds with one stone: First, owing to the photothermal effect of IR780, the nanocarriers will be dissociated upon exposure to laser irradiation, leading to complete drug release. Second, the photothermal effect‐induced hyperthermia is expected to avoid the efflux of DOX and realize efficient drug retention. Last but not least, photothermal ablation of cancer cells can be achieved after laser irradiation. Therefore, the UCST‐type drug nanocarriers provide a new strategy in reversing drug resistance in cancer therapy. 相似文献
10.
A key issue that needs to be addressed while performing fault diagnosis using black box models is that of robustness against abrupt changes in unknown inputs. A fundamental difficulty with the robust FDI design approaches available in the literature is that they require some a priori knowledge of the model for unmeasured disturbances or modeling uncertainty. In this work, we propose a novel approach for modeling abrupt changes in unmeasured disturbances when innovation form of state space model (i.e. black box observer) is used for fault diagnosis. A disturbance coupling matrix is developed using singular value decomposition of the extended observability matrix and further used to formulate a robust fault diagnosis scheme based on generalized likelihood ratio test. The proposed modeling approach does not require any a priori knowledge of how these faults affect the system dynamics. To isolate sensor and actuator biases from step jumps in unmeasured disturbances, a statistically rigorous method is developed for distinguishing between faults modeled using different number of parameters. Simulation studies on a heavy oil fractionator example show that the proposed FDI methodology based on identified models can be used to effectively distinguish between sensor biases, actuator biases and other soft faults caused by changes in unmeasured disturbance variables. The fault tolerant control scheme, which makes use of the proposed robust FDI methodology, gives significantly better control performance than conventional controllers when soft faults occur. The experimental evaluation of the proposed FDI methodology on a laboratory scale stirred tank temperature control set-up corroborates these conclusions. 相似文献