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1.
Two complex perovskite-related structures were solved by ab initio from precession electron diffraction intensities. Structure models were firstly derived from HREM images and than have been confirmed independently using two and three-dimensional sets of precession intensities. Patterson techniques prove to be effective for ab initio structure resolution, specially in case of projections with no overlapping atoms. Quality of precession intensity data may be suitable enough to resolve unknown heavy oxide structures.  相似文献   
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Extracts obtained by supercritical carbon dioxide extraction of cones and leaves of hop (Humulus lupulus L) at different combinations of temperature and pressure were analysed for their α- and β-acids and volatiles, using HPLC and GC respectively. The yield and composition of the mixtures of bitter compounds from the cones were largely influenced by the temperature and pressure applied during the extraction. Bitter compounds could not be detected in the extracts from the leaves. The most important volatile components identified were β-myrcene, β-caryophyllene and α-humulene. The extraction parameters also influenced the composition of the mixture of volatiles from the cones and leaves, 40°C and 20.0 MPa being optimum for the extraction of both bitter compounds and volatiles, which are thought to be important for the aroma of beer.  相似文献   
4.
While it has been argued that field‐dependent geminate pair recombination (GR) is important, this process is often disregarded when analyzing the recombination kinetics in bulk heterojunction organic solar cells (OSCs). To differentiate between the contributions of GR and nongeminate recombination (NGR) the authors study bilayer OSCs using either a PCDTBT‐type polymer layer with a thickness from 14 to 66 nm or a 60 nm thick p‐DTS(FBTTh2)2 layer as donor material and C60 as acceptor. The authors measure JV‐characteristics as a function of intensity and charge‐extraction‐by‐linearly‐increasing‐voltage‐type hole mobilities. The experiments have been complemented by Monte Carlo simulations. The authors find that fill factor (FF) decreases with increasing donor layer thickness (Lp) even at the lowest light intensities where geminate recombination dominates. The authors interpret this in terms of thickness dependent back diffusion of holes toward their siblings at the donor–acceptor interface that are already beyond the Langevin capture sphere rather than to charge accumulation at the donor–acceptor interface. This effect is absent in the p‐DTS(FBTTh2)2 diode in which the hole mobility is by two orders of magnitude higher. At higher light intensities, NGR occurs as evidenced by the evolution of s‐shape of the JV‐curves and the concomitant additional decrease of the FF with increasing layer thickness.  相似文献   
5.
This paper proposes a power efficient multipath video packet scheduling scheme for minimum video distortion transmission (optimised Video QoS) over wireless multimedia sensor networks. The transmission of video packets over multiple paths in a wireless sensor network improves the aggregate data rate of the network and minimizes the traffic load handled by each node. However, due to the lossy behavior of the wireless channel the aggregate transmission rate cannot always support the requested video source data rate. In such cases a packet scheduling algorithm is applied that can selectively drop combinations of video packets prior to transmission to adapt the source requirements to the channel capacity. The scheduling algorithm selects the less important video packets to drop using a recursive distortion prediction model. This model predicts accurately the resulting video distortion in case of isolated errors, burst of errors and errors separated by a lag. Two scheduling algorithms are proposed in this paper. The Baseline scheme is a simplified scheduler that can only decide upon which packet can be dropped prior to transmission based on the packet’s impact on the video distortion. This algorithm is compared against the Power aware packet scheduling that is an extension of the Baseline capable of estimating the power that will be consumed by each node in every available path depending on its traffic load, during the transmission. The proposed Power aware packet scheduling is able to identify the available paths connecting the video source to the receiver and schedule the packet transmission among the selected paths according to the perceived video QoS (Peak Signal to Noise Ratio—PSNR) and the energy efficiency of the participating wireless video sensor nodes, by dropping packets if necessary based on the distortion prediction model. The simulation results indicate that the proposed Power aware video packet scheduling can achieve energy efficiency in the wireless multimedia sensor network by minimizing the power dissipation across all nodes, while the perceived video quality is kept to very high levels even at extreme network conditions (many sensor nodes dropped due to power consumption and high background noise in the channel).  相似文献   
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Designing hardware often involves several types of modeling and analysis, e.g., in order to check system correctness, to derive performance properties such as throughput, to optimize resource usages (e.g., buffer sizes), and to synthesize parts of a circuit (e.g., control logic). Working directly with low-level hardware models such as finite-state machines (FSMs) to answer such questions is often infeasible, e.g., due to state explosion. Instead, designers often use dataflow models such as SDF and CSDF, which are more abstract than FSMs, and less expensive to use since they come with more efficient analysis algorithms. However, dataflow models are only abstractions of the real hardware, and often omit critical information. This raises the question, when can one say that a certain dataflow model faithfully captures a given piece of hardware? The question is of more than simply academic interest. Indeed, as illustrated in this paper, dataflow-based analysis outcomes may sometimes be defensive (e.g., buffers that are too big) or even incorrect (e.g., buffers that are too small). To answer the question of faithfully capturing hardware using dataflow models, we develop a formal conformance relation between the heterogeneous formalisms of (1) finite-state machines with synchronous semantics, typically used to model synchronous hardware, and (2) asynchronous processes communicating via queues, used as a formal model for dataflow. The conformance relation preserves performance properties such as worst-case throughput and latency.  相似文献   
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Multidimensional Systems and Signal Processing - In this paper we present new methods for the reduction of a polynomial system matrix describing a discrete linear repetitive process, to equivalent...  相似文献   
8.
In this paper, a new approach in identifying chaotic behaviour of nonlinear circuits is presented. This approach could be very useful to circuit designers, whether they pursue a chaotic behaviour or not. Simulation tools used for radio-frequency circuit design (Cadence SpectreRF), initially developed to characterise harmonic oscillators, are now utilised to detect chaotic behaviour, as well as routes to chaotic mode of operation. Specifically, Periodic Steady State Convergence Norm is used for the first time for chaos detection in circuits. The advantages of this method (especially in terms of simulation time) are presented, together with an example of detection of chaotic route to chaos in the case of a chaotic-operating Colpitts oscillator.  相似文献   
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Model analysis of sorption isotherms   总被引:2,自引:0,他引:2  
Stavros Yanniotis  Ji?í Blahovec 《LWT》2009,42(10):1688-1695
The equation developed by Blahovec and Yanniotis, which is based on surface adsorption and solution water, was applied for fitting experimental sorption data for starchy and high protein foods, fruits and vegetables, nuts, legumes, and seeds. Analysis of sorption isotherms shows that surface adsorption is more important than solution water in the isotherms for cereals, potatoes, legumes and seeds, while in vegetables, fruits, meat, milk products and some nuts solution water is more important. The ratio of solution water to surface adsorption increases as water activity increases, it is higher for the adsorption isotherm than the desorption isotherm at any water activity value and decreases as temperature increases.  相似文献   
10.
The aim of the present study was to investigate the volatile fraction and discriminate 34 commercial thyme honeys from Morocco, Egypt, Spain, and Greece according to geographical origin, using key volatile compounds in combination with chemometrics. Sixty-two volatile compounds belonging to different classes were identified and semi-quantified using headspace solid phase micro-extraction coupled to gas chromatography/mass spectrometry (HS-SPME-GC/MS). Applying chemometric analyses to 17 volatiles (p < 0.05), honeys were successfully discriminated according to geographical origin. Correct classification rate was 88.2% using the cross-validation method. Volatile compounds proved to be a powerful tool for discriminating commercial thyme honeys from different countries.  相似文献   
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