Effects of B2O3 addition on structural and dielectric properties of PVDF

α‐Crystalline form of PVDF doped with Boron oxide (B₂O₃₎ composite films were produced between 0.2 and 1% weight ratio via the casting procedure. This low‐level doping rate did not change the crystalline structure of PVDF; however, they increased the lower and upper glass transition temperatures, which are associated with the amorphous ratio of polymer. This increment was found to be the highest for the sample 0.8% B₂O₃‐doped PVDF as 25 and 9.7%, respectively. Because of the low specific volume occurred in the 0.8% doped sample, B₂O₃ molecules are closer to the side groups of PVDF and, therefore, the coordination bonds also occurred according to the interaction between them and as a result of this interaction a geometric deformation occurred on the morphology of B₂O₃. In consequence of this deformation, morphology of B₂O₃ gained net dipole moment and provided a contribution to the dipole moment density of the structure. Hence, higher dielectric constant values obtained than that of pure PVDF. At 1 kHz and 300 K, the real dielectric constant increased by 236% compared to that of pure PVDF. It was shown experimentally by the 0.8% doping level of B₂O₃ that decreasing porous and gap structure resulted a high dielectric constant. POLYM. ENG. SCI., 54:2536–2543, 2014. © 2013 Society of Plastics Engineers     

Optimum design of laminated composite plates to maximize buckling load using MFD method

This paper presents optimal design of simply supported laminated composite plates subject to given in-plane static loads for which the critical failure mode is buckling. The objective function is to maximize the buckling load capacity of laminated plates and the fiber orientation is considered as design variable. The first-order shear deformation theory is used for the finite element analysis. In this paper, the effects of bending–twisting coupling are also included for the buckling optimization. The modified feasible direction method is used as an optimization method. Also, computer programs are coded in MATLAB and Golden Section method is adapted in this program for the optimal design of laminated plates for maximum buckling load. The effect of width-to-thickness ratio, aspect ratio, number of layers, material anisotropy, load ratios (N_y/N_x), uncertainties in material properties and functionally graded materials on the results is investigated and compared.     

Martensitic phase transformations in Ni–Ti-based shape memory alloys: The Landau theory

We present a simple Landau free energy functional for cubic-to-orthorhombic and cubic-to-monoclinic martensitic phase transformations. The functional is derived following group–subgroup relations between different martensitic phases – tetragonal, trigonal, orthorhombic and monoclinic – in order to fully capture the symmetry properties of the free energy of the austenite and martensite phases. The derived free energy functional is fitted to the elastic and thermodynamic properties of NiTi and NiTiCu shape memory alloys which exhibit cubic-to-monoclinic and cubic-to-orthorhombic martensitic phase transformations, respectively.     

Area-based quality control of airborne laser scanning 3D models for different land classes using terrestrial laser scanning: sample survey in Houston,USA

Airborne laser scanning (ALS) is a remote-sensing technique that provides scale-accurate 3D models consisting of dense point clouds with x, y planimetric coordinates and altitude z. Using ALS, very high-resolution (VHR) digital surface models (DSMs) have been widely used for commercial and scientific applications since the early 1990s. Although there is widespread usage, there has been little comprehensive investigation of quality control for ALS DSMs in the literature, as most studies have been limited to assessing point-based vertical accuracy. This article is dedicated to investigating the quality of ALS DSMs for different land classes using statistical and visual approaches based on absolute and relative vertical accuracy metrics. Rather than a limited number of ground control points (GCP), the model-to-model-based approach is applied and DSMs derived from terrestrial laser scanning (TLS) point clouds that have around 5 mm absolute and 3 mm relative geolocation accuracy were used as the reference data for comparison. The results demonstrate that in open, grass, and building land classes, the ALS DSMs reached both standard deviation (σ) and normalized median absolute deviation (NMAD) of 3–5 cm after the elimination of any systematic biases. This result sufficiently satisfies the vertical accuracy requirements for 1/1000-scale topographic maps determined by National Digital Elevation Program (NDEP) specifications. In tall vegetation, a higher number of discrepancies larger than 0.5 m exist, reversing the relation between σ and NMAD. These vegetation errors also do not appear to be normally distributed. As an additional investigation, the performance of ALS DEMs under dense high-vegetation areas was assessed. These under-canopy ALS DEMs, created using only classified ground returns, offer both σ and NMAD of 12–14 cm, a performance level that is difficult to achieve under-canopy using photogrammetric techniques.     

Are Propositional Attitudes Mental States?

Minds and Machines - I present an argument that propositional attitudes are not mental states. In a nutshell, the argument is that if propositional attitudes are mental states, then only minded...     

Maximization of buckling load of laminated composite plates with central circular holes using MFD method

This paper addresses optimal design of simply supported symmetrically laminated composite plates with central circular holes. The design objective is the maximization of the buckling load, and the design variable is considered as the fiber orientation. The first-order shear deformation theory is used for the finite element analysis. The study is complicated because the effects of bending–twisting coupling are also included for the buckling optimization. The modified feasible direction method is used to solve the optimization problems. Finally, the effect of different number of layers, boundary conditions, width-to-thickness ratio, plate aspect ratios, hole daimeter-to-width ratio, and load ratios on the results is investigated.     

Fair referee assignments for professional football leagues

Assignment of referees to football games is an important problem faced in professional football leagues. Despite its importance, the problem has received limited academic attention. This paper presents a model and analysis of the problem for fair referee assignments, and develops a constructive heuristic and a local search procedure for its solution. Results from an extensive computational study show that the methods are effective in solving the problem in a second of computation time and yielding an excellent solution quality.     

The Data Locality of Work Stealing

This paper studies the data locality of the work-stealing scheduling algorithm on hardware-controlled shared-memory machines, where movement of data to and from the cache is solely controlled by the hardware. We present lower and upper bounds on the number of cache misses when using work stealing, and introduce a locality-guided work-stealing algorithm and its experimental validation. {As a lower bound, we show that a work-stealing application that exhibits good data locality on a uniprocessor may exhibit poor data locality on a multiprocessor. In particular, we show a family of multithreaded computations G _n whose members perform Θ(n) operations (work) and incur a constant number of cache misses on a uniprocessor, while even on two processors the total number of cache misses soars to Ω(n) . On the other hand, we show a tight upper bound on the number of cache misses that nested-parallel computations, a large, important class of computations, incur due to multiprocessing. In particular, for nested-parallel computations, we show that on P processors a multiprocessor execution incurs an expected

Melt‐Centrifuged (Bi,Sb)2Te3: Engineering Microstructure toward High Thermoelectric Efficiency

Microstructure engineering is an effective strategy to reduce lattice thermal conductivity (κ_l) and enhance the thermoelectric figure of merit (zT). Through a new process based on melt‐centrifugation to squeeze out excess eutectic liquid, microstructure modulation is realized to manipulate the formation of dislocations and clean grain boundaries, resulting in a porous network with a platelet structure. In this way, phonon transport is strongly disrupted by a combination of porosity, pore surfaces/junctions, grain boundaries, and lattice dislocations. These collectively result in a ≈60% reduction of κ_l compared to zone melted ingot, while the charge carriers remain relatively mobile across the liquid‐fused grains. This porous material displays a zT value of 1.2, which is higher than fully dense conventional zone melted ingots and hot pressed (Bi,Sb)₂Te₃ alloys. A segmented leg of melt‐centrifuged Bi_0.5Sb_1.5Te₃ and Bi_0.3Sb_1.7Te₃ could produce a high device ZT exceeding 1.0 over the whole temperature range of 323–523 K and an efficiency up to 9%. The present work demonstrates a method for synthesizing high‐efficiency porous thermoelectric materials through an unconventional melt‐centrifugation technique.     

Characterization of nanocrystalline Ni–Cu thin films electrodeposited onto ITO coated glass substrates: effect of pretreatment current density

In this work, Ni–Cu films were grown onto indium tin oxide coated glass substrates without and with galvanostatic pretreatment process at different current densities. In all cases, Ni–Cu films were electrodeposited at a constant deposition potential of ?1,800 mV versus saturated calomel electrode. After that, the surface morphology and structural properties of electrodeposited Ni–Cu films in dependence of pretreatment current density were studied. X-ray diffraction analysis showed that all films have face-centered cubic structure and consist of segregated two Ni-rich and Cu-rich phases regardless of pretreatment current density. The compositional analysis carried out by energy dispersive X-ray spectroscopy revealed that all films contain almost 90 wt% Ni and 10 wt% Cu. The average crystallite size decreased with decreasing pretreatment current density towards more negative values without inducing significant changes in the composition of the films. It was found that the preferred orientation of all films is in the [111] direction regardless of pretreatment current density. The effect of galvanostatic pretreatment process on the surface morphology investigated using a scanning electron microscopy and an atomic force microcopy were also discussed by means of obtained results.