柔性石墨板的氢气透过率研究

对于聚合物电解质膜燃料电池双极板,阻气性是其重要属性.为了方便测量柔性石墨板样品的阻气性能,自制了气体透过性测量装置,并利用此装置研究了柔性石墨双极板的密度对其阻气性的影响.     

头发角蛋白质子导电材料的制备和理化特性表征

将头发氧化后用模压法制备了氧化角蛋白膜,考察了氧化角蛋白膜的电导率及其影响因素,并对其进行了表征。考察了角蛋白膜的微观结构、氧化前后头发角蛋白的官能团变化以及氧化时间、模压压强、颗粒粒径对电导率的影响。实验结果表明,角蛋白膜的电导率达3.6×10-3S/cm,且随氧化时间延长,电导率先上升后下降,随模压压强的增大,电导...     

干式煤气柜泄漏及中毒事故预测后果分析

文章通过对煤气柜煤气泄漏及扩散范围的研究,利用相应的数学模型可以估算出CO扩散影响的范围及相应的中毒人数,可以帮助企业了解煤气柜区域事故后果的影响范围,并对煤气柜这种重大危险源的管理和控制有一个量的概念。     

多层爆炸焊接参数的试验研究

在论述双金属板爆炸焊接参数试验方法基础上，结合工程中大幅板面爆炸焊接的实际应用，介绍一种比较实用和高效的3层板爆炸焊接倾角试验方法，在单面布药，一次完成双界面爆炸焊接的倾角试验研究中，以较少的试验次数，获取了多组试验数据，从而节省多时间和精力，收到了事半功倍的效果。     

聚丙烯酰胺固体凝胶膜中甲醇透过性能研究

采用膜扩散法，由示差折光仪在线测试了聚丙烯酰胺(PAAM)固体凝胶膜室温下甲醇透过系数。实验结果表明，随凝胶浓度的增加，PAAM固体凝胶膜的甲醇透过系数呈下降趋势；但在凝胶浓度一定的情况下，随凝胶中文链度的增加，PAAM固体凝胶膜的甲醇透过系数出现极小值。因此，PAAM固体凝胶膜在掺杂导电成分后可于直接甲醇燃料电池(DMFC)中作为阻醇电解质膜使用。     

催化层厚度对质子交换膜燃料电池性能影响的数值研究

采用一维稳态宏观均相模型,首次对不同阴极催化层（CCL）厚度的质子交换膜燃料电池（PEMFC）在全操作电流范围内的功率输出进行了计算和比较。在催化层中各相的体积比不变的前提下,催化层厚度以2种方式变化：一是变化单位面积催化层内的Pt载量;二是变化Pt在碳载铂（Pt/C）催化剂颗粒中的质量分数。2种方式的模拟结果均表明,催化层较厚的PEMFC具有较高的功率输出。但是从提高催化剂利用率角度考虑,第1种催化层厚度变化方式中催化层越薄催化剂利用率越高,第2种方式相反。在本研究设定的CCL参数范围内,最适宜厚度催化层在整个电流密度范围内都使PEMFC有最高的功率输出。     

DMFCs用磺化聚醚醚酮/磺化酚酞型聚醚砜共混质子交换膜

A sulfonated poly(ether ether ketone) (SPEEK) membrane with fairly high degree of sulfonation (DS) swells excessively and even dissolves at high temperature. To solve these problems, sulfonated phenolphthalein poly(ether sulfone) (SPES-C, DS 53.7%) is blended with the SPEEK matrix (DS 55.1%, 61.7%) to prepare SPEEK/SPES-C blend membrane. The decrease in swelling degree and methanol permeability of the membrane is dose-dependent. Pure SPEEK (DS 61.7%) membrane dissolves completely in water at 70ºC, whereas the swelling degree of the SPEEK (DS 61.7%)/SPES-C (40%, by mass) membrane is 29.7% at 80ºC. From room temperature to 80ºC, the methanol permeability of all SPEEK (DS 55.1%)/SPES-C blend membranes is about one order of magnitude lower than that of Nafion®115. At higher temperature, the addition of SPES-C polymer increases the dimensional stability and greater proton conductivity can be achieved. The SPEEK (DS 55.1%)/SPES-C (40%, by mass) membrane can withstand temperatures up to 150ºC. The proton conductivity of SPEEK (DS 55.1%)/SPES-C (30%, by mass) membrane approaches 0.16 S•cm－1, matching that of Nafion115 at 140ºC and 100% RH, while pure SPEEK (DS 55.1%) membrane dissolves at 90ºC. The SPEEK/SPES-C blend membranes are promising for use in direct methanol fuel cells because of their good dimensional stability, high proton conductivity, and low methanol permeability.     

DMFCs用SPEEK/SiOx-S复合质子交换膜

A sulfonated poly(ether ether ketone) (SPEEK) membrane with a fairly high degree of sulfonation (DS) can swell excessively and even dissolve at high temperature. To solve these problems, insolvable functionalized silica powder with sulfonic acid groups (SiOx-S) was added into the SPEEK matrix (DS 55.1%) to prepare SPEEK/ SiOx-S composite membranes. The decrease in both the swelling degree and the methanol permeability of the membranes was a dose-dependent result of addition of the SiOx-S powder. Pure SPEEK membrane swelled 52.6% at 80°C, whereas the SPEEK/SiOx-S (15%, by mass) membrane swelled only 27.3% at the same temperature. From room temperature to 80℃, all SPEEK/SPEEK/SiOx-S composite membranes had methanol permeability of about one order of magnitude lower than that of Nafion115. Compared with pure SPEEK membranes, the addition of the SiOx-S powder not only leads to higher proton conductivity, but also increases the dimensional stability at higher temperatures, and greater proton conductivity can be achieved at higher temperature. The SPEEK/SiOx-S (20%, by mass) membrane could withstand temperature up to 145°C, at which in 100% relative humidity (RH) its proton conductivity exceeded slightly that of Nafion115 membrane and reached 0.17 S•cm－1, while pure SPEEK mem-brane dissolved at 90°C. The SPEEK/SiOx-S composite membranes are promising for use in direct methanol fuel cells because of their good dimensional stability, high proton conductivity, and low methanol permeability.     

非接触式浮体六自由度监测系统研究

提出了一种非接触式浮体六自由度运动测量与分析系统。该系统由视频采集模块、三维计算模块、用户交互模块3 部分构成。视频采集模块用来获取不同视角的图像信息;三维计算模块融合了改进的摄像机自标定技术、立体视觉特征点检测技术、六分量解算方法等,目的是求得物体6 个自由度的运动情况;用户交互模块提供了定点可视的物体姿态及角度变化信息,方便用户进行分析计算。实测证明,该测量系统设备简单,重构速度快,能适应复杂的海上环境并能够实现远距离监测,满足浮体测量使用要求。