Al-In-Mg系铝合金阳极在NaOH溶液中的电化学行为

以Al-In-Mg合金为基础，选择添加Pb、Mn、sn制备了4类铝合金阳极材料。通过自腐蚀、开路电位、阳极极化方式研究了该系列合金阳极在c(NaOH)=4mol／L溶液中的电化学腐蚀行为，初步分析了合金成分、介质温度及溶液缓蚀剂对合金阳极性能的影响。结果发现：制备的3#(Al-In-Mg-Sn)合金、4#(Al-In-Mg-Sn-Pb)合金阳极在c(NaOH)=4mol／L c(Na2SnO3)=0．04mol／L溶液中表现出更好的电化学性能，具有比纯铝(99．95％)更负的开路电位，更小的自腐蚀速率和更低的阳极极化。     

含氟化镁电解质体系的性质探讨和生产对策

针对电解铝生产中出现的含镁电解质体系性质进行了探讨。对生产中出现的操作问题,系统的分析了原因,并结合生产实际找出了应对措施。     

高锂钾铝电解质的初晶温度

为了研究Na₃AlF₆-AlF₃-Al₂O₃-CaF₂-LiF-KF体系的初晶温度,基于130组高可靠性铝电解质初晶温度的文献数据,采用非线性拟合法得到了适用于计算高锂钾复杂铝电解质体系初晶温度的经验公式.采用差热分析法测定了32组铝电解质的初晶温度,与本文中的公式计算值进行对比分析,结果表明,计算值与实验值之间的最大绝对误差仅为2.7℃.该经验公式可用于预测高锂钾铝电解质的初晶温度.     

Study on spinel-based inert anode for aluminium electrolysis

1 IntroductionSince the Hall-Heroult process was applied in aluminium production,an inert anode was al ways thetarget that the aluminiumindustry is seeking for in the newtechnology field. The greenhouse gases CO2and the fluoride CFnemittedfromthe present carbon anodes ,give a huge pressure onthe environment .Theapplication of inert anodes will help us go through this trouble :a cell with inert anodes emits oxygen in-stead of CO2and other nocuous gases ;the newtype of cell with inert anodes …     

铝电解陶瓷类惰性阳极材料的发展

对了铝电解对惰性阳极材料的要求进行了说明。介绍了多种对金属氧化物陶瓷材料和金属陶瓷材料为基体惰性阳极的实验室研究及工业试验情况，并阐述了对添加剂对阳极性能的影响。     

高温透明铝电解槽中50cm2石墨阳极上气泡析出行为

铝电解阳极气泡行为对研究电解质流场模拟和阳极效应都至关重要.本文采用高温透明电解槽观测了底面积为50 cm2(10 cm×5 cm)的石墨阳极上的气泡行为,实验温度为924℃.结果表明:在阳极电流密度为0.3～1.7A/cm2范围内,最大气体覆盖率在48％～65％之间,与工业电解槽炭阳极上的最大气体覆盖率相近,低于文献...     

电极材料对铝电解阴极过程研究的影响

电解铝工业中铝的析出发生在阴极上,研究铝析出反应的机理对实际工况有很好的指导意义。研究发现,炭电极上的Al、Na共沉积现象严重,致使循环伏安曲线上Al的析出峰被掩盖。因此人们试图用一些金属电极Ni、Pt、Au、Ta、Cu、W等来代替炭电极,但研究发现大部分金属电极都与Al反应生成合金,干扰了对真实电极过程的研究。只有W与Al的合金化作用较小,因此对冰晶石一氧化铝熔体的阴极电化学研究采用了W电极。而目前TiH2基可湿润阴极是极具发展前景的铝电解槽阴极材料,但这方面的研究还很不够,需做进一步的研究。     

Density and ionic structure of NdF3-LiF melts

NdF3-LiF melts are commonly used in the electrolysis process of metallic neodymium production. Research on the density and ionic structure of the electrolyte is important for its close connection with the electrolysis mechanism and process. In this paper, the density of LiF-NdF3 melts was studied by the Archimedes method. The results showed that the density decreased with increasing temperature and LiF contents. The changing law was discussed and explained in terms of the micro ionic structure of the melts....     

Equivalent conductivity and its activation energy of NaF-AlF3 melts

Electrical conductivity of NaF-AlF3 melts was measured by continuously varying cell constant(CVCC) technique. Relationships between equivalent conductivity at 990-1 030 ℃ and temperature and composition, and relationship between equivalent conductivity activation energy and composition of the melts were then studied on the basis of two-step decomposition mechanism of AlF63-. According to the changes of molar fractions of different anions in NaF-AlF3 melts, courses of dependence of equivalent conductivity and its activation energy on composition were analyzed. The results show that the influence of temperature on equivalent conductivity of the melts is small in the researched temperature range, and equivalent conductivity increases with increasing the molar fraction of AlF3; there is a minimum point in the activation energy-composition curve when molar fraction of AlF3 is 0.29.     

Identification of structural entities in NdF3-LiF melts with cryoscopic method

Nd-F species in NdF3-LiF melts were studied using cryoscopic method.Liquidus temperatures of melts of various compositions were determined by differential thermal analysis(DTA).Based on the different model calculations,NdF4- was identified as the most likely Nd-F entity in the melts in which the mole fraction of NdF3 was lower than 20%,considering only one single Nd species in the melt,and which was formed in accordance with Temkin model or Flood model.Then,activities of different components in the melts were researched.The results show that activity of LiF decreases,and that of NdF3 increases with increasing the mole fraction of NdF3.The value of activity coefficient of NdF3 is higher than 1,and that of LiF is lower than 1.