Performance of the first Japanese large-scale facility for radon inhalation experiments with small animals

A radon test facility for small animals was developed in order to increase the statistical validity of differences of the biological response in various radon environments. This paper illustrates the performances of that facility, the first large-scale facility of its kind in Japan. The facility has a capability to conduct approximately 150 mouse-scale tests at the same time. The apparatus for exposing small animals to radon has six animal chamber groups with five independent cages each. Different radon concentrations in each animal chamber group are available. Because the first target of this study is to examine the in vivo behaviour of radon and its effects, the major functions to control radon and to eliminate thoron were examined experimentally. Additionally, radon progeny concentrations and their particle size distributions in the cages were also examined experimentally to be considered in future projects.     

Liquefaction and dechlorination of hydrothermally treated waste mixture containing plastics with glass powder

Additive effects of glass powder upon the product yields and chlorine distribution after liquefaction of hydrothermally pretreated mixed waste (HMW) are compared with liquefaction of HMW with any one of water, quartz sand, or glass powder plus water. As a result, addition of either water or quartz sand did not affect liquefaction and dechlorination of HMW. Further, water (5 g) addition did not enhance liquefaction and dechlorination of HMW with glass powder. On the other hand, after liquefaction of HMW with glass powder, the yields of chlorine in the gas and water insoluble constituents decreased and the chlorine yield in the water-soluble constituent increased significantly. Because sodium in glass powder dissolved in a small amount (0.5 g) of water resulted from dehydration of HMW during liquefaction. Further, hydrogen chloride derived from polyvinylchloride in HMW was neutralized by ion exchange between H(+) and Na(+) dissolved in a small amount of water forming NaCl in the Residue (water-soluble) constituent. Therefore, most of chlorine in HMW was removed easily by water extraction of the Residue constituent after liquefaction of HMW with glass powder. Further, upgrading of HMW into the oil constituent was enhanced due to inhibition of production of chlorine containing organic compounds. Accordingly, it was clarified that glass powder was the most effective additive for liquefaction and dechlorination of HMW.     

Effect of proton irradiation on electrical properties of CuInSe2 thin films

High-energy proton irradiation (380 keV and 1 MeV) on the electrical properties of CuInSe₂ (CIS) thin films has been investigated. The samples were epitaxially grown on GaAs (0 0 1) substrates by Radio Frequency sputtering. As the proton fluence exceeded 1×10¹³ cm⁻², the carrier concentration and mobility of the CIS thin films were decreased. The carrier removal rate with proton fluence was estimated to be about 1000 cm⁻¹. The electrical properties of CIS thin films before and after irradiation were studied between 80 and 300 K. From the temperature dependence of the carrier concentration in CIS thin films, we found N_D=9.5×10¹⁶ cm⁻³, N_A=3.7×10¹⁶ cm⁻³ and E_D=21 meV from the fitting to the experimental data on the basis of the charge balance equation. After irradiation, a defect level was created, and N_T=1×10¹⁷ cm⁻³ for a fluence of 3×10¹³ cm⁻², N_T=5.7×10¹⁷ cm⁻³ for a fluence of 1×10¹⁴ cm⁻² and E_T=95 meV were also obtained from the same fitting. The new defect, which acted as an electron trap, was due to proton irradiation, and the defect density was increased with proton fluence.     

Thermomagnetic Effects in High-Mobility PbTe Films

The narrow-gap compound semiconductor PbTe has high Hall mobility. The Fermi surface at the L-point in the Brillouin zone has large anisotropy. In this work, we measured thermomagnetic effects in PbTe thin films to confirm anisotropy of the Nernst coefficient A _Ne and show Nernst mobility from the ratio of A _Ne and the Seebeck coefficient S: μ _Ne = A _Ne/S. Angular dependences of the Nernst voltage show that A _Ne is independent of the angle between the temperature gradient and the magnetic field, because of the high L-point symmetry. The calculated Nernst mobility was compared with the Hall mobility. Because the former is smaller, the Mott equation cannot explain the Seebeck coefficient at room temperature.     

Oxidation behavior of copper nanoparticles at low temperature

A mass gain for copper nanoparticles with a mean diameter of 20 nm in a 20% oxygen-nitrogen atmosphere was measured at 150-300 °C using thermogravimetry (TG). The mass gain equilibrium of the copper particles differed at each temperature, and a threshold temperature was recorded. Oxide products, consisting mainly of Cu₂O, formed on the copper nanoparticles below the threshold temperature. Above the threshold temperature, there was an initial, and drastic, formation of Cu₂O, which then changed to CuO. The activation energy for the oxidation of the copper nanoparticles that could be calculated from the rate of the mass gain was an indication of the nano-effect of the copper nanoparticles.     

Perhydropolysilazane-derived silica-polymethylmethacrylate hybrid thin films highly doped with spiropyran: Effects of polymethylmethacrylate on the hardness, chemical durability and photochromic properties

Polymethylmethacrylate (PMMA)-perhydropolysilazane (PHPS) hybrid thin films doped with spiropyran were prepared by spin-coating, which were then converted into 0.26-1.7 μm thick, spiropyran-doped PMMA-silica hybrid films by exposure treatment over aqueous ammonia. The spiropyran/(spiropyran + PHPS + PMMA) mass ratio was fixed at a high value of 0.2 so that the films exhibit visual photochromic changes in color, while the PMMA/(PMMA + PHPS) mass ratio, r, was varied. The spiropyran molecules in the as-prepared films were in merocyanine (MC) and spiro (SP) forms, with and without an optical absorption at 500 nm, at low (r ≤ 0.2) and high (r ≥ 0.4) PMMA contents, respectively. When PMMA content r was increased from 0 to 0.2, the degree of the MC-to-SP conversion on vis light illumination was enhanced, while at higher r's the spiropyran molecules underwent photodegradation. When the silica film (r = 0) was soaked in xylene under vis light, the spiropyran molecules were almost totally leached out, while not on soaking in the dark. On the other hand, no leaching occurred for the film of r = 0.2 either in the presence or absence of vis light. These suggest that the introduction of PMMA is effective in improving the chemical durability of the films, while the silica film (r = 0) is an interesting material with a photoresponsive controlled-release ability. The pencil hardness of the films decreased with increasing PMMA content, but remained over 9H at r ≤ 0.4.     

Clinical features of ovarian cancer in Japanese women with germ-line mutations of BRCA1

BACKGROUND: Stentless aortic xenografts are an important addition to the range of prosthetic valves. So far their use has been restricted to a limited number of study centers. This report summarizes the principal findings from the Second International Symposium on Stentless Bioprostheses. Attention is focused on the Toronto SPV and Freestyle valves recently approved by the United States Food and Drug Administration. METHODS: Stentless xenografts are used predominantly in elderly patients with aortic stenosis. Implant techniques are more complex than for stented valves, as reflected by longer ischemic and cardiopulmonary bypass times. The valves have been subjected to detailed serial echocardiographic assessment and clinical follow-up. RESULTS: The hemodynamic characteristics resemble those of the aortic homograft. There is a progressive increase in effective orifice area and decrease in transvalvular pressure gradients with time. Left ventricular mass index and wall thickness normalize between 6 and 12 months postoperatively. Left ventricular remodeling is accompanied by improved symptomatic status and a low incidence of valve-related complications. Limited comparative studies suggest important benefits over stented xenografts. Improved hemodynamics may translate into better bioprosthetic durability. CONCLUSIONS: Reproducible and reliable implant methods should be taught carefully, but the hemodynamic advantages are substantial. Stentless xenografts are ideal for the elderly patient with aortic stenosis.     

A control method for the matrix converter based on virtual AC/DC/AC conversion using carrier comparison method

This paper proposes a novel control method based on the virtual AC/DC/AC conversion for the matrix converter. The virtual AC/DC/AC conversion method is a very simple strategy to control the input current and the output voltage for the matrix converter. There are two new topics proposed in this paper. First, this paper proposes the minimum switching loss modulation on the virtual rectifier. In our proposed modulation, only two arms switching in the virtual rectifier using DC link current control by the virtual inverter can obtain clean sinusoidal input current. Second, a novel lean controlled carrier modulation on the virtual inverter is proposed. The leans of the triangle carrier are controlled by the duty ratio of the rectifier side pulse. The lean controlled carrier reduces harmonic distortion of the input current by avoiding interference between the rectifier control and the inverter control. These new proposals are confirmed by simulation and experimental results. © 2005 Wiley Periodicals, Inc. Electr Eng Jpn, 152(3): 65–73, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20144     

Deuterium NMR analysis of main-chain polymer liquid crystals

Summary Deuterium NMR measurements have been performed for main-chain polymer liquid crystals having structures such as {Ø-OC(O)-Ø-O(CD₂)_nO-Ø-C(O)O-Ø-O(CH₂)_nO}_x with n = 9, 10. D-NMR spectra obtained in the nematic mesophase are compared with those previously reported for the dimer liquid crystals of the type NC---O(CD₂)_nO---CN with n = 9, 10, Although resolutions are relatively poor in the polymer spectrum, the general profiles of the spectra were found to be similar to those of the corresponding dimer. The results of the RIS analysis suggest that the spatial configurations of the spacer are nearly identical between the dimer and polymer. It has been concluded that the observed enhancement in the quadru-polar splittings should arise largely from a higher orientational ordering of the molecular axis in the polymeric system.