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31.
Recently, in our laboratory a closed form expression for the correlation function of the hard-sphere dimer fluid obtained
from Wertheims multidensity Ornstein-Zernike integral equation theory with Percus-Yevick approximation was presented by Kim
et al. [2001]. However, it is difficult to apply its expression to perturbation theory and vapor-liquid equilibria calculations,
since it is of very complex form. In this work, we present a simplified expression for the first shell of the radial distribution
function (RDF) of the hard-sphere dimer fluid using a series expansion of the analytical expression. The expansion is carried
out in terms of both the packing fraction and the radial distance. Expressions are also obtained for the coordination number
and its first and second derivatives as functions of radial distance and packing fraction. These expressions, which are useful
in perturbation theory, are simpler to use than those obtained from the starting equation, while giving good agreement with
the original expression results. Then we present an simplified equation of state for the square-well dimer fluid of variable
well width (λ) based on Barker-Henderson perturbation theory using its expression for the radial distribution function of
the hard-sphere dimer fluid, and test its expression with NVT and Gibbs ensemble Monte Carlo simulation data [Kim et al.,
2001]. 相似文献
32.
如何利用循环体诸如初值、终值、步长和下标式等数学对象的诸如恒等、正负、单调性一类的数学特征,按照严格推导出来的简单规则,绕过各种复杂的数据依赖关系图及其上诸如拓扑排序或等价变换等复杂的操作,直接从事向量化处理,这是极富实用价值的研究方向.文献[2,3,5]给出的可原形/准原形算法,以及本文的可反原形与拟离散性,正是这样的捷径.它们能使相当部分的常见循环,直接向量化. 相似文献
33.
34.
Nguyen An Tien I. Ya. Mittova O. V. Almjasheva S. A. Kirillova V. V. Gusarov 《Glass Physics and Chemistry》2008,34(6):756-761
Nanocrystalline LaFeO3 is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO3 nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size. 相似文献
35.
We present a numerical study of the packing of uniform spheres under three-dimensional vibration using the discrete element method (DEM), focusing on the effects of vibration condition (amplitude and frequency) and inter-particle frictions (sliding and rolling frictions). The results are analysed in terms of packing density, coordination number (CN), radial distribution function (RDF) and pore structure. It is shown that increasing either the vibration amplitude or frequency causes packing density to increase initially to a maximum and then decrease. Both vibration frequency and amplitude should be considered to characterize the effect of vibration process on packing structure. The sliding and rolling frictions between particles can decrease packing density since they dissipate energy, although the effect of rolling friction is less significant. In line with the change of packing density, microstructural properties such as CN, RDF and pore distribution also change: a looser packing often corresponds to smaller CN, less peaked RDF and larger but more widely distributed pores. 相似文献
36.
37.
Sung-Hoon An U-Yeol Park Kyung-In Kang Moon-Young Cho Hun-Hee Cho 《Canadian Metallurgical Quarterly》2007,21(4):259-264
Total conceptual cost estimates and the assessment of the quality of these estimates are critical in the early stages of a building construction project. In this study, the support vector machine (SVM) model for assessing the quality of conceptual cost estimates is proposed, and the application of SVM in construction areas is investigated. The results show that the SVM model assessed the quality of conceptual cost estimates slightly more accurately than the discriminant analysis model. This shows that using the SVM has potential in construction areas. In addition, the SVM model can assist clients in their evaluation of the quality of the estimated cost and the probability of exceeding the target cost, and in their decision on whether or not it is necessary to seek a more accurate estimate in the early stages of a project. 相似文献
38.
39.
Control of calcium hexaluminate grain morphology in in-situ toughened ceramic composites 总被引:2,自引:0,他引:2
The influence of processing conditions on the morphology of calcium hexaluminate (CA6) grains in Al2O3: 30 vol% CaO·6Al2O3 (CA6) ceramic composites was investigated. Specimens were prepared by in-situ reaction sintering using precursor powders of alumina, and either calcium carbonate or calcium oxide. In some samples, 1 vol% anorthite glass was added as a sintering aid. X-ray diffraction was used to study the phase development in the as-calcined and sintered states. The resultant microstructures were characterized using both scanning electron microscopy (SEM), and imaging secondary ion mass spectrometry (SIMS). It was found that the CA6 grains developed a platelike morphology when CaCO3 was used as the starting calcium-rich powder. In contrast, samples prepared using CaO resulted in equiaxed CA6 grains. This result was observed to be independent of the anorthite glass addition. The findings are rationalized in terms of distinct CA6 reaction mechanisms, resulting from differences in the reactivity of the powders during the early stages of calcining.Cement Nomenclature C
CaO
- A
Al2O3 相似文献
40.
混酸PEG酯的合成及性能研究 总被引:3,自引:1,他引:2
用从大豆油脚水解制得的脂肪酸合成混酸聚乙二醇酯,通过测定酸值的方法确定了最佳反应时间为16h。与油酸聚乙二醇酯相比,混酸聚乙二醇酯具有更优良的乳化性、润湿性,可以替代油酸聚乙二醇酯用于纺织、农药和化妆品工业中。 相似文献