Elevated temperature impact on performance of Low Temperature Co-fired Ceramic dielectrics

The need for electronics to operate at temperatures of 200°C and above continues to grow. These applications include avionics, aerospace, automotive, downhole drilling, mining, and many others. To satisfy this demand, a significant amount of research and development has been conducted. Despite the efforts, the number of new electronic components designed specifically for high-temperature operation is still relatively limited. In Low Temperature Co-fired Ceramic (LTCC) packages, LTCC materials are generally used as the host media for a number of pre-fabricated semiconductor components. As a result, reliability of the entire LTCC package largely depends on the performance of the least robust component. Ferro A6M-E and Ferro L8 are the two well-established and recognized LTCC dielectrics widely used for mid and high frequency LTCC applications, including several high reliability aerospace and defense applications that require demanding Mil-Spec qualifications. This study is our first attempt to characterize and understand basic high-temperature dielectric properties of these two commercial LTCC materials. The secondary objective is to initiate a dialogue in attempt to establish reliability requirements for LTCC packages dedicated for high-temperature operation.     

Aging effect of atmospheric pressure plasma jet treated polycaprolactone polymer solutions on electrospinning properties

In previous work, an atmospheric pressure plasma jet was applied to successfully improve the electrospinnability of poly-ε-caprolactone (PCL) which enabled the fabrication of beadless nanofibers. In this paper, we report the aging effect of the plasma treatment to evaluate the robustness of the developed process. For this purpose, plasma-treated PCL polymer solutions with different exposure time were stored for 1 and 8 days and the aged solutions were analyzed in terms of conductivity, viscosity, surface tension, pH, and polymer molecular weight. During storage, the surface tension and acidity of the plasma-treated solutions were maintained constant. However, the viscosity was found to be significantly lower after 8 days which was attributed to PCL degradation. Electrospinning of all stored PCL solutions resulted in the generation of beadless PCL nanofibers. The plasma treatment effects were thus found to be highly stable over time and capable of producing high-quality PCL nanofibers up to 8 days. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48914.     

Lignin from Annual Plants as Raw Material Source for Flavors and Basic Chemicals

The enzymatic conversion of lignins, possibly in combination with electrochemical oxidation, makes aromatics such as syringol, guaiacol, vanillin and catechol available in the qualities required by the fragrance industry. The lignins were obtained by soda digestion from wheat straw and Miscanthus, characterized and then converted with laccases. The overall yield amounted up to 9 wt % with a product spectrum confined to four substances. Catechol was the major product, with a fraction of ≈75 %. It can easily be isolated by extraction with acetone.     

Cyclic distillation technology – a mini‐review

Process intensification in distillation systems has received much attention during past decades, with the aim of increasing both energy and separation efficiency. Various techniques, such as internal heat‐integrated distillation, membrane distillation, rotating packed bed, dividing‐wall columns and reactive distillation were studied and reported in the literature. All these techniques employ the conventional continuous counter‐current contact of vapor and liquid phases. Cyclic distillation technology is based on an alternative operating mode using separate phase movement which leads to key practical advantages in both chemical and biochemical processes. This article provides a mini‐review of cyclic distillation technology. The topics covered include the working principle, design and control methods, main benefits and limitations as well as current industrial applications. Cyclic distillation can be rather easily implemented in existing columns by simply changing the internals and the operating mode, thus bringing new life to old distillation towers by significantly increasing the column throughput, reducing the energy requirements and offering better separation performance. © 2016 Society of Chemical Industry     

Cloning and heterologous expression of three type II PKS gene clusters from Streptomyces bottropensis

Mensacarcin is a potent cytotoxic agent isolated from Streptomyces bottropensis. It possesses a high content of oxygen atoms and two epoxide groups, and shows cytostatic and cytotoxic activity comparable to that of doxorubicin, a widely used drug for antitumor therapy. Another natural compound, rishirilide A, was also isolated from the fermentation broth of S. bottropensis. Screening a cosmid library of S. bottropensis with minimal PKS-gene-specific primers revealed the presence of three different type II polyketide synthase (PKS) gene clusters in this strain: the msn cluster (mensacarcin biosynthesis), the rsl cluster (rishirilide biosynthesis), and the mec cluster (putative spore pigment biosynthesis). Interestingly, luciferase-like oxygenases, which are very rare in Streptomyces species, are enriched in both the msn cluster and the rsl cluster. Three cosmids, cos2 (containing the major part of the msn cluster), cos3 (harboring the mec cluster), and cos4 (spanning probably the whole rsl cluster) were introduced into the general heterologous host Streptomyces albus by intergeneric conjugation. Expression of cos2 and cos4 in S. albus led to the production of didesmethylmensacarcin (DDMM, a precursor of mensacarcin) and the production of rishirilide A and B (a precursor of rishirilide A), respectively. However, no product was detected from the expression of cos3. In addition, based on the results of isotope-feeding experiments in S. bottropensis, a putative biosynthesis pathway for mensacarcin is proposed.     

Synthesis and properties of YBa2Cu3O7-δ – Y2Ba4CuWO10.8 superconducting composites

YBa₂Cu₃O_7-δ (YBCO) is a well-known high-temperature superconductor. However, its critical current density and thus maximum trapped magnetic field can be improved significantly by introducing the secondary phases (artificial pinning centers). In this contribution, we successfully prepared YBCO single-grain bulks with Y₂Ba₄CuWO_10.8 phase serving as a source of pinning centers. This phase was prepared by solid-state reaction and further refined by milling. In the next step single-grain YBCO bulks with homogeneously distributed Y₂Ba₄CuWO_10.8 were prepared by top-seeded melt growth. Precursors as well as the final product were characterized by XRD, SEM and EDS. The phase composition of YBCO bulks containing Y₂Ba₄CuWO_10.8 was analyzed using Rietveld analysis. Thermal stability of YBCO bulk was studied by STA. Furthermore, PPMS was used to study electrical resistivity and critical current density. Bulk superconducting properties such as levitation force and trapped field ability were also measured.     

A surface-enhanced Raman spectroscopy study of thin graphene sheets functionalized with gold and silver nanostructures by seed-mediated growth

We describe a simple method for decorating graphene (1–5 layers) with Au and Ag nanostructures (nanoparticles, nanorods, and nanoplates). We deposit graphene electrostatically from highly-oriented pyrolytic graphite onto Si/SiO₂ surfaces functionalized with (aminopropyl)trimethoxysilane and grow the metal nanostructures by a seed-mediated growth method from hexanethiolate-coated Au monolayer-protected cluster “seeds” that are attached to graphene by hydrophobic interactions. Scanning electron microscopy reveals the selective growth of Au or Ag nanostructures on the graphene surface. In the case of Au, the low pH 2.8 growth solution causes etching of the graphene and formation of scroll-like structures. For Ag, the high pH 9.3 solution does not seem to affect the graphene. Raman spectroscopy is consistent with the graphene morphology and reveals that the presence of Au and Ag nanostructures increases the Raman scattering from the graphene by a factor of about 45 and 150, respectively. This work demonstrates a simple method for decorating graphene with noble metal nanostructures that may have interesting optical, electronic, and chemical properties for applications in nanoelectronics, sensing, and catalysis.     

A review of biodiesel production by integrated reactive separation technologies

Biodiesel is a biodegradable and renewable fuel, emerging as a viable alternative to petroleum diesel. Conventional biodiesel processes still suffer from problems associated with the use of homogeneous catalysts and the limitations imposed by the chemical reaction equilibrium, thus leading to severe economic and environmental penalties. This work provides a detailed review—illustrated with relevant examples—of novel reactive separation technologies used in biodiesel production: reactive distillation/absorption/extraction, and membrane reactors. Reactive separation offers new and exciting opportunities for manufacturing the fatty acid alkyl esters involved in the industrial production of biodiesel and specialty chemicals. The integration of reaction and separation into one operating unit overcomes equilibrium limitations and provides major benefits such as low capital investment and operating costs. These reactive separation processes can be further enhanced by heat‐integration and powered by heterogeneous catalysts, to eliminate all conventional catalyst related operations, using efficiently the raw materials and the reaction volume, while offering higher conversion and selectivity, as well as significant energy savings compared with conventional biodiesel processes. Remarkable, in spite of the high degree of integration, such integrated reactive‐separation processes are still very well controllable as illustrated by the included examples. Copyright © 2012 Society of Chemical Industry     

Nanoparticles of CdCl2 with closed cage structures

Nanoparticles of various layered compounds having a closed cage or nanotubular structure, designated also inorganic fullerene-like (IF) materials, have been reported in the past. In this work IF-CdCl₂ nanoparticles were synthesized by two methods. In one technique, a high temperature evaporation and subsequent condensation of dried cadmium chloride powder was used. In the other method, electron beam irradiation of the source powder led to its recrystallization into closed nanoparticles with a nonhollow core. The two methods are shown to produce nanoparticles of different topologies. While mostly spherical nested structures are obtained from the high temperature process, polyhedra with hexagonal or elongated rectangular characters are obtained by the electron beam induced process. The analysis also shows that, while the source (dried) powder is orthorhombic cadmium chloride monohydrate, the crystallized IF cage consists of the anhydrous 3R polytype which is not stable as bulk material in ambient atmosphere. Consistent with previous observations, this study shows that the seamless structure of the IF materials can stabilize phases, which are otherwise unstable in ambient conditions.     

Temperature influence on the behavior of polysulfone‐b‐poly(alkylene oxide)‐b‐poly(dimethylsiloxane) triblock copolymers in a selective solvent

Triblock copolymers containing polysulfone, poly(alkylene oxide), and poly(dimethylsiloxane) segments were obtained by addition of preformed α,ω‐bis(hydrogensilyl) poly(dimethylsiloxane) oligomers to alyl end‐capped poly(alkylene oxide)‐b‐polysulfone. Viscometric and UV absorption measurements were carried out in dilute 1,2‐dichlorethane solutions, in the temperature range of 20–75°C. The specific interactions exhibited by the block copolymers in a selective solvent are influenced by the copolymer composition and temperature. The results point to a conformational transition phenomenon, located around 55°C, which is attributed to the transition from a segregated to a pseudo‐Gaussian conformation through a compressed‐segregated conformation. POLYM. ENG. SCI., 57:114–118, 2017. © 2016 Society of Plastics Engineers