Color PCA eigenimages and their application to compression and watermarking

From the birth of multi-spectral imaging techniques, there has been a tendency to consider and process this new type of data as a set of parallel gray-scale images, instead of an ensemble of an n-D realization. However, it has been proved that using vector-based tools leads to a more appropriate understanding of color images and thus more efficient algorithms for processing them. Such tools are able to take into consideration the high correlation of the color components and thus to successfully carry out energy compaction. In this paper, a novel method is proposed to utilize the principal component analysis in the neighborhoods of an image in order to extract the corresponding eigenimages. These eigenimages exhibit high levels of energy compaction and thus are appropriate for such operations as compression and watermarking. Subsequently, two such methods are proposed in this paper and their comparison with available approaches is presented.     

In vitro gas production profiles and fermentation end‐products in processed peas,lupins and faba beans

BACKGROUND: An experiment was carried out to establish whether using a pre‐compacting device (expander) changes the contribution of dry matter (DM) and degradative behaviour of peas, lupins and faba beans over the different fractions (non‐washable fraction, NWF; insoluble washable fraction, ISWF; soluble washable fraction, SWF). Samples of the entire concentrate ingredients (WHO ingredients) and their different fractions (NWF, ISWF and SWF) were subjected to three processes (Retsch milling, R; expander treatment, E; expander‐pelleting, EP) and their fermentation characteristics were evaluated using an in vitro gas production technique. RESULTS: In peas and faba beans, both the E and EP processes increased the size of the NWF (P < 0.05) and decreased the size of the SWF compared with the R process. The maximum fractional rate of gas production in the first phase of fermentation was higher in the E and EP samples than in the R samples (P < 0.05). In lupins and faba beans the E and EP processes shifted the pattern of fermentation towards a more glucogenic fermentation, as represented by a lower non‐glucogenic to glucogenic ratio (NGR). Ammonia production (NH₃‐N) in the E and EP samples was significantly (P < 0.05) lower than that in the R samples. CONCLUSION: It is concluded that the E and EP processes provide a certain level of protection against ruminal breakdown to dietary protein and shift the pattern of fermentation towards a more glucogenic fermentation. Copyright © 2008 Society of Chemical Industry     

纳米结构Ni-Al_2O_3梯度涂层的制备及结构表征（英文）

将微米级的Ni和Al_2O_3粉末通过行星式球磨机沉积在固定于球磨罐内顶端的铝板上,制备纳米结构的Ni-Al_2O_3复合涂层。共采用五组不同Ni与Al_2O_3质量比(1:1~16:1)的混合粉末,并制备一组纯Ni涂层。用XRD、SEM和TEM技术对涂层的相组成和微观结构进行表征。结果表明,初始混合粉末的成分对涂层中Al_2O_3颗粒的含量和微观结构有很大影响。Al_2O_3含量高的初始混合粉沉积的涂层中,Al_2O_3颗粒所占体积分数大。虽然通过本研究的方法可沉积出含有50%Al_2O_3颗粒的Ni-Al_2O_3复合涂层,但其性能差,制备出的致密度高、无裂纹和/或孔洞的涂层中Al_2O_3颗粒的含量小于20%,且需用Ni和Al_2O_3质量比≥4:1的初始混合粉制备。研究还发现,机械和冶金结合是涂层和铝基体结合的主要机理。通过在同一制备条件下沉积两种独立的涂料层可以成功制备出具有较好的致密度和完整性的功能梯度复合涂层。     

Effect of Immersion Time on Corrosion Behavior of Single-Phase Alloy and Nanocomposite Bismuth Telluride-Based Thermoelectrics in NaCl Solution

The corrosiveness of bismuth telluride-based thermoelectric materials (n-type single-phase alloy and a nanocomposite with MoS₂ nanoinclusions), in 0.1 molar solution of sodium chloride (NaCl), was investigated. The electrochemical impedance spectroscopy curves obtained after 1, 24, 48 and 72 h immersion time revealed the enhancement of the corrosion resistance of the nanocomposite specimen in a 0.1 molar NaCl solution in comparison with the single-phase bismuth telluride-based alloys, and the passivity increased by immersion time up to 72 h. The nanocomposite sample with submicron grains provided suitable nucleation sites for passive film nucleation that led to higher protective behavior.     

Oxovanadium(IV) salicylidene Schiff base complex anchored on mesoporous silica MCM-41 as hybrid materials: a robust catalyst for the oxidation of sulfides

Oxovanadium(IV) Schiff base complex have been anchored onto the surface of purely siliceous MCM-41 and tested for its activity as catalyst for the oxidation of sulfides. This catalyst could alter this oxidation reaction extremity, exhibiting excellent yields with 100 % selectivity. The intercalation of the complex inside the silica matrix was supported by various characterization techniques like X-ray diffraction, differential thermogravimetric (TG-DTA), BET measurements, UV–Vis diffuse reflectance spectroscopy and Fourier transform infrared spectroscopy (FT-IR). The stability of the catalyst during the course of the reaction was confirmed from its post catalytic FT-IR and XRD analysis. The catalyst could be reused five times without notable loss of its catalytic activity and efficiency which indicates that the metal-Schiff base moiety is intact and the coordination environments are not altered during the reaction.     

The effect of nano-size additives on the electrical conductivity of matrix suspension and properties of self-flowing low-cement high alumina refractory castables

Influence of two nano-size additives on electrical properties of suspension matrix of self-flowing low-cement high alumina refractory castable is investigated. For this purpose, castament FS 10 and FS 20 on the basis of polycarboxylate ether were considered. The self-flow value, workability and mechanical strength of the castable are evaluated and their relations with electrical conductivity are determined. Using these relations, the type and optimum amount of proper additive for these refractory castables are determined. It was shown that if the electrical conductivity of matrix suspension is less than 0.71 mS/cm, high alumina low-cement self-flowing refractory castable can be obtained. The best self-flow, sufficient working time and adequate mechanical strength in the castables are obtained with 0.08 wt.% FS 20.     

TiN Nanoparticles for Enhanced THz Generation in TDS Systems

By virtue of the surface plasmon resonance effect, plasmonic nanoparticles (NPs) can localize the light field and significantly enhance the performance of some optoelectronic devices. In this work, NPs are employed for an enhanced generation of terahertz radiation from LT-GaAs-based antennas. Therefore, we have prepared plasmonic TiN NPs by direct ultrasonication (ULS) and pulsed laser ablation (PLA) techniques. The zeta potential, particle size, and absorbance were used to characterize the NPs in their colloidal forms in a comparison to commercial Au NPs. A layer of polydispersed titanium nitride (TiN) NPs prepared by PLA and deposited on the surface of an LT-GaAs device shows a significant improvement of terahertz signal generation from these devices with an enhancement of the peak to peak amplitude of 100%.     

Study the effect of distribution of density of states on the depletion width of organic Schottky contacts

Organic semiconductor to metal Schottky contacts have been widely used in electronic devices and to investigate the properties of organic semiconductors. In designing and characterizing these devices the full depletion approximation is used. The analytical and numerical simulations presented in this paper suggest that this approximation is not generally valid. Simulations of a Schottky contact between regioregular-poly 3 hexylthiophene (rr-P3HT) and aluminum show that this approximation becomes worse as molecular order decreases, with the potential profile increasingly deviating from the expected quadratic function of position. Also the depletion width decreasing well below that predicted using the approximation. In this work the slope of the band tail is used as a measure of disorder.     

Probabilistic stability of uncertain composite plates and stochastic irregularity in their buckling mode shapes: A semi-analytical non-intrusive approach

In this study, the mechanical properties of the composite plate were considered Gaussian random fields and their effects on the buckling load and corresponding mode shapes were studied by developing a semi-analytical non-intrusive approach. The random fields were decomposed by the Karhunen−Loève method. The strains were defined based on the assumptions of the first-order and higher-order shear-deformation theories. Stochastic equations of motion were extracted using Euler–Lagrange equations. The probabilistic response space was obtained by employing the non-intrusive polynomial chaos method. Finally, the effect of spatially varying stochastic properties on the critical load of the plate and the irregularity of buckling mode shapes and their sequences were studied for the first time. Our findings showed that different shear deformation plate theories could significantly influence the reliability of thicker plates under compressive loading. It is suggested that a linear relationship exists between the mechanical properties’ variation coefficient and critical loads’ variation coefficient. Also, in modeling the plate properties as random fields, a significant stochastic irregularity is obtained in buckling mode shapes, which is crucial in practical applications.     

Double-walled microspheres loaded with meglumine antimoniate: preparation,characterization and in vitro release study

Objective: The objective of this study was to fabricate double-walled poly(lactide-co-glycolide) (PLGA) microspheres to increase encapsulation efficiency and avoid rapid release of hydrophilic drugs such as meglumine antimoniate.

Methods: In this study, double-walled and one-layered microspheres of PLGA were prepared using the emulsion solvent evaporation technique to better control the release of a hydrophilic drug, meglumine antimoniate (Glucantime®), which is the first choice treatment of cutaneous leishmaniasis. The effect of hydrophobic coating on microspheres' size, morphology, encapsulation efficiency and drug release characteristics was evaluated. Furthermore, the presence of antimony in meglumine antimoniate made it possible to observe the drug distribution within the microspheres' cross section by means of energy dispersive X-ray spectroscopy.

Results: Drug distribution images confirmed accumulation of the drug within the inner core of double-walled microspheres. In addition, these microspheres encapsulated the drug more efficiently up to 87% and demonstrated reduced initial burst and prolonged release compared to one-layered microspheres. These superiorities make double-walled microspheres an optimum candidate for sustained delivery of hydrophilic drugs.

Conclusion: Double-walled microspheres provide some advantages over traditional microspheres overcoming most of their limitations. Double-walled microspheres were found to be more efficient than their corresponding one-layered microspheres in terms of encapsulation efficiencies and release characteristics.