Influence of very long aging on the relaxation behavior of flame‐retardant printed circuit board epoxy composites under mechatronic conditions

Very long aging times, up to 15,100 h (629 days) at 110°C, were achieved on flame‐retardant printed circuit board laminates commonly used in automotive design. This composite was fabricated from glass fibers embedded in an epoxy resin. Aging was performed in an oven under an air atmosphere at a temperature lower than the glass‐transition temperature. Temperature‐modulated differential scanning calorimetric analysis was used to investigate the influence of such aging on the glass‐transition phenomena. A new amorphous phase appeared during aging. By extending the analysis to samples collected at different thicknesses, we demonstrated the existence of a time‐dependent gradient of the properties. A skin–core structure was evidenced, and this slowed down oxidation and allowed physical aging to occur in the bulk sample. An exponential law described the variations of the glass‐transition of the new external compound. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 786‐792, 2013     

Periodic-like words, periodicity, and boxes

We introduce the notion of periodic-like word. It is a word whose longest repeated prefix is not right special. Some different characterizations of this concept are given. In particular, we show that a word w is periodic-like if and only if it has a period not larger than , where is the least non-negative integer such that any prefix of w of length $\geq R'_{w}$ is not right special. We derive that if a word w has two periods , then also the greatest common divisor of p andq is a period ofw. This result is, in fact, an improvement of the theorem of Fine and Wilf. We also prove that the minimal period of a word w is equal to the sum of the minimal periods of its components in a suitable canonical decomposition in periodic-like subwords. Moreover, we characterize periodic-like words having the same set of proper boxes, in terms of the important notion of root-conjugacy. Finally, some new uniqueness conditions for words, related to the maximal box theorem are given. Received: 10 July 2000 / Accepted: 24 January 2001     

Numerical Investigation of Engineering Systems: Analysis of Accuracy Reduction Due to Model Oversimplification

When faced with the mathematical modeling of any engineering system, whether for design, performance assessment, optimization, or control, the engineer has to determine the level of accuracy versus the simplicity of the mathematical formulation. Although it is universally accepted that the more complex the formulation, the more accurate the results will be, these usually come at the expense of larger CPU times, a substantial amount of computer resources, and are generally limited by the capacity of computers and computing power, which most times precludes their use in favor of simpler models. Many times, however, engineers do not realize the potential risk that oversimplification of a problem generates in terms of accuracy of the results; that is, the model solution does not resemble the system behavior. Through a demonstrative example, the present study addresses the issue of oversimplification of the resulting mathematical model and the corresponding accuracy of its solution. After constructing three sets of models of the physical system, each with a different level of detail, the solutions are then compared to experimental data. The results show that the accuracy of the numerical approximation depends directly on the level of complexity of the mathematical model used, and that oversimplification may result in up to a ninefold degradation of the results. In addition, minor changes in the inlet boundary condition and geometry result in significant changes in the flow pattern, up to a fivefold difference between different models in the recirculation bubble relative error. This information is fundamental for engineering professionals to consider during the modeling process in applications.     

Transfer of urban ideas: The emergence of Venezuelan urbanism in the proposals for 1930s’ Caracas

This article focuses on the emergence of Venezuela's modern urbanism through the proposals for 1930s’ Caracas. In an effort to combine the different discourses which underpinned the urban discipline, both technical and legal literature are reviewed. As a way of illustrating how urbanistic ideas travelled from Europe to Latin America until the early decades of this century, the article stresses the professional background of the French urbanists called to design the 1939 ‘Plan Monumental’ of Caracas. The role of the local administration in assembling the different strands which had shaped Venezuelan urbanism since the late 19th century is highlighted.     

Optimization by lumped control of reactors with langmuir-hinshelwood catalyst deactivation

A method is proposed for solving the problem of temperature optimal control in tubular fixed-bed reactors with reaction systems described by Langmuir-Hinshelwood-Hougen-Watson kinetic equations. The optimization problem is formulated by N state differential equations corresponding to the N differential fixed-bed reactors in which the integral reactor is divided. It is solved using the control vector parameterization computational technique. The proposed method when applied to a simple reaction system reported previously in the literature gives analogous results, and thus validates the theory. This theory is applied to the dehydrogenation of benzyl alcohol to benzaldehyde. An analysis of optimality problem shows a strong influence of the temperature dependence of the ratio of reaction rate to deactivation reaction rate on the optimal policy.     

CO-gasification of pelletized wood residues

A pelletization process was designed which produces cylindrical pellets ∼8 mm in length and 4 mm in diameter. These ones were manufactured using a blend of Pinus Patula and Cypress sawdust and coal in proportions of 0%, 5%, 10%, 20%, and 30% v/v of coal of rank sub-bituminous extracted from the Nechí mine (Amagá-Antioquia). For this procedure, sodium carboxymethyl cellulose (CMC) was used as binder at three different concentrations. The co-gasification experiments were carried out with two kinds of mixtures, the first one was composed of granular coal and pellets of 100% wood and the second one was composed of pulverized wood and granular coal pellets. All samples were co-gasified with steam by using an electrical heated fluidized-bed reactor, operating in batches, at 850 °C. The main components of the gaseous product were H₂, CO, CO₂, CH₄, and N₂ with approximate quantities of 59%, 6.0%, 20%, 5.0%, and 9.0% v/v, respectively, and the higher heating values ranged from between 7.1 and 9.5 MJ/Nm³.     

A review of instance selection methods

In supervised learning, a training set providing previously known information is used to classify new instances. Commonly, several instances are stored in the training set but some of them are not useful for classifying therefore it is possible to get acceptable classification rates ignoring non useful cases; this process is known as instance selection. Through instance selection the training set is reduced which allows reducing runtimes in the classification and/or training stages of classifiers. This work is focused on presenting a survey of the main instance selection methods reported in the literature.     

Within- and between-language priming differ: Evidence from repetition of pictures in Spanish-English bilinguals.

In the current study, the authors used an immediate repetition paradigm with pictures to observe whether repetition enhances word production in bilinguals. In Experiment 1, participants were asked to name pictures that were named previously in the same language (Spanish-Spanish or English-English) or in the opposite language (Spanish-English or English-Spanish). Results revealed a repetition effect both within languages and between languages. Furthermore, there was an asymmetry within language, with repetition priming being larger in Spanish than in English. Experiments 2 and 3 revealed that lag interacted with language for both within- and between-language priming. However, lag resulted in a decrease in the asymmetry for within- but not between-language priming. The results are consistent with the view that within- and between-language repetition priming are mediated by different mechanisms. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

An Evaluation of Vaporizing Rates of SiO2 and TiO2 As Protective Coatings for Ultrahigh Temperature Ceramic Composites

For temperatures >1973 K, the thermodynamic and kinetic analyses of the major gaseous species for a liquid titanate layer would vaporize significantly less than a silicate layer, when considering these layers as a protective barrier for ultrahigh temperature ceramic composites. At 2500 K, the major species is TiO( g ) with p _{TiO( g )}=0.1 kPa compared with SiO( g ) with p _{SiO( g )}=1.3 × 10³ kPa at the Ti/TiO₂ and Si/SiO₂ equilibrium, respectively. The SiO( g ) attains a partial pressure greater than ambient pressure at 2500 K even with a thermodynamic activity of 0.01 considering equilibration with a silicide (e.g., TiSi _x ). In addition, at 2500 K the TiO₂ layer would vaporize at a rate of 0.23 mm/s compared with the SiO₂ layer's loss rate of 207 mm/s. Although the oxygen diffusivity and permeability through titanate solutions must be further analyzed, the thermodynamic and kinetic analyses for vaporization indicate a longer duration for a liquid titanate than for a liquid silicate layer at ultrahigh temperatures.