Improvement in shape memory in magnesium niobate modified PZST

A modified lead zirconate stannate titanate system (PZST) has been studied for shape memory effect. Addition of magnesium niobate (MN) slows down the dipole relaxation process, leading to increased (∼3-fold improvement) remnant strain in the PZST system (0.99PZST–0.01PMN). Room temperature X-ray diffraction patterns before poling (antiferroelectric (AFE) tetragonal) and after poling (ferroelectric (FE) rhombohedral), clearly demonstrate that the transition to the ferroelectric phase is stable even in the absence of any electric field. A small applied electric field (∼1.7 kV/cm) in the opposite direction was required to bring the sample back to its original shape. Field-induced strain butterfly loops taken at 50 Hz show that the material response time is quite small.     

Affinity Studies of Hemicyanine Derived Water Soluble Colorimetric Probes with Reactive Oxygen/Nitrogen/Sulfur Species

Peroxynitrite (ONOO^-) is an essential endogenous reactive oxygen species (ROS) generated in mitochondria under various pathological and physiological conditions. An increase in its level in mitochondria is related to numerous diseases. Herein, we report a series of hemicyanine-derived water-soluble colorimetric probes ( 1 – 4 ) and the reactivity of which was studied with various reactive oxygen, nitrogen, and sulfur species. Probes 1 – 4 are formed by conjugating 1,2,3,3-tetramethyl-3H-indolium iodide and 4-hydroxybenzaldehyde or its derivatives through an alkene linkage formed by the Knoevenagel reaction. Oxidative cleavage of the electron-rich double bond of the conjugated hemicyanine dye revealed a discerning affinity of probe 3 towards peroxynitrite among all reactive oxygen species. The rapid change in color of 3 provides a sensitive and selective method for detecting peroxynitrite with a low detection limit of 180 nM. Notably, the water solubility of the probe displays excellent performance for the selective detection of peroxynitrite among ROS and reactive nitrogen (RNS)/sulfur species (RSS). UV-vis, ¹H NMR, and ¹³C NMR spectroscopic data and results from theoretical calculations provide further information on the interaction of peroxynitrite with probe 3 .     

Nonwoven viscose fabric-polyvinyl alcohol based flexible composite

Development of ecofriendly packaging materials is still a challenging area. Researchers are continuously working to improve the mechanical and barrier properties of the different polymers which are used in the packaging industry. Selection of reinforcement and matrix for any composite are based upon end use applications. The novelty of the work is development of fully biodegradable, flexible, lightweight biocomposite by reinforcing needle punched flexible nonwoven viscose fabric to the PVA solution. The effect of PVA concentration and areal density of viscose fabric on the properties of prepared composite is examined. The composite thus prepared is assessed in terms of mechanical, thermal, breathability, and UV blocking properties. The nonwoven viscose-PVA composite shows excellent improvement in tensile strength of 100% to 300% with respect to PVA film of equivalent concentration for two different areal densities of viscose fabric. The composite also exhibits improved thermal stability and UV blocking property with respect to parent components. However, a reduction in flexibility (with respect to PVA film) as well as breathability (with respect to viscose fabric) of the composite is observed. Based upon the improved performance of the viscose-PVA composite in terms of mechanical properties, UV and water vapor permeability, it seems that the composite has a strong potential for application in the packaging sector as a flexible as well as biodegradable composite.     

A copper–cyclen coordination complex associated with a polyoxometalate anion: Synthesis,crystal structure and electrochemistry of [Cu(cyclen)(MeCN)][W6O19]

The reaction between Cu(NO₃)₂·3H₂O and a tetra-aza macrocycle, more specifically, cyclen in 1:1 MeCN–MeOH solvent mixture forms a Cu²⁺–cyclen coordination complex in situ, that has been reacted with an isopolyanion [W₆O₁₉]^2? in a slow diffusion technique, resulting in the isolation of an ion-pair solid [Cu(cyclen)(MeCN)][W₆O₁₉] (1). Single crystal structural investigation on 1 shows a square pyramidal geometry around the metal centre (copper ion) with an axially bound MeCN solvent molecule. The title compound 1 is the first crystallographically characterized ion-pair compound, in which a transition metal coordination complex of a tetra-aza-crown ether (cyclen) has been associated with a polyoxometalate cluster anion. This communication deals with synthesis, spectroscopic, structural and electrochemical analyses of compound 1.     

Profile of Triacylglycerols,Phenols, and Vitamin E of Manjari Medika Grape Seed Oil and Cake: Introducing a Novel Indian Variety

The aim of the study is to investigate the biochemical composition of grapeseed oil and cake from an unexplored Indian grape‐juice cultivar, Manjari Medika (MM). The composition of oil and residual seed cake is evaluated using various chromatographic and spectroscopic techniques. The findings demonstrate that the vitamin E content of MM‐seed oil (1.15–1.35 g kg^?1) is distinctively higher than the Codex standard, suggesting its superior quality as an edible oil. The predominant triacylglycerols include trilinolein (LLL, 43%), dilinoleoyl‐stearylglycerol (LSL, 19%), and dilinoleoyl‐palmitoylglycerol (LLP, 11%), which are earlier recognized as natural antioxidants. The seed‐cake is rich in polyphenols including acylated anthocyanins (e.g., pelargonidin‐3‐O‐coumaroyl glucoside) and certain other flavonoids (e.g., catechin). The profile of phytonutrients in MM seed‐oil and cake is significantly superior to its seeded female parent and two other widely cultivated wine‐grape varieties. In brief, the studied by‐products of this new grape‐juice cultivar can be an important source of high‐value ingredients for use in food supplements, nutraceuticals, and functional foods. Practical applications: This study reports the phytochemical profile of the seed‐oil and seed cake derived from a newly developed grape variety, Manjari Medika. High contents of selective antioxidants: lipids, vitamin E, and phenols in the seed‐oil and cake with health benefits suggest their potential for use in nutraceutical and functional foods. These byproducts can be utilised as ingredients of functional foods and nutraceuticals (e.g., grape seed oil capsule) and also as raw materials in food supply chains (e.g., for production of grape cookies or cake). MM can also be utilized as a colorant in the food industry.     

Pattern synthesis of centre fed linear array using Taylor one parameter distribution and restricted search Particle Swarm Optimization

In this article, a new method of pattern synthesis of centre fed, equal distance linear array having single and multiple synthesis objectives has been proposed and statistically investigated. Single objective of reduced side lobe level (SLL) and first null beamwidth (FNBW) has been considered separately. Consequently, multiple objectives of beamwidth and side lobe level have been investigated. Synthesis of linear array for suitable objectives has been investigated on Taylor one parameter distribution with equal progressive phase. Excitation amplitude of each array element is taken as optimization parameter where distribution has been optimized using Particle Swarm Optimization (PSO) for achieving low SLL. Later the same has been incorporated for obtaining suitable FNBW. In our optimization algorithm conventional PSO has been modified with a restricted search PSO (RSPSO) where search space has been predefined within excitation amplitude range. PSO within the defined range searches for optimum excitation amplitude to achieve the desired objectives. In order to illustrate the effectiveness of the proposed RSPSO, simulation results of three significant instances of linear array have been presented for both even and odd number of element. The design results obtained using RSPSO have improved result than those obtained using other state of the art evolutionary algorithms like differential evolution (DE), invasive weeds optimization (IWO) and Conventional particle Swarm optimization (CPSO) in a statistically significant way.     

The effect of modifying an edge-plane pyrolytic graphite electrode with single-wall carbon nanotubes on its use for sensing diclofenac

A simple and highly sensitive sensor based on edge-plane pyrolytic graphite electrode (EPPGE) coated with single-wall carbon nanotubes is proposed for diclofenac determination in nanomolar concentrations. The oxidation of diclofenac occurred in two well-defined peaks having peak potentials ∼439 and ∼854 mV at pH 7.2. The modified electrode showed excellent catalytic activity presenting much higher peak currents than those measured on a bare EPPGE. Under the optimum conditions, the calibration curve was linear in the concentration range 1 × 10⁻⁹-500 × 10⁻⁹ M and 25 × 10⁻⁹-1500 × 10⁻⁹ M for peaks I and II, respectively. The limit of detection for peaks I and II was found as 0.82 × 10⁻⁹ and 22.5 × 10⁻⁹ M, respectively. The developed sensor was applied for the determination of diclofenac in biological and pharmaceutical samples using square-wave voltammetry and the validation of results using high performance liquid chromatography showed excellent agreement.     

BIST/Digital-Compatible Testing of RF Devices Using Distortion Model Fitting

Testing of Radio Frequency (RF) circuits for nonlinearity specifications generally requires the use of multiple test measurements thereby contributing to increased test cost. Prior RF test methods have suffered from significant test calibration effort (training for supervised learners) when using compact tests or from increased test time due to direct specification measurement. On the other hand, due to aggressive technology scaling, there are plenty of digital transistors available that can be used to simplify testing of Analog/Mixed-Signal (AMS) and RF devices. In this paper, an RF test methodology is developed that: (a) allows RF devices to be tested for several distortion specifications using distortion model fitting algorithms in test time comparable to what can be achieved using supervised learning techniques while retaining the accuracy of direct specification measurement, (b) allows multiple RF specifications to be determined concurrently from a single data acquisition and (c) allows digital-compatible testing/BIST to be performed using digital testers or on-chip built in self-test (BIST) circuitry. With regard to (a), a key benefit is that no training of supervised learning algorithm is necessary. The proposed method based on distortion model fitting is shown to give excellent results across common RF performance metrics while providing ~10× improvements in test time compared to previous methods.     

Junction Temperature Measurements and Thermal Modeling of GaInN/GaN Quantum Well Light-Emitting Diodes

We present a junction temperature analysis of GaInN/GaN quantum well (QW) light-emitting diodes (LEDs) grown on sapphire and bulk GaN substrate by micro-Raman spectroscopy. The temperature was measured up to a drive current of 250 mA (357 A/cm²). We find better cooling efficiency in dies grown on GaN substrates with a thermal resistance of 75 K/W. For dies on sapphire substrates we find values as high as 425 K/W. Poor thermal performance in the latter is attributed to the low thermal conductivity of the sapphire. Three-dimensional finite-element simulations show good agreement with the experimental results, validating our thermal model for the design of better cooled structures.     

Conventional and Unconventional Mechanisms by which Exocytosis Proteins Oversee β-cell Function and Protection

Type 2 diabetes (T2D) is one of the prominent causes of morbidity and mortality in the United States and beyond, reaching global pandemic proportions. One hallmark of T2D is dysfunctional glucose-stimulated insulin secretion from the pancreatic β-cell. Insulin is secreted via the recruitment of insulin secretory granules to the plasma membrane, where the soluble N-ethylmaleimide-sensitive factor attachment protein receptors (SNAREs) and SNARE regulators work together to dock the secretory granules and release insulin into the circulation. SNARE proteins and their regulators include the Syntaxins, SNAPs, Sec1/Munc18, VAMPs, and double C2-domain proteins. Recent studies using genomics, proteomics, and biochemical approaches have linked deficiencies of exocytosis proteins with the onset and progression of T2D. Promising results are also emerging wherein restoration or enhancement of certain exocytosis proteins to β-cells improves whole-body glucose homeostasis, enhances β-cell function, and surprisingly, protection of β-cell mass. Intriguingly, overexpression and knockout studies have revealed novel functions of certain exocytosis proteins, like Syntaxin 4, suggesting that exocytosis proteins can impact a variety of pathways, including inflammatory signaling and aging. In this review, we present the conventional and unconventional functions of β-cell exocytosis proteins in normal physiology and T2D and describe how these insights might improve clinical care for T2D.