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排序方式: 共有2102条查询结果,搜索用时 62 毫秒
101.
Cover Picture: Development of Potent and Metabolically Stable APJ Ligands with High Therapeutic Potential (ChemMedChem 21/2016) 下载免费PDF全文
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加工技术与设备的发展通常会使加工时间缩短.但是新型助剂的应用也可减少加工时间,大大降低成本.随着iFlash系统的应用,漂白温度可降至80℃,活性染料染色后皂洗的时间也大大缩短.因此,织物间歇式染色得到优化,在不增加额外投资的情况下运行更经济. 相似文献
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Kseniya Khamina Andreas B. Diendorfer Susanna Skalicky Moritz Weigl Marianne Pultar Teresa L. Krammer Catharine Aquino Fournier Amy L. Schofield Carolin Otto Aaron Thomas Smith Nina Buchtele Christian Schoergenhofer Bernd Jilma Bernhard J. H. Frank Jochen G. Hofstaetter Regina Grillari Johannes Grillari Klemens Ruprecht Christopher E. Goldring Hubert Rehrauer Warren E. Glaab Matthias Hackl 《International journal of molecular sciences》2022,23(3)
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Gernot HACKL Yong TANG Gerald NITZL Dennis SCHURMANN Bernd WILLERS Sven ECKERT 《中国耐火材料》2021,(2):45-50
Fluid flow in the mold has a significant impact on the quality of continuously cast steel products.Since it is strongly influenced by the SEN design,attention h... 相似文献
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Bernd H. Engler 《化学,工程师,技术》1991,63(4):298-312
Catalysts for environmental protection. The main emitters of anthropogenic air pollution are internal combustion engines, power plants, and production processes. Components of exhaust gases which are regarded as pollutants are hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NOx), sulfur dioxide (SO2), and dust. Three main types of catalyst are understood to improve the environment; namely automotive emission control, NOx abatement and oxidation. To reduce the pollutants HC, CO, and NOx in automobile exhaust gas, three-way catalysts are currently applied. The reduction of particle emissions in diesel exhaust gas is achieved by diesel filters and oxidation catalysts. Pollutants from power plants are mainly the inorganic components NOx and SO2. In the SCR process, NOx is catalytically reduced to nitrogen and water. The DESONOX process is suited for the simultaneous catalytic abatement of NOx and SOx. Exhaust gases from production processes in many areas require after-treatment. Therefore catalyst formulations depend on process parameters and exhaust gas components. This overview presents and explains catalyst types, design, mode of operation, and processes. 相似文献
108.
Discovery of a Short‐Chain Dehydrogenase from Catharanthus roseus that Produces a New Monoterpene Indole Alkaloid 下载免费PDF全文
Dr. Anna K. Stavrinides Dr. Evangelos C. Tatsis Dr. Thu‐Thuy Dang Dr. Lorenzo Caputi Dr. Clare E. M. Stevenson Dr. David M. Lawson Dr. Bernd Schneider Prof. Sarah E. O'Connor 《Chembiochem : a European journal of chemical biology》2018,19(9):940-948
Plant monoterpene indole alkaloids, a large class of natural products, derive from the biosynthetic intermediate strictosidine aglycone. Strictosidine aglycone, which can exist as a variety of isomers, can be reduced to form numerous different structures. We have discovered a short‐chain alcohol dehydrogenase (SDR) from plant producers of monoterpene indole alkaloids (Catharanthus roseus and Rauvolfia serpentina) that reduce strictosidine aglycone and produce an alkaloid that does not correspond to any previously reported compound. Here we report the structural characterization of this product, which we have named vitrosamine, as well as the crystal structure of the SDR. This discovery highlights the structural versatility of the strictosidine aglycone biosynthetic intermediate and expands the range of enzymatic reactions that SDRs can catalyse. This discovery further highlights how a sequence‐based gene mining discovery approach in plants can reveal cryptic chemistry that would not be uncovered by classical natural product chemistry approaches. 相似文献
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Tandy S Bossart K Mueller R Ritschel J Hauser L Schulin R Nowack B 《Environmental science & technology》2004,38(3):937-944
Metal pollution of soils is widespread across the globe, and the clean up of these soils is a difficulttask. One possible remediation technique is ex-situ soil washing using chelating agents. Ethylenediaminetetraacetic acid (EDTA) is a very effective chelating agent for this purpose but has the disadvantage that it is quite persistent in the environment due to its low biodegradability. The aim of our work was to investigate the biodegradable chelating agents [S,S]-ethylenediaminedisuccinic acid (EDDS), iminodisuccinic acid (IDSA), methylglycine diacetic acid (MGDA), and nitrilotriacetic acid (NTA) as potential alternatives and compare them with EDTA for effectiveness. Kinetic experiments showed for all metals and soils that 24 h was the optimum extraction time. Longer times only gave minor additional benefits for heavy metal extraction but an unwanted increase in iron mobilization. For Cu at pH 7, the order of the extraction efficiency for equimolar ratios of chelating agent to metal was EDDS > NTA> IDSA > MGDA > EDTA and for Zn it was NTA > EDDS > EDTA >MGDA > IDSA. The comparatively low efficiency of EDTA resulted from competition between the heavy metals and co-extracted Ca. For Pb the order of extraction was EDTA > NTA >EDDS due to the much stronger complexation of Pb by EDTA compared to EDDS. At higher concentration of complexing agent, less difference between the agents was found and less pH dependence. There was an increase in heavy metal extraction with decreasing pH, but this was offset by an increase in Ca and Fe extraction. In sequential extractions EDDS extracted metals almost exclusively from the exchangeable, mobile, and Mn-oxide fractions. We conclude that the extraction with EDDS at pH 7 showed the best compromise between extraction efficiency for Cu, Zn, and Pb and loss of Ca and Fe from the soil. 相似文献