粉末冶金法制备SiC晶须增强MB15镁基复合材料

采用粉末冶金法制备了SiC晶须增强镁基复合材料(SiCW／MB15)试样。通过检测基体显微硬度探讨了SiCW对镁合金时效规律的影响，并借助扫描电镜(SEM)、透射电镜(TEM)和拉伸试验，研究了混粉方式对复合材料室温力学性能、SiCW分布及显微结构的影响。结果表明，MB15及其复合材料的时效硬化曲线上均存在双峰现象；SiCW的加入既提高了MB5的硬度，又加快了其时效速度：混粉方式对晶须分布及SiCW／MB15复合材料的室温力学性能影响很大。     

钼酸盐与其他缓蚀剂协同缓蚀效应的研究

简要介绍了钼酸盐缓蚀剂的缓蚀机理,并对钼酸盐与其他缓蚀剂协同缓蚀效应的研究作了综述。     

改善聚酯装置热媒炉运行状况的几项措施

介绍了聚酯装置的热媒炉在运行过程中多次停炉的原因和存在的问题 ,比如燃料油压力波动、燃料油温度低、含水高、控制系统联锁频繁、热效率下降等 ,通过增设燃料油罐、提高油罐温度、改造增压泵、优化VR -4控制系统以及其它措施 ,大大改善了热媒炉的运行状况     

Data-based adaptive online prediction model for plant-wide production indices

A data-based adaptive online prediction model is proposed for plant-wide production indices based on support vector regression, a general method which we customized specifically to model very large data sets that are generated dynamically and periodically. The proposed model can update its parameters online according to the statistical properties of the training samples. Further, in order to improve the prediction precision, each sample is weighted with a dynamic penalty factor that considers the effect of each sample on the prediction model accuracy. Moreover, a customized procedure is introduced to handle large training sets. After having been convincingly evaluated on benchmark data, effectiveness and performance of our approach for plant-wide production indices is demonstrated using industrial data from an operating ore dressing plant over a range of scale in training data set size. The higher accuracy and shorter computation times than existing methods suggest that it may prove advantageous in actual application to dynamic production processes.     

Swelling of pH‐sensitive chitosan–poly(vinyl alcohol) hydrogels

The swelling properties of different chitosan–poly(vinyl alcohol) (PVA) hydrogels were investigated as functions of the medium pH and salt concentration. The maximum swelling ability of the hydrogels was at a buffer pH of approximately 3, regardless of the PVA content in the hydrogels. The maximum mass of the swollen hydrogels was about 13 times that of their contracted counterparts. The cyclical swelling and contraction between pH 3 and pH 7 buffers and pH 3 and pH 3 buffers with salt confirmed the Donnan swelling mechanism of these hydrogels. The swelling mechanism was considered the transfer of water molecules driven by a concentration gradient. This was represented by a simplified mass‐balance model, which neglected the effect of the ionization reaction, for the initial swelling period. The effective mass‐transfer coefficient of water molecules during swelling, estimated with this model, gradually decreased with increasing PVA content in the hydrogels. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4665–4671, 2006     

meso-四(2-氨基-5-磺酸苯基)卟啉的合成及其与钴显色反应的研究

研究了新水溶性 meso-四(2-氨基-5-磺酸苯基)卟啉的合成。提出以冰乙酸加乙酸酐代替常用的丙酸作介质,所得 meso-四(2-硝基苯基)卟啉为紫蓝色片状晶体,再将其还原和磺化得标题试剂。还研究了试剂于氨性介质中,在 Pb(Ⅱ)存在下与钴(Ⅱ)的显色反应。钴的二元配合物的最大吸收波长为429nm,表观摩尔吸光系数为1.50×10~5。可用于维生素 B_(12)注射液中痕量钴的测定。     

乙苯/乙烯烷基化反应中EA-8402分子筛催化剂的失活动力学研究

用内循环无梯度反应器,在593～633K范围内考察了在乙苯/乙烯进行定向烷基化反应合成对二乙苯时,EA-8402分子筛催化剂的失活行为,建立了相应的失活动力学模型: -da/dt=0.3271exp(-12.94/T)P_(EB)~(0.02)P_(E(?))~(0.383)·α这一模型可作为该反应的宏观动力学模型的补充。由失活级数d=1,按Levenspiel判据推断:其失活机理应该是不受内扩散阻力控制的平行-连串失活。     

Inhibitory effect of Cr（Ⅵ） on activities of soil enzymes

To evaluate the influence of various Cr(VI) concentrations (0.05, 0.25, 0.50, 1.00 and 2.00 g/kg) on the activity of soil enzymes, the activities of catalase, polyphenol oxidase, dehydrogenase, alkaline phosphatase in soils were investigated in the incubation experiment with a period of 35 d. The results indicate that all the tested Cr(VI) concentrations significantly inhibit dehydrogenase activity by over 70% after 35 d. The activity of alkaline phosphatase is slightly inhibited during the whole experiment except for on the day 7. Cr(VI) has no obvious effect on the activity of catalase in soil. On the contrary, Cr(VI) stimulates the activity of polyphenol oxidase. The results suggest that dehydrogenase activity can be used as an indicator for assessing the severity of chromium pollution. Foundation item: Projects(2006AA06Z374, 2007AA021304) supported by the National High-Tech Research and Development Program of China; Project(2008SK2007) supported by the Key Program of Science and Technology of Hunan Province, China     

基于扩展OpenC++植入技术研究与实现

本文首先介绍了常用的植入方法并分析了优缺点,重点详细分析了基于扩展OpenC+-植入技术的实现方法。     

Promotion of hydrogen permeation on metal-dispersed alumina membranes and its application to a membrane reactor for methane steam reforming

A mesoporous membrane for selective separation of hydrogen was prepared usingthe sol-gel method. Some metal salts such as RuCl₃, Pd(NH₃)₄Cl₂, RhCl₃,, and H ₂PtCl₆, were added to the boehmite sol and coated on a porous alumina substrate before firing at 500°C. It was foundthat the permeability of hydrogen and the separation factor for a hydrogen-nitrogen gaseous mixture of these metaldispersed membranes exceeded the limitations of the Knudsen diffusion mechanism. Although the gas permeation through a neat alumina membrane is governed by the Knudsen diffusion, the metals dispersed in alumina membranes were effective in promoting hydrogen permeation. These metaldispersed alumina membranes were also used in a membrane reactor for methane steam reforming at low temperature. In the temperature range of 300 to 500°C, the membrane reactor attained a methane conversion twice as high as the equilibrium value of the packed bed catalytic reactor system as a result of the selective removal of hydrogen from the reaction system.