Development of a Highly Selective,Sensitive, and Fast Response Upconversion Luminescent Platform for Hydrogen Sulfide Detection

Hydrogen sulfide (H₂S) has been recognized as one of most important gaseous signaling molecules mediated by a variety of physiological and pathological processes. Yet, its functions remain largely elusive due to the lack of potent monitoring methods. Hereby this issue is addressed with a powerful new platform—dye‐assembled upconversion nanoparticles (UCNPs). A series of chromophores with different absorption bands and fast responses towards H₂S is combined with UCNPs and results in a library of H₂S sensors with responsive emission signals ranging from the visible to the near‐infrared (NIR) region. These nanoprobes demonstrate highly selective and rapid responses to H₂S in vitro and in cells. Furthermore, H₂S levels in blood can be detected using the developed nanoprobes. Hence the reported H₂S sensing platform can serve as a powerful diagnostic tool to research H₂S functions and to investigate H₂S‐related diseases.     

Embedding RhPx in N,P Co‐Doped Carbon Nanoshells Through Synergetic Phosphorization and Pyrolysis for Efficient Hydrogen Evolution

Rational design and controllable synthesis of well‐defined nanostructures with high stability and Pt‐like activity for hydrogen evolution reaction (HER) are critical for renewable energy conversion. Herein, a unique pyrolysis strategy is demonstrated for the synthesis of RhP_x nanoparticles (NPs) in N, P co‐doped thin carbon nanoshells (RhP_x@NPC nanoshells) that display high electrocatalytic activity and stability over a wide pH range. This strategy involves simultaneous phosphorization and pyrolysis processes that can produce highly‐dispersed RhP_x NPs within N, P co‐doped carbon nanoshells and at the same time induce thinning of carbon nanoshells from inside out. The resulting RhP_x@NPC nanoshells not only possess Pt‐like activity for HER with low overpotentials to achieve 10 mA cm^?2 (22 mV in 0.5 m H₂SO₄, 69 mV in 1.0 m KOH, and 38 mV in 1.0 m phosphate buffered saline (PBS)) but also provide long‐term durability in a wide pH range. The remarkable HER performance of RhP_x@NPC nanoshells is ascribed to the high surface area, abundant mesoporosity, strong catalyst–support interaction, ultrathin carbon encapsulation, and N, P co‐doping. This work provides an effective strategy for designing heterostructured electrocatalysts with high catalytic activity and stability desired for reactions that may occur under harsh conditions.     

一种空空导弹发射装置故障诊断仪设计

导弹发射装置是目前我国某型战斗机所装备的主要作战武器之一,它的性能直接影响到战斗机的战斗能力,由于目前缺乏有效的故障诊断系统和仪器对导弹发射装置进行测试,所以设计了一种空空导弹发射装置故障诊断仪器;该仪器以工业控制计算机为核心,采用数据库编程技术编程,综合运用标准接口及总线技术、故障诊断技术,FIFO技术,有效地提高了仪器的通用性、可靠性;研究结果表明,该仪器能够对某型空空导弹发射装置的各种故障进行快速准确的诊断,提高部队的保障能力,具有很好的推广应用前景和重大的经济效益.     

Strengthening and toughening mechanism of a Cu-bearing high-strength low-alloy steel with refined tempered martensite/bainite (M/B) matrix and minor inter-critical ferrite

The microstructure–mechanical property relationship of a Cu-bearing low-carbon high-strength low-alloy steel, subjected to a novel multistage heat treatment inc...     

光子晶体光纤飞秒激光技术研究进展

光子晶体光纤自诞生至今的十几年来得到了快速发展,不同结构和各具特色的光子晶体光纤层出不穷。以应用于飞秒激光技术的各种光子晶体光纤为主线,介绍了目前基于光子晶体光纤飞秒激光技术的实验研究进展,尤其是高功率、高能量飞秒激光系统的研究现状和发展方向。     

Linear Study of a Large-orbit Coaxial-waveguide Cyclotron Autoresonance Maser Amplifier

A linear theory based on Maxwell-Vlasov equations and the Laplace transform is presented to describe the large-orbit coaxial-waveguide cyclotron autoresonance maser (CARM) amplifier. A 35-GHz, TE_5,1-mode large-orbit coaxial-waveguide CARM amplifier is specifically analyzed. Good agreement between the linear theory and the nonlinear simulations is found in the exponentially growing region of the wave. Results show that the operating magnetic field and the electron-beam energy and average radius substantially affect the power, and especially, a small beam current may be unsuitable to a large-orbit CARM amplifier operation.     

带闪蒸器补气的R134a准二级压缩制冷/热泵系统实验研究

为增加空气源热泵运行的稳定性及提高其性能系数,本文提出了以R134a为工质的涡旋压缩机闪蒸器补气制冷/热泵系统。搭建了实验台对压缩机排气温度、功耗、制冷量、制热量及制冷、制热性能系数进行研究。结果表明:当冷凝温度为45℃,蒸发温度为-20~0℃时,与采用相同工质的单级系统相比,补气系统的排气温度降低了6.2℃,功耗增加1.4%~2.8%,制冷量和制冷COPc分别提高19.8%和17.6%,制热量和制热COPh分别提高15.3%和13.2%。     

Experimental analysis of wet mill load based on vibration signals of laboratory-scale ball mill shell

Real-time measurement of the mill load is the key to improve the production capacity and energy efficiency for the grinding process. In this paper, experimental analysis of the wet mill load based on the vibration signals of the laboratory-scale ball mill shell is presented. A series of experiments are conducted to investigate the vibration characteristics corresponding to different grinding conditions such as dry grinding, wet grinding and water grinding. The power spectral density of the vibration signals is systematically interpreted.Experimental results show that the rheological properties of the pulp affect the amplitude and frequency of the vibration signal. The most important conclusion is that the frequency range of the shell vibration of the laboratory wet mill can be divided into three parts, namely natural frequency band, main impact frequency band and secondary impact frequency band. Finally, soft-sensor models between vibration signal and mill operating parameters of mill load are established using genetic algorithm-partial least square (GA-PLS) technology. After more work on industry scale ball mill is done, the soft-sensor modeling based on the mill shell vibration for operating parameters of mill load will improve the performance of the ball mill in the grinding process.     

麦秸秆加筋盐渍土的尺寸效应与制样问题处置

制备均匀且整体性较好的试样是保证室内实验结果可靠的前提条件。提出了两端压实的静力制样法,围绕制样中出现的几个问题,制定了适宜的应对措施。同时完成了不同直径的盐渍土和麦秸秆加筋土试样的抗压强度实验,分析了试样抗压强度的尺寸效应,以及试样直径与加筋条件间的比例关系。结果显示:采用两端压实的静力制样方法制备加筋土试样是可行的;两种试样均存在明显的尺寸效应;由于麦秸秆的加筋作用,使得麦秸秆加筋土不同尺寸试样的抗压强度尺寸效应大于盐渍土的,且其抗压强度的尺寸效应随试样尺寸的增大而越来越明显;适宜加筋长度为0.316倍试样直径,适宜加筋率0.25%。研究结果可为制备合格的加筋土试样提供参考,也有益于在未来的研究中选择更合理的麦秸秆加筋条件。     

Comparative study of porous anodic alumina: effects of aluminium deposition methods

This article reports on the comparative study of the fabrication of porous anodic alumina films by anodisation of the aluminium films on glass substrates which were deposited by direct current sputtering and electron beam evaporation methods. The relationship between surface morphology of the deposited aluminum films and porous anodic alumina films was investigated. A more uniform and ordered porous anodic alumina was obtained by fabricating from electron beam evaporation deposited aluminium film with smaller and compact grains. Two-step anodisation was used to further improve the quality of porous anodic alumina compared to one-step anodisation. The optical transmittance spectra within wavelength of 370–800 nm were obtained and the optical properties were studied.